Metal Catalysed Reactions In Ionic Liquids
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| Author | : Paul J. Dyson |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 255 |
| Release | : 2006-01-24 |
| Genre | : Science |
| ISBN | : 1402039158 |
Metal Catalysed Reactions in Ionic Liquids is the first non-edited book on the subject of metal catalyzed reactions in ionic liquids to cover the literature from its origins until early 2005. Following a general introduction to the field of biphasic/multiphasic catalysis, the book moves on to describe the synthesis, the functionalisation, and fundamental properties of ionic liquids relevant to catalysis. It then analyses the catalysed reactions according to their type, encompassing hydrogenation, hydroformylation, oxidation, C-C coupling reactions, metathesis, dimerisation, polymerisation and more. Trends, generalisations, advantages and disadvantages of ionic liquids for specific reaction types are also examined as well as specific processes such as supported ionic liquid phase catalysis, continuous processes using CO2 extraction and nanoparticle catalysis. Metal Catalysed Reactions in Ionic Liquids is of interest to those working in catalysis/green chemistry, in particular to advanced level undergraduate and graduate students and researchers in bi- or multiphasic catalysis using ionic liquids.
| Author | : Hieronim Maciejewski |
| Publisher | : MDPI |
| Total Pages | : 196 |
| Release | : 2021-08-30 |
| Genre | : Science |
| ISBN | : 3036512462 |
Due to their distinctive properties, ionic liquids have attracted the great and unflagging interest of researchers for over 30 years. This interest has been focused mainly on their use as a green alternative to volatile organic solvents. However, they often act not only as solvents but also as catalysts, catalyst immobilizers and initiators. Over 100 types of chemical reactions are known in which ionic liquids (ILs) were applied successfully. This Special Issue is aimed at showing the most recent advances and trends in the design, synthesis and characterization of catalysts based on ILs, as well as presenting their activity and application potential.
| Author | : Chris Hardacre |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 634 |
| Release | : 2014-04-01 |
| Genre | : Science |
| ISBN | : 1849736030 |
Although ionic liquids have only been studied in depth during the last decades, the field is now maturing to such a degree that the focus is on larger scale applications for use in real processes such as catalysis. Current information is scattered across the literature and Catalysis in Ionic Liquids provides a critical analysis of the research published to date on ionic solvents in all areas of the catalytic science. The book covers both catalyst synthesis using ionic liquids as solvents and green syntheses using both ionic liquids as well as mixtures of ionic liquids and carbon dioxide (as a subcritical and supercritical liquid), including enzymatic, homogeneous, and heterogeneous catalysis, electrocatalysis and organocatalysis. As well as the catalysis community, the book will also be of interest to postgraduates, postdoctoral workers and researchers in academia and industry working in organic synthesis, new materials synthesis, renewable sources of energy and electrochemistry. Written by leading experts in the field, this is the reference source to find about catalysis in ionic liquids.
| Author | : Alwar Ramani |
| Publisher | : |
| Total Pages | : 0 |
| Release | : 2019 |
| Genre | : Electronic books |
| ISBN | : |
With the invention of ionic liquids, synthetic chemistry reached a new arena towards the transition metal catalyzed reactions in the syntheses of fine, specialty, agricultural, commodity, fragrant chemicals and building blocks. Inside the ionic liquid matrix, the transition metal catalysts, when immobilized, offer a valuable solution in terms of heterogenization. This technology offers high level of recyclability without loss of activity and improves the turnover number with high selectivity. Synthetic chemists, chemical engineers and technologists continue their efforts to recover and recycle the transition metal catalysts through various methodologies to convert the processes cost effective. The processes that are reported in the literature reveals that the ionic liquids by virtue of their inertness coupled with ability to retain the catalytic materials provide an excellent solution in terms of high levels of recovery and recyclability. This chapter presents a short account on the recent development in the transition metal catalyzed reactions in ionic liquid systems where both the solvent and the catalyst were recycled and reused without any emission of volatile materials.
| Author | : Peter Wasserscheid |
| Publisher | : John Wiley & Sons |
| Total Pages | : 776 |
| Release | : 2008-06-25 |
| Genre | : Science |
| ISBN | : 3527621202 |
The second, completely revised and enlarged edition of what has become the standard reference work in this fascinating field brings together the latest developments, supplemented by numerous practical tips, providing those working in both research and industry with an indispensable source of information. New contributions have been added, to reflect the fact that industrial processes are already established, and ionic liquids are now commercially available. A must for everyone working in the field.
| Author | : Jairton Dupont |
| Publisher | : Springer |
| Total Pages | : 354 |
| Release | : 2015-07-13 |
| Genre | : Science |
| ISBN | : 3662478579 |
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal
| Author | : Dickson Ozokwelu |
| Publisher | : Elsevier |
| Total Pages | : 282 |
| Release | : 2017-03-20 |
| Genre | : Technology & Engineering |
| ISBN | : 0128020555 |
Novel Catalytic and Separation Process Based on Ionic Liquids presents the latest progress on the use of ionic liquids (ILs) in catalytic and separation processes. The book discusses the preparation of ILs, the characterization of IL catalysts by spectroscopic techniques, catalytic reactions over IL catalysts, separation science and technology of ILs, applications in biomass utilization, and synthesis of fine chemicals. Scientists, engineers, graduate students, managers, decision-makers, and others interested in ionic liquids will find this information very useful. The book can be used as a springboard for more advanced work in this area as it contains both theory and recent applications, research conducted, and developments in separation techniques and catalysis using ionic liquids. Presents new preparation and advanced characterization of ionic liquids catalysts Outlines catalytic reactions using ionic liquid, thus showing higher yields and selectivity Presents novel separation science and technology based on ionic liquids and non-thermal processes
| Author | : Jiro Tsuji |
| Publisher | : John Wiley & Sons |
| Total Pages | : 500 |
| Release | : 2002-08-16 |
| Genre | : Science |
| ISBN | : 9780471560272 |
Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
| Author | : Sanjay V. Malhotra |
| Publisher | : ACS Symposium |
| Total Pages | : 0 |
| Release | : 2007 |
| Genre | : Language Arts & Disciplines |
| ISBN | : 9780841274075 |
Ionic Liquids in Organic Synthesis brings together leading scientists who have made major contributions to the field of ionic liquids. This book assembles several new methodologies that are interdisciplinary by nature, discussing the unique properties of ionic liquids and the ways in which they induce significant solvent effects on a wide range of pf processes. Twenty-two chapters are included. Ionic Liquids in Organic Synthesis covers areas of rapid progress and industrial importance. Ionic liquids are emerging as novel replacements for volatile organic compounds traditionally used as industrial solvents this book will elaborate on this subject while also examining practical synthetic applications of ionic liquids. This field has been an important topic of research for scientists in both industry and academia over the past 30 years and continues to grow.
| Author | : Daniel Glossman-Mitnik |
| Publisher | : BoD – Books on Demand |
| Total Pages | : 260 |
| Release | : 2020-01-15 |
| Genre | : Science |
| ISBN | : 1789852811 |
Solvents and ionic liquids are ubiquitous within our whole life since ancient times and their effects are actually being studied through basic sciences like Chemistry, Physics and Biology as well as being researched by a large number of scientific disciplines.This book represents an attempt to present examples on the utility of old and new solvents and the effects they exercise on several fields of academic and industrial interest. The first section, Solvents, presents information on bio-solvents and their synthesis, industrial production and applications, about per and trichloroethylene air monitoring in dry cleaners in the city of Sfax (Tunsia) and on the synthesis of polyimides using molten benzoic acid as the solvent. The second section, Ionic Liquids, shows information about the synthesis, physicochemical characterization and exploration of antimicrobial activities of imidazolium ionic liquid-supported Schiff base and its transition metal complexes, the technology of heterogenization of transition metal catalysts towards the synthetic applications in an ionic liquid matrix, the progress in ionic liquids as reaction media, monomers, and additives in high-performance polymers, a pre-screening of ionic liquids as gas hydrate inhibitor via application of COSMO-RS for methane hydrate, the extraction of aromatic compounds from their mixtures with alkanes from ternary to quaternary (or higher) systems and a review on ionic liquids as environmental benign solvent for cellulose chemistry. The final section, Solvent Effects, displays interesting information on solvent effects on dye sensitizers derived from anthocyanidins for applications in photocatalysis, about the solvent effect on a model of SNAr reaction in conventional and non-conventional solvents, and on solvent effects in supramolecular systems.
