Metalloporphyrins In Catalytic Oxidations
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| Author | : F. Montanari |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 364 |
| Release | : 2013-11-11 |
| Genre | : Science |
| ISBN | : 9401722471 |
Oxidative catalysis by metalloporphyrin systems occupies a prominent role in the current research in the fields of chemical and biological catalysis. Our particular interest and approach has been to collect in the same volume papers dealing with both the chemical and biological aspects of the reactivity of heme systems because of the realization that a better understanding of the complementary discipline can be extremely useful for the researchers from either field. The current progress of the research on synthetic metalloporphyrin catalysts has led to the development of several systems that are able to reproduce the heme-enzyme mediated oxygenation and oxidation reactions, at least in terms of reaction types, mechanisms and often rates. These achievements have stimulated the of creating metalloporphyrin catalysts which are both ambitious project efficient and stable enough to become competitive for large-scale industrial processes. Although this project is still far from being realized, the efforts in this direction parallel those aimed at the application of heme enzymes to chemical technologies, e. g. for the mild, selective oxidation of organics or the detoxification of pollutants. Both the two approaches will be advantageous because while the enzyme systems can achieve selectivities which are probably unattainable by synthetic catalysts, the latter can be active under experimental conditions that would readily inactivate the enzymes.
| Author | : Roger A. Sheldon |
| Publisher | : CRC Press |
| Total Pages | : 412 |
| Release | : 1994-06-28 |
| Genre | : Science |
| ISBN | : 9780824792282 |
This volume provides an in-depth overview of the chemistry of metalloporphyrins as oxidation catalysts in chemical and biological systems. It discusses practical techniques for the synthesis of metalloporphyrins and introduces useful methods of immobilization to improve their synthetic utility. Detailed discussions of underlying mechanistic features are provided.
| Author | : Karl Kadish |
| Publisher | : Elsevier |
| Total Pages | : 238 |
| Release | : 2000 |
| Genre | : Science |
| ISBN | : 9780123932297 |
The Porphyrin Handbook, Volume 19: Applications of Phthalocyanines provides information pertinent to every aspect of the chemistry, synthesis, spectroscopy, and structure of phthalocyanines. This book examines the biology and medical implications of porphyrin systems. Organized into five chapters, this volume begins with an overview of the basic photobiology of phthalocyanines, their structure-activity relationships, mechanisms of action in a variety of biological systems, and their potential applications for various medical purposes. This text then examines the type of organization of the molecules in the solid state and the intensity of the intermolecular interactions. Other chapters consider the applications of phthalocyanines as decorative and functional materials, with emphasis on properties and structures of phthalocyanines with industrial relevance. This book discusses as well the enzyme-like catalytic functions of metal complexes derivatives and their practical applications as odor-removing systems and bacterial systems based on their effective catalytic activities. This book is a valuable resource for research scientists, engineers, and clinicians.
| Author | : D.H.R. Barton |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 503 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 1461530008 |
This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract form are invited to communicate directly with the authors of the abstracts. This is the fifth international symposium that has been held on this subject. The first was hosted by the CNRS, May 21-29, 1979, in Bendor, France (on the Island of Bandol). The second meeting was organized as a NATO workshop in Padova, Italy, June 24-27, 1984. This was followed by a meeting in Tsukuba, Japan, July 12-16, 1987. The fourth symposium was held at Balatonfured, Hungary, September 10-14, 1990. The sixth meeting is scheduled to take place in Delft, The Netherlands (late Spring, 1996); the organizer and host will be Professor R. A. Sheldon.
| Author | : Francesc X. Llabrés i Xamena |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 446 |
| Release | : 2013-07-01 |
| Genre | : Science |
| ISBN | : 1849735727 |
This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.
| Author | : B. Meunier |
| Publisher | : Springer |
| Total Pages | : 327 |
| Release | : 2003-09-04 |
| Genre | : Science |
| ISBN | : 3540465928 |
This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world’s renowned experts.
| Author | : Bernard Meunier |
| Publisher | : World Scientific |
| Total Pages | : 697 |
| Release | : 2000-03-08 |
| Genre | : Science |
| ISBN | : 1783262389 |
Since the classic work Metal-Catalyzed Oxidations of Organic Compounds (edited by R A Sheldon and J K Kochi, 1991), no book has been devoted to advances in the field of biomimetic oxidations, which was created nearly 18 years ago. This expanding research field is covered in this volume. All the different aspects of the modeling of oxidations catalyzed by metalloenzymes are dealt with.This invaluable book will be useful to postgraduates as well as researchers in academia and industry, and will also benefit second year university students.
| Author | : Jose M Palomo |
| Publisher | : World Scientific |
| Total Pages | : 350 |
| Release | : 2021-03-15 |
| Genre | : Science |
| ISBN | : 1786349639 |
Iron Catalysis: Design and Applications is an exciting new book that takes readers inside the world of iron catalysis guided by international catalysis expert, Dr Jose M Palomo. Iron is the most abundant metal in the planet, cost-effective, environmentally friendly, with an easily manipulated remediation process. In the last few years the use of this nonprecious metal has gained extraordinary attention particularly for its potential as a catalyst in different areas. This book compiles a series of chapters describing the most significant advances in the last few years since the design of different iron catalysts and nanocatalysts and iron-containing artificial and natural enzymes. The chapters also cover its application in different areas of interest such as organic synthesis, environmental remediation, enzyme-like activities or the creation of novel types of electrodes for battery design.
| Author | : A. B. P. Lever |
| Publisher | : Wiley-VCH |
| Total Pages | : 322 |
| Release | : 1989-03-31 |
| Genre | : Science |
| ISBN | : 9780471187158 |
Porphyrins play a vital role in many biological functions including oxygen transport, electron transfer and catalyzing the incorporation of oxygen into other molecules. This current survey discusses the use of modern physical techniques to probe porphyrin structure and function. The authors review the data available through a particular technique and show what can be learned therefrom about the (electronic) structure and function of biologically important porphyrins. The techniques include magnetic circular dichroism, X-ray absorption fine structure (EXAFS) and Mössbauer spectroscopies. All contributors are well known in their respective fields, enjoying world-wide reputation.
| Author | : Armando J. L. Pombeiro |
| Publisher | : John Wiley & Sons |
| Total Pages | : 680 |
| Release | : 2019-03-11 |
| Genre | : Science |
| ISBN | : 111937880X |
Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.
