Low-valent Main Group Complexes and Their Transition Metal-like Reactivity
| Author | : Matthew M. D. Roy |
| Publisher | : |
| Total Pages | : 294 |
| Release | : 2019 |
| Genre | : Chemical bonds |
| ISBN | : |
Low Valent Main Group Complexes And Their Transition Metal Like Reactivity
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Reactivity of Low-Valent Group 14 Species Toward Main Group Element, Transition Metal and Lanthanide Compounds
| Author | : Xiaofei Sun |
| Publisher | : Cuvillier Verlag |
| Total Pages | : 259 |
| Release | : 2022-08-22 |
| Genre | : Science |
| ISBN | : 3736966628 |
Die Dissertation befasst sich mit der Anwendung von niedervalenten Gruppe-14-Verbindungen in metallorganischer Chemie und Hauptgruppenchemie. Ausgehend von mono- und divalenten Siliziumverbindungen wurde die analoge Siliziumverbindung des 2π-Hückel-aromatischen Verbindung dargestellt (Kapitel 3.1). Ein chirales Silen wurde synthetisiert und weitere Reaktivität mit unterschiedlichen kleinen Molekülen untersucht (Kapitel 3.2). Außerdem wurden bidentate Silylene als Liganden zur Stabilisierung von Seldenerdelementen, Erdalkalielementen und Gruppe-12-Metallen eingesetzt (Kapitel 3.3-3.4). Verschiedene Polyphosphide wurden aus reduzierenden Silylenen oder Plumbolen generiert (Kapitel 3.5-3.6). Die dianionischen Gruppe-14-Metallole, Silol, Germol und Plumbol wurden als Liganden für sandwichartige Lanthanidkomplexe eingesetzt und die magnetischen Eigenschaften der Er-Verbindung wurden untersucht (Kapitel 3.7-3.8).
Synthesis and Reactivity of Low Valent Transition Metal Alkoxides and Related Compounds
| Author | : Kathryn Mary Sanchez |
| Publisher | : |
| Total Pages | : 514 |
| Release | : 1988 |
| Genre | : Transition metal catalysts |
| ISBN | : |
Synthesis of Heterometallic Zinc-Gold and Lanthanide-Transition Metal Carbonyl Complexes and Reactivity Study of Pentaphosphaferrocene Towards Low-Valent Main Group Species
| Author | : Ravi Yadav |
| Publisher | : Cuvillier Verlag |
| Total Pages | : 170 |
| Release | : 2019-11-27 |
| Genre | : Science |
| ISBN | : 3736961235 |
The work reported in this thesis is divided into three parts. In the first part, the synthesis of Zn-Au heterometallic complexes is described by using bifunctional carboxy-phosphine ligands. The second part of this thesis focuses on redox reactions between divalent lanthanides (LnII) and transition metal (TM) carbonyl complexes for the synthesis of high nuclearity heterometallic complexes. The third and final part of this thesis focuses on reactivity studies of [Cp*Fe(Л5-P5)] with lowvalent main group compounds.
The Organometallic Chemistry of the Transition Metals
| Author | : Robert H. Crabtree |
| Publisher | : John Wiley & Sons |
| Total Pages | : 600 |
| Release | : 2005-06-14 |
| Genre | : Science |
| ISBN | : 0471718750 |
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
