Modern Methods In Stereoselective Aldol Reactions
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| Author | : Rainer Mahrwald |
| Publisher | : John Wiley & Sons |
| Total Pages | : 604 |
| Release | : 2013-02-22 |
| Genre | : Science |
| ISBN | : 3527656731 |
The selective formation of bondings between molecules is one of the major challenges in organic chemistry, and the so-called aldol reaction is one of the most important for this purpose. These reactions are a highly useful tool for developing such novel substances as natural products and pharmaceuticals. Likes its highly successful and much appreciated predecessor, "Modern Aldol Reactions", this ready reference provides a systematic overview of methodologies for installing a required configuration during an aldol addition step, but shifts the focus so as to cover the latest developments. As such, it presents a set of brand new tools, including vinylogous Mukaiyama-aldol reactions and substrate-controlled aldol reactions, as well as asymmetric induction in aldol additions. Furthermore, new developments in existing stereoselective aldol additions are described, such as the deployment of supersilyl groups or organocatalyzed aldol additions. All of these methodologies are presented in the context of their deployment in the total synthesis of natural products.
| Author | : W. Carruthers |
| Publisher | : Cambridge University Press |
| Total Pages | : 556 |
| Release | : 1978-06-22 |
| Genre | : Science |
| ISBN | : 9780521217156 |
The third edition of this well-known textbook discusses some modern methods used in organic synthesis, and aims to show the value and scope of these methods and how they are used in the synthesis of complex molecules. The general plan of the book follows that of the second edition, but the opportunity has been taken to bring the book up to date and to take account of advances in knowledge and of new reactions which have come into use since publication of the earlier editions. Particular emphasis is placed on highly stereoselective organic chemistry, including stereoselective alkylations, aldol reactions, oxidations, epoxidations and reductions. New methods for the stereoselective formation of carbon-carbon double bonds, and modern application reactions are also fully considered. The book will be of use to students of chemistry and biochemistry at graduate and senior undergraduate level. It will also interest practising scientists in industry and research establishments who wish to familiarise themselves with modern synthetic methods.
| Author | : W. Carruthers |
| Publisher | : Cambridge University Press |
| Total Pages | : 510 |
| Release | : 2004-10-14 |
| Genre | : Science |
| ISBN | : 9780521778305 |
Textbook on modern methods of organic synthesis.
| Author | : Erick M. Carreira |
| Publisher | : John Wiley & Sons |
| Total Pages | : 664 |
| Release | : 2009-02-09 |
| Genre | : Science |
| ISBN | : 9783527324521 |
Die wichtigsten und nützlichsten Methoden der modernen stereoselektiven Synthese sind in diesem Band zusammengefasst. Viele anschauliche Beispiele für die Darstellung von Wirkstoffen und Naturstoffen regen zur gezielten Abwandlung und Integration in eigene Synthesewege an. Dabei geht es den Autoren weniger darum, das Gebiet in seiner Gesamtheit darzustellen; vielmehr versuchen sie, die wirklich grundlegenden Ansätze auszuwählen, die jeder organische Synthesechemiker kennen und anwenden sollte.
| Author | : Mihály Nógrádi |
| Publisher | : John Wiley & Sons |
| Total Pages | : 386 |
| Release | : 2008-07-11 |
| Genre | : Science |
| ISBN | : 3527615687 |
The state-of-the-art in stereoselective synthesis! Thoroughly revised and updated, this enlarged second edition offers a plethora of valuable information on methods and reagents in stereoselective synthesis. Methods have been selected for high efficiency and selectivity; mechanistic aspects are treated succinctly, with a strong emphasis on practical applications. For this new edition, material has been added on * homogeneous diastereoselective hydrogenations * enantioselective oxidations * novel, efficient chiral auxiliaries Much of the information given is presented in figures and tables, which makes the book a valuable reference work for the practically minded organic chemist. From reviews of the first edition: 'The extensive material in the volume should prove particularly useful to anyone involved in synthetic chemistry or teaching a course in organic chemistry.' Journal of Medicinal Chemistry 'With nearly 1400 references cited, the book contains a wealth of information and should be a useful addition to the chemist's library.' The American Scientist
| Author | : W. Carruthers |
| Publisher | : Cambridge University Press |
| Total Pages | : 416 |
| Release | : 1971-10-31 |
| Genre | : Science |
| ISBN | : 9780521081450 |
| Author | : W. Carruthers |
| Publisher | : Cambridge University Press |
| Total Pages | : 550 |
| Release | : 1986 |
| Genre | : Science |
| ISBN | : 9780521311175 |
The general plan of the book follows that of the second edition, but the opportunity has been taken to bring the book up to date and to take account of advances in knowledge and of new reactions which have come into use since publication of the earlier editions.
| Author | : Manfred Braun |
| Publisher | : John Wiley & Sons |
| Total Pages | : 454 |
| Release | : 2016-02-23 |
| Genre | : Science |
| ISBN | : 3527334521 |
Authored by one of the world?s leading synthetic chemists in the field, this reference presents modern enolate chemistry with an emphasis on metal O-enolates in asymmetric synthesis. While great care is taken to cover novel, successful concepts, such classical methods as the famous Evans enolates are equally highlighted. Throughout the book representative reaction procedures are presented, thus helping readers to find the best solution for their own synthetic problem. Of high interest to synthetic chemists in academia, as well as the pharmaceuticals, agrochemicals and fine chemicals industries.
| Author | : Manfred Braun |
| Publisher | : Springer Nature |
| Total Pages | : 326 |
| Release | : 2020-12-08 |
| Genre | : Science |
| ISBN | : 3030453049 |
The series Topics in Heterocyclic Chemistry presents critical reviews on present and future trends in the research of heterocyclic compounds. Overall the scope is to cover topics dealing with all areas within heterocyclic chemistry, both experimental and theoretical, of interest to the general heterocyclic chemistry community. The series consists of topic related volumes edited by renowned editors with contributions of experts in the field. All chapters from Topics in Heterocyclic Chemistry are published Online First with an individual DOI. In references, Topics in Heterocyclic Chemistry is abbreviated as Top Heterocycl Chem and cited as a journal.
| Author | : Gonzalo De Gonzalo |
| Publisher | : Elsevier |
| Total Pages | : 522 |
| Release | : 2024-05-04 |
| Genre | : Science |
| ISBN | : 0443190585 |
Biocatalysis in Asymmetric Synthesis, a new volume in the Foundations and Frontiers of Enzymology series, offers an applied discussion of synthesizing biological catalysts using asymmetric synthesis, for applications across research and industry. Here, global experts in the field analyze a wide variety of biocatalysts and their physical states, process conditions for their asymmetric synthesis, solvents required during synthesis, and even downstream procedures for the recovery of final products. The book adopts an interdisciplinary approach, merging fundamental biology and its synthetic applications across industries, with a wide range of practical examples, from directed evolution to biotransformation and production of novel enzymes and non-conventional catalysts. Throughout the book, the impact and application of biocatalysis in sustainable processing is considered in-depth. This book will also help non-experts in biocatalysis to apply this knowledge in their own research, providing a thorough overview of the ways asymmetric biocatalytic approaches may be adapted for different disciplines and downstream products. Explores biocatalysts as exquisite catalysts for fine chiral compound synthesis in different reaction media Features both foundational overviews and applied, practical examples across research and industry Includes chapter contributions from international leaders in the field
