Transformation Toughening Of Ceramics

Transformation Toughening Of Ceramics
Author: David J. Green
Publisher: CRC Press
Total Pages: 292
Release: 2018-02-06
Genre: Technology & Engineering
ISBN: 1351094300

The aim of this book is to provide a coherent and up-to-date discussion of the scientific work concerning the transformation toughening of ceramics. We hope the book is useful to scientists, engineers and students who are new to these materials. It is intended both as a source of learning and information to those who are new to these materials. It is intended both as a source of learning behaviour and microstructural relationships in transformation-toughened ceramics. While it has been our aim to present a book that is current as possible at the time of publication, the subject is still expanding in many areas; so our hope is that the reader will also gain an insight into the direction of future advances.

Mechanics of Transformation Toughening and Related Topics

Mechanics of Transformation Toughening and Related Topics
Author: J.H. Andreasen
Publisher: Elsevier
Total Pages: 541
Release: 1996-05-01
Genre: Technology & Engineering
ISBN: 0080536042

Since the benefit of stress-induced tetragonal to monoclinic phase transformation of confined tetragonal zirconia particles was first recognized in 1975, the phenomenon has been widely studied and exploited in the development of a new class of materials known as transformation toughened ceramics (TTC). In all materials belonging to this class, the microstructure is so controlled that the tetragonal to monoclinic transformation is induced as a result of a high applied stress field rather than as a result of cooling the material below the martensitic start temperature. The significance of microstructure to the enhancement of thermomechanical properties of TTC is now well understood, as are the mechanisms that contribute beneficially to their fracture toughness. The micromechanics of these mechanisms have been extensively studied and are therefore presented here in a cogent manner. The authors also review dislocation formalism for the modelling of cracks and Eshelby's technique. In compiling this monograph the authors present the most up-to-date and complete review of the field and include several topics which have only recently been fully investigated.

Transformation Toughening of Ceramics

Transformation Toughening of Ceramics
Author:
Publisher:
Total Pages: 19
Release: 1995
Genre:
ISBN:

This report summarizes the results from a 3-year research program aimed at developing a basic understanding of the microstructural design, fabrication, and properties of multilayered zirconia-based composites with high toughness and oxidation resistance. Most of the effort focused on multilayered composites of Ce-ZrO2 and Al2O3 which have strongly bonded interfaces. The design of the layered composite microstructure was based on micromechanics analysis: the layers modify the shape and extent of a crack tip transformation zone, leading to toughnesses over 20 MPa.m1/2. Optimum layer thicknesses were determined and related to effects of autocatalytic transformation and crack tip advance mechanisms. Crack resistance curves were measured at various temperatures: the very high toughnesses (> 10 MPa.m1/2) were limited to temperature range of approx. 100 deg C above the Ms temperature for the martensitic transformation. A preliminary study of multilayered composites containing weakly bonded layers (which achieve toughening by debonding) indicated that rare earth phosphates (LaPO4 and CePO4) are potentially suitable layers for Y- and Ce-stabilized zirconia composites. jg.

Toughening Mechanisms in Quasi-Brittle Materials

Toughening Mechanisms in Quasi-Brittle Materials
Author: S.P. Shah
Publisher: Springer Science & Business Media
Total Pages: 590
Release: 2012-12-06
Genre: Science
ISBN: 9401133883

A variety of ceramic materials has been recently shown to exhibit nonlinear stress strain behavior. These materials include transformation-toughened zirconia which undergoes a stress-induced crystallographic transformation in the vicinity of a propagating crack, microcracking ceramics, and ceramic-fiber reinforced ceramic matrices. Since many of these materials are under consideration for structural applications, understanding fracture in these quasi-brittle materials is essential. Portland cement concrete is a relatively brittle material. As a result mechanical behavior of concrete, conventionally reinforced concrete, prestressed concrete and fiber reinforced concrete is critically influenced by crack propagation. Crack propagation in concrete is characterized by a fracture process zone, microcracking, and aggregate bridging. Such phenomena give concrete toughening mechanisms, and as a result, the macroscopic response of concrete can be characterized as that of a quasi-brittle material. To design super high performance cement composites, it is essential to understand the complex fracture processes in concrete. A wide range of concern in design involves fracture in rock masses and rock structures. For example, prediction of the extension or initiation of fracture is important in: 1) the design of caverns (such as underground nuclear waste isolation) subjected to earthquake shaking or explosions, 2) the production of geothermal and petroleum energy, and 3) predicting and monitoring earthquakes. Depending upon the grain size and mineralogical composition, rock may also exhibit characteristics of quasi-brittle materials.

Transformation Toughening of Composite Ceramics

Transformation Toughening of Composite Ceramics
Author:
Publisher:
Total Pages: 129
Release: 1990
Genre:
ISBN:

Research is underway into the application of martensitic transformations in ceramics to toughen a variety of ceramic-ceramic composites, i.e., to reduce their brittleness. The toughening agents of interest and their volume changes are dicalcium silicate (Ca2SiO4, 12%), nickel sulfide (NiS, 4%), lanthanide sesquioxides (Ln2O3, 8%) and lutentium borate (LuBO3, 8%). Ceramic processing routes have been developed to fabricate different types of toughened composites, viz., either by using a dispersed second phase microstructure or as a fine grained, single phase material. Specifically, Ca2SiO4 has been dispersed in CaZrO3 and the mechanical properties measured by bend tests. The critical importance of matrix toughness and grain size, as well as role of intergranular microcracking has been established. Dense pellets of fine grained, pure beta- Ca2SiO4 have been sintered and their transformability by grinding established. Their microstructures were examined by TEM and preliminary micromechanical studies made on it, and on Gd2O3, by indentation and SEM techniques. NiS inclusions in glass were examined by TEM and EDS and a sol gel processing route to precipitate NiS in glass has been identified. Composites of Dy2O3 in SiC and powders of LuBO3 in B2O3 have been fabricated.

Fracture Mechanics of Ceramics

Fracture Mechanics of Ceramics
Author: R.C. Bradt
Publisher: Springer Science & Business Media
Total Pages: 548
Release: 2002-02-28
Genre: Science
ISBN: 9780306466632

This volume constitutes the proceedings of the 7th International Symposium on the Fracture Mechanics of Ceramics, held at the Presidium of the Russian Academy of Sciences, Moscow, Russia, on July 20-22, 1999. The theme of the symposium focused on the mechanical behavior of advanced ceramics in terms of the cracks, particularly the crack-microstructure interaction, delayed failure, and environmental effects in fracture. Special attention was paid to the novel methods in fracture mechanics testing, pre-standardization and standardization. Authors from 19 countries represented the current state of the field.