Molecular Mobility In Polymer Systems
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Molecular Mobility in Deforming Polymer Glasses
Author | : Nikhil Padhye |
Publisher | : Springer Nature |
Total Pages | : 111 |
Release | : 2021-10-15 |
Genre | : Science |
ISBN | : 3030825590 |
This book bridges disparate fields in an exploration of the phenomena and applications surrounding molecular mobility in glassy materials experiencing inelastic deformation. The subjects of plastic deformation and polymer motion/interdiffusion currently belong to the two different fields of continuum mechanics and polymer physics, respectively. However, molecular motion associated with plastic deformation is a key ingredient to gain fundamental understanding, both at the macroscopic and microscopic level. This short monograph provides necessary background in the aforementioned fields before addressing the topic of molecular mobility accompanied by macroscopic inelastic deformation in an accessible and easy-to-understand manner. A new phenomenon of solid-state deformation-induced bonding in polymers is discussed in detail, along with some broad implications in several manufacturing sectors. Open questions pertaining to mechanisms, mechanics, and modeling of deformation-induced bonding in polymers are presented. The book’s clear language and careful explanations will speak to readers of diverse backgrounds.
Molecular Characterization of Polymers
Author | : Muhammad Imran Malik |
Publisher | : Elsevier |
Total Pages | : 670 |
Release | : 2021-03-09 |
Genre | : Technology & Engineering |
ISBN | : 012822598X |
Molecular Characterization of Polymers presents a range of advanced and cutting-edge methods for the characterization of polymers at the molecular level, guiding the reader through theory, fundamentals, instrumentation, and applications, and supporting the end goal of efficient material selection and improved material performance. Each chapter focuses on a specific technique or family of techniques, including the different areas of chromatography, field flow fractionation, long chain branching, static and dynamic light scattering, mass spectrometry, NMR, X-Ray and neutron scattering, polymer dilute solution viscometry, microscopy, and vibrational spectroscopy. In each case, in-depth coverage explains how to successfully implement and utilize the technique. This practical resource is highly valuable to researchers and advanced students in polymer science, materials science, and engineering, and to those from other disciplines and industries who are unfamiliar with polymer characterization techniques. - Introduces a range of advanced characterization methods, covering aspects such as molecular weight, polydispersity, branching, composition, and tacticity - Enables the reader to understand and to compare the available technique, and implement the selected technique(s), with a view to improving properties of the polymeric material - Establishes a strong link between basic principles, characterization techniques, and real-life applications
Molecular Motion in Polymers by ESR
Author | : Steven E. Keinath |
Publisher | : CRC Press |
Total Pages | : 360 |
Release | : 1980 |
Genre | : Science |
ISBN | : 9783718600120 |
Handbook of Multiphase Polymer Systems
Author | : Abderrahim Boudenne |
Publisher | : John Wiley & Sons |
Total Pages | : 1322 |
Release | : 2011-06-09 |
Genre | : Technology & Engineering |
ISBN | : 1119972884 |
Multiphase polymeric systems include a wide range of materials such as composites, blends, alloys, gels, and interpenetrating polymer networks (IPNs). A one-stop reference on multiphase polymer systems, this book fully covers the preparation, properties, and applications of advanced multiphase systems from macro to nano scales. Edited by well-respected academics in the field of multiphase polymer systems, the book includes contributions from leading international experts. An essential resource for plastic and rubber technologists, filler specialists and researchers in fields studying thermal and electrical properties.
Electrical and Optical Polymer Systems
Author | : Donald L. Wise |
Publisher | : CRC Press |
Total Pages | : 1266 |
Release | : 1998-03-27 |
Genre | : Science |
ISBN | : 9780824701185 |
"Offers background information, methods of characterization, and applications for electrical and optical polymers, including biopolymers, and tutorial sections that explain how to use the techniques."
Clay-Polymer Nanocomposites
Author | : Khouloud Jlassi |
Publisher | : Elsevier |
Total Pages | : 548 |
Release | : 2017-07-26 |
Genre | : Technology & Engineering |
ISBN | : 0323461611 |
Clay–Polymer Nanocomposites is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This book covers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers. Indeed, nanocomposites can be prepared at industrial scale by melt mixing. Regardless the synthesis method, much is said in this book about the importance of theclay pre-modification step, which is demonstrated to be effective, on many occasions, in obtaining exfoliated nanocomposites. Clay–Polymer Nanocomposites reports the background to numerous characterization methods including solid state NMR, neutron scattering, diffraction and vibrational techniques as well as surface analytical methods, namely XPS, inverse gas chromatography and nitrogen adsorption to probe surface composition, wetting and textural/structural properties. Although not described in dedicated chapters, numerous X-ray diffraction patterns of clay–polymer nanocomposites and reference materials are displayed to account for the effects of intercalation and exfoliations of layered aluminosilicates. Finally, multiscale molecular simulation protocols are presenting for predicting morphologies and properties of nanostructured polymer systems with industrial relevance. As far as applications are concerned, Clay–Polymer Nanocomposites examines structural composites such as clay–epoxy and clay–biopolymers, the use of clay–polymer nanocomposites as reactive nanocomposite fillers, catalytic clay-(conductive) polymers and similar nanocomposites for the uptake of hazardous compounds or for controlled drug release, antibacterial applications, energy storage, and more. - The most comprehensive coverage of the state of the art in clay–polymer nanocomposites, from synthesis and design to opportunities and applications - Covers the various methods of characterization of clay–polymer nanocomposites - including spectroscopy, thermal analyses, and X-ray diffraction - Includes a discussion of a range of application areas, including biomedicine, energy storage, biofouling resistance, and more
Polymer Dynamics and Relaxation
Author | : Richard Boyd |
Publisher | : Cambridge University Press |
Total Pages | : 369 |
Release | : 2007-09-13 |
Genre | : Technology & Engineering |
ISBN | : 1107320259 |
Polymers exhibit a range of physical characteristics, from rubber-like elasticity to the glassy state. These particular properties are controlled at the molecular level by the mobility of the structural constituents. Remarkable changes in mobility can be witnessed with temperature, over narrow, well defined regions, termed relaxation processes. This is an important, unique phenomenon controlling polymer transition behaviour and is described here at an introductory level. The important types of relaxation processes from amorphous to crystalline polymers and polymeric miscible blends are covered, in conjunction with the broad spectrum of experimental methods used to study them. In-depth discussion of molecular level interpretation, including atomistic level computer simulations and applications to molecular mechanism elucidation, are discussed. The result is a self-contained approach to polymeric interpretation suitable for researchers in materials science, physics and chemistry interested in the relaxation processes of polymeric systems.
The Glass Transition
Author | : E. Donth |
Publisher | : Springer Science & Business Media |
Total Pages | : 433 |
Release | : 2013-04-17 |
Genre | : Science |
ISBN | : 3662043653 |
Describes and interrelates the following processes: cooperative alpha processes in a cold liquid, structural relaxation in the glass near Tg, the Johari-Goldstein beta process, the Williams-Götze process in a warm liquid, fast nonactivated cage rattling and boson peak, and ultraslow Fischer modes.
Molecular Dynamics of Additives in Polymers
Author | : Alexander Kovarski |
Publisher | : CRC Press |
Total Pages | : 289 |
Release | : 2023-01-27 |
Genre | : Science |
ISBN | : 1466563745 |
This volume focuses on the dynamical behaviour of low-molecular additives in solid polymer matrixes. It covers: types and models of molecular motion in condensed media; dependence of motional frequency on particle structure and size, temperature, volume and stress; and polymer properties and polymeric structures. Extensive analysis of common regularities of rotational and translational dynamics of molecules introduced into polymers are given. The book also includes experimental techniques for molecular mobility evaluation, and features detailed data on rotational dynamics of additives. It should be of interest to specialists in various fields of polymer physical chemistry and materials science.