Modelling Phase Equilibria
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| Author | : Stanislaw Malanowski |
| Publisher | : John Wiley & Sons |
| Total Pages | : 338 |
| Release | : 1992-05-29 |
| Genre | : Science |
| ISBN | : |
Presents a rigorous development of thermodynamic laws of phase equilibria beginning with fundamental principles, accompanied by a short description of the mathematics vital to a clear understanding of basic concepts as well as the practical methods used to calculate phase equilibria. Offers excellent explanations of well-established thermodynamic tools and novel, state-of-the-art techniques representing real fluid behavior. Models covered are relevant to the modeling of nonelectrolyte mixtures over wide ranges of pressure, temperature, composition and molecular diversity.
| Author | : Esteban Alberto Brignole |
| Publisher | : Newnes |
| Total Pages | : 347 |
| Release | : 2013-04-02 |
| Genre | : Technology & Engineering |
| ISBN | : 044459471X |
Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. - Methodologies are discussed using relevant industrial examples - The molecular nature and composition of the process mixture is given a key role in process decisions - Phase equilibrium diagrams are used as a drawing board for process implementation
| Author | : Arthur D. Pelton |
| Publisher | : Academic Press |
| Total Pages | : 404 |
| Release | : 2018-09-19 |
| Genre | : Science |
| ISBN | : 0128016698 |
Phase Diagrams and Thermodynamic Modeling of Solutions provides readers with an understanding of thermodynamics and phase equilibria that is required to make full and efficient use of these tools. The book systematically discusses phase diagrams of all types, the thermodynamics behind them, their calculations from thermodynamic databases, and the structural models of solutions used in the development of these databases. Featuring examples from a wide range of systems including metals, salts, ceramics, refractories, and concentrated aqueous solutions, Phase Diagrams and Thermodynamic Modeling of Solutions is a vital resource for researchers and developers in materials science, metallurgy, combustion and energy, corrosion engineering, environmental engineering, geology, glass technology, nuclear engineering, and other fields of inorganic chemical and materials science and engineering. Additionally, experts involved in developing thermodynamic databases will find a comprehensive reference text of current solution models. - Presents a rigorous and complete development of thermodynamics for readers who already have a basic understanding of chemical thermodynamics - Provides an in-depth understanding of phase equilibria - Includes information that can be used as a text for graduate courses on thermodynamics and phase diagrams, or on solution modeling - Covers several types of phase diagrams (paraequilibrium, solidus projections, first-melting projections, Scheil diagrams, enthalpy diagrams), and more
| Author | : Mats Hillert |
| Publisher | : Cambridge University Press |
| Total Pages | : 525 |
| Release | : 2007-11-22 |
| Genre | : Technology & Engineering |
| ISBN | : 1139465864 |
Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior. Accurate use and interpretation however, requires a strong understanding of the thermodynamic principles that underpin phase equilibrium, transformation and state. This fully revised and updated edition covers the fundamentals of thermodynamics, with a view to modern computer applications. The theoretical basis of chemical equilibria and chemical changes is covered with an emphasis on the properties of phase diagrams. Starting with the basic principles, discussion moves to systems involving multiple phases. New chapters cover irreversible thermodynamics, extremum principles, and the thermodynamics of surfaces and interfaces. Theoretical descriptions of equilibrium conditions, the state of systems at equilibrium and the changes as equilibrium is reached, are all demonstrated graphically. With illustrative examples - many computer calculated - and worked examples, this textbook is an valuable resource for advanced undergraduates and graduate students in materials science and engineering.
| Author | : Stanley I. Sandler |
| Publisher | : CRC Press |
| Total Pages | : 704 |
| Release | : 1993-10-07 |
| Genre | : Science |
| ISBN | : 9780824791308 |
Provides a definitive state-of-the-art review of the models used in applied thermodynamics. Dis-cusses all aspects of thermodynamic modeling relevant to the chemical industry-including activ4 coefficient models, equations of state, mixture group contribution methods, and specialized procedures for polymer and ele tr@01 e solutions.
| Author | : Arnold Reisman |
| Publisher | : Elsevier |
| Total Pages | : 560 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483265846 |
Phase Equilibria: Basic Principles, Applications, Experimental Techniques presents an analytical treatment in the study of the theories and principles of phase equilibria. The book is organized to afford a deep and thorough understanding of such subjects as the method of species model systems; condensed phase-vapor phase equilibria and vapor transport reactions; zone refining techniques; and nonstoichiometry. Physicists, physical chemists, engineers, and materials scientists will find the book a good reference material.
| Author | : Hasan Orbey |
| Publisher | : Cambridge University Press |
| Total Pages | : 230 |
| Release | : 1998-05-28 |
| Genre | : Science |
| ISBN | : 9780521620277 |
Reviews the latest developments in a subject relevant to professionals involved in the simulation and design of chemical processes - includes disk of computer programs.
| Author | : Adrian Bonilla-Petriciolet |
| Publisher | : John Wiley & Sons |
| Total Pages | : 381 |
| Release | : 2020-10-05 |
| Genre | : Technology & Engineering |
| ISBN | : 1119580277 |
A comprehensive overview of current developments and applications in biofuels production Process Systems Engineering for Biofuels Development brings together the latest and most cutting-edge research on the production of biofuels. As the first book specifically devoted to process systems engineering for the production of biofuels, Process Systems Engineering for Biofuels Development covers theoretical, computational and experimental issues in biofuels process engineering. Written for researchers and postgraduate students working on biomass conversion and sustainable process design, as well as industrial practitioners and engineers involved in process design, modeling and optimization, this book is an indispensable guide to the newest developments in areas including: Enzyme-catalyzed biodiesel production Process analysis of biodiesel production (including kinetic modeling, simulation and optimization) The use of ultrasonification in biodiesel production Thermochemical processes for biomass transformation to biofuels Production of alternative biofuels In addition to the comprehensive overview of the subject of biofuels found in the Introduction of the book, the authors of various chapters have provided extensive discussions of the production and separation of biofuels via novel applications and techniques.
| Author | : Bruno Predel |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 357 |
| Release | : 2013-03-09 |
| Genre | : Science |
| ISBN | : 366209276X |
This advanced comprehensive textbook introduces the practical application of phase diagrams to the thermodynamics of materials consisting of several phases. It describes the fundamental physics and thermodynamics as well as experimental methods, treating all material classes: metals, glasses, ceramics, polymers, organic materials, aqueous solutions. With many application examples and realistic cases from chemistry and materials science, it is intended for students and researchers in chemistry, metallurgy, mineralogy, and materials science as well as in engineering and physics. The authors treat the nucleation of phase transitions, the production and stability of technologically important metastable phases, and metallic glasses. Also concisely presented are the thermodynamics and composition of polymer systems. This innovative text puts this powerful analytical approach into a readily understandable and practical context, perhaps for the first time.
| Author | : Andre Muhlbauer |
| Publisher | : CRC Press |
| Total Pages | : 490 |
| Release | : 1997-09-01 |
| Genre | : Science |
| ISBN | : 9781560325505 |
This new book provides, for the first time, a thorough survey of the techniques and equipment for both high- and low-pressure phase equilibrium measurement and addresses the equally challenging task of accurately modeling or predicting the equilibria. The book is unique because it combines in depth and authoritative coverage of both experimental and theoretical procedures in a single volume. Written as a reference for practicing engineers and scientists in the chemical engineering field, this book will also be useful as an advanced graduate-level text.
