Lignin Utilization Strategies

Lignin Utilization Strategies
Author: Chang Geun Yoo
Publisher:
Total Pages: 314
Release: 2021
Genre: Lignin
ISBN: 9780841298453

Emerging applications of lignin Lignin has great potential as a sustainable, renewable resource for aromatic molecules that can be used in downstream applications. However, its natural heterogeneity and complexity are substantial barriers to its efficient utilization. Industrial lignin, a byproduct from the pulping and biorefinery industries, is usually burned or directly discharged as waste. This work provides a comprehensive exploration of recent lignin utilization strategies with chapters written by experts from agricultural science and engineering, biotechnology, biology, catalysis, chemical engineering, chemistry, wood science, and other related fields.

Lignin Valorization

Lignin Valorization
Author: Gregg T. Beckham
Publisher: Royal Society of Chemistry
Total Pages: 544
Release: 2018-03-29
Genre: Science
ISBN: 1782625542

"Chapters will specifically focus on the production of fuels and chemicals from lignin."--Page [4] of cover.

Lignin-based Materials for Biomedical Applications

Lignin-based Materials for Biomedical Applications
Author: Patrícia Figueiredo
Publisher: Elsevier
Total Pages: 450
Release: 2021-07-26
Genre: Technology & Engineering
ISBN: 0128203048

Lignin-based Materials for Biomedical Applications: Preparation, Characterization, and Implementation explores the emerging area of lignin-based materials as a platform for advanced biomedical applications, guiding the reader from source through to implementation. The first part of the book introduces the basics of lignin, including extraction methods, chemical modifications, structure and composition, and properties that make lignin suitable for biomedical applications. In addition, structural characterization techniques are described in detail. The next chapters focus on the preparation of lignin-based materials for biomedical applications, presenting methodologies for lignin-based nanoparticles, hydrogels, aerogels, and nanofibers, and providing in-depth coverage of lignin-based materials with specific properties—including antioxidant properties, UV absorbing capability, antimicrobial properties, and colloidal particles with tailored properties—and applications, such as drug and gene delivery, and tissue engineering. Finally, future perspectives and possible new applications are considered. This is an essential reference for all those with an interest in lignin-based materials and their biomedical applications, including researchers and advanced students across bio-based polymers, polymer science, polymer chemistry, biomaterials, nanotechnology, materials science and engineering, drug delivery, and biomedical engineering, as well as industrial R&D and scientists involved with bio-based polymers, specifically for biomedical applications. - Unlocks the potential of lignin-based materials with advanced properties for cutting-edge applications in areas such as drug delivery, gene delivery and tissue engineering - Presents state-of-the-art methodologies used in the development of lignin-based nanoparticles, hydrogels, aerogels and nanofibers - Explains the fundamentals of lignin, including structure and composition, extraction and isolation methods, types and properties, chemical modifications, and characterization techniques

Biomass Utilization: Conversion Strategies

Biomass Utilization: Conversion Strategies
Author: Nhuan Phu Nghiem
Publisher: Springer Nature
Total Pages: 248
Release: 2022-08-20
Genre: Science
ISBN: 3031058356

This book focuses on the technologies developed for the conversion of all three biomass components, i.e. cellulose, hemicellulose and lignin, and their constituents, to fuels and high-value products. Both biochemical and thermochemical approaches are reviewed. Additionally, the developed technologies are described in detail and their potential applications as well as their commercial status are discussed. The early attempts to produce fuel ethanol from lignocellulosic biomass feedstock focused solely on the biological conversion of cellulose because the only organism that had been used successfully for commercial production of ethanol, i.e. Saccharomyces cerevisiae, could only ferment glucose, which was obtained from the hydrolysis of cellulose. Hemicellulose and lignin were considered as wastes in these processes and were normally removed in pretreatment processes to enhance enzymatic hydrolysis of the remaining cellulose. However, this approach was not economically feasible and as a result, the biorefinery concept was developed. In a biorefinery, in addition to ethanol, various higher-value products are produced from hemicellulose and lignin, which were previously not considered. Consequently, technologies were developed for the fractionation of biomass and conversion of hemicellulose and lignin to fuels and high-value products to improve the economic feasibility. Written and edited by a team of investigators with many years of experience in biomass processing research and development, this book is an informative resource for postgraduate students and researchers interested in biorefinery and biofuel technologies both in academia- and commercial laboratories.

Lignin Conversion Catalysis

Lignin Conversion Catalysis
Author: Chaofeng Zhang
Publisher: John Wiley & Sons
Total Pages: 468
Release: 2022-08-19
Genre: Science
ISBN: 3527835024

Lignin Conversion Catalysis Authoritative reference providing comprehensive knowledge on the lignin conversion process with recent developments of mechanisms and techniques Lignin Conversion Catalysis: Transformation to Aromatic Chemicals covers the strategy, catalysis, and mechanisms of cleaving lignin linkages to aromatic chemicals and crucially elaborates on the specifics of multiple original lignins. Sample topics covered in the work include: Lignin depolymerization, models, and techniques of various lignins by heterogeneous substrates (such as native lignins, Kraft lignins, and organosolv lignins) Cleavage methods for lignins (such as oxidation and hydrogenation) as well as their main products (such as arenes, phenol, and acid) Relationships among the strategy/method, catalyst, and mechanism when viewed from the cleavage order and the type of corresponding chemical bonds Commercial components of lignin, a globally available raw material with many applications in drug design, polymers, and more Organic chemists, polymer chemists, and chemical engineers can use the valuable information contained in Lignin Conversion Catalysis: Transformation to Aromatic Chemicals to get up to date on this new raw material and understand the various developments that have been made in the field to make it viable for industrial purposes.

Chemical Modification, Properties, and Usage of Lignin

Chemical Modification, Properties, and Usage of Lignin
Author: Thomas Q. Hu
Publisher: Springer Science & Business Media
Total Pages: 292
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 1461506433

One of the most significant challenges facing mankind in the twenty-first century is the development of a sustainable global economy. Within the scientific community, this calls for the development of processes and technologies that will allow the sustainable production of materials from renewable natural resources. Plant material, in particular lignin, is one such resource. During the annual production of about 100 million metric tons of chemical wood pulps worldwide, approximately 45 and 2 million metric tons/year of kraft lignin and lignosulfonates, respectively, are also generated. Although lignosulfonates have found many applications outside the pulp and paper industry, the majority of kraft lignin is being used internally as a low-grade fuel for the kraft pulping operation. A surplus of kraft lignin will become available as kraft mills increase their pulp production without expanding the capacity of their recovery boilers that utilize lignin as a fuel. There is a tremendous opportunity and an enormous economic incentive to find better uses of kraft lignin, lignosulfonates and other industriallignins. The pulp and paper industry not only produces an enormous amount of lignins as by products of chemical wood pulps, but it also utilizes about 10 million metric tons of lignin per year as a component of mechanical wood pulps and papers. Mechanical wood pulps, produced in a yield of 90-98% with the retention of lignin, are mainly used to make low-quality, non-permanent papers such as newsprint and telephone directories because of the light-induced photooxidation of lignin and the yellowing of the papers.

Chemical Catalysts for Biomass Upgrading

Chemical Catalysts for Biomass Upgrading
Author: Mark Crocker
Publisher: John Wiley & Sons
Total Pages: 634
Release: 2020-03-09
Genre: Technology & Engineering
ISBN: 3527344667

A comprehensive reference to the use of innovative catalysts and processes to turn biomass into value-added chemicals Chemical Catalysts for Biomass Upgrading offers detailed descriptions of catalysts and catalytic processes employed in the synthesis of chemicals and fuels from the most abundant and important biomass types. The contributors?noted experts on the topic?focus on the application of catalysts to the pyrolysis of whole biomass and to the upgrading of bio-oils. The authors discuss catalytic approaches to the processing of biomass-derived oxygenates, as exemplified by sugars, via reactions such as reforming, hydrogenation, oxidation, and condensation reactions. Additionally, the book provides an overview of catalysts for lignin valorization via oxidative and reductive methods and considers the conversion of fats and oils to fuels and terminal olefins by means of esterification/transesterification, hydrodeoxygenation, and decarboxylation/decarbonylation processes. The authors also provide an overview of conversion processes based on terpenes and chitin, two emerging feedstocks with a rich chemistry, and summarize some of the emerging trends in the field. This important book: -Provides a comprehensive review of innovative catalysts, catalytic processes, and catalyst design -Offers a guide to one of the most promising ways to find useful alternatives for fossil fuel resources -Includes information on the most abundant and important types of biomass feedstocks -Examines fields such as catalytic cracking, pyrolysis, depolymerization, and many more Written for catalytic chemists, process engineers, environmental chemists, bioengineers, organic chemists, and polymer chemists, Chemical Catalysts for Biomass Upgrading presents deep insights on the most important aspects of biomass upgrading and their various types.

Handbook of Biomass Valorization for Industrial Applications

Handbook of Biomass Valorization for Industrial Applications
Author: Shahid ul-Islam
Publisher: John Wiley & Sons
Total Pages: 555
Release: 2022-01-05
Genre: Science
ISBN: 1119818796

HANDBOOK of BIOMASS VALORIZATION for INDUSTRIAL APPLICATIONS The handbook provides a comprehensive view of cutting-edge research on biomass valorization, from advanced fabrication methodologies through useful derived materials, to current and potential application sectors. Industrial sectors, such as food, textiles, petrochemicals and pharmaceuticals, generate massive amounts of waste each year, the disposal of which has become a major issue worldwide. As a result, implementing a circular economy that employs sustainable practices in waste management is critical for any industry. Moreover, fossil fuels, which are the primary sources of fuel in the transportation sector, are also being rapidly depleted at an alarming rate. Therefore, to combat these global issues without increasing our carbon footprint, we must look for renewable resources to produce chemicals and biomaterials. In that context, agricultural waste materials are gaining popularity as cost-effective and abundantly available alternatives to fossil resources for the production of a variety of value-added products, including renewable fuels, fuel components, and fuel additives. Handbook of Biomass Valorization for Industrial Applications investigates current and emerging feedstocks, as well as provides in-depth technical information on advanced catalytic processes and technologies that enable the development of all possible alternative energy sources. The 22 chapters of this book comprehensively cover the valorization of agricultural wastes and their various uses in value-added applications like energy, biofuels, fertilizers, and wastewater treatment. Audience The book is intended for a very broad audience working in the fields of materials sciences, chemical engineering, nanotechnology, energy, environment, chemistry, etc. This book will be an invaluable reference source for the libraries in universities and industrial institutions, government and independent institutes, individual research groups, and scientists working in the field of valorization of biomass.

Advancements in Biomass Recalcitrance: The Use of Lignin for the Production of Fuels and Chemicals

Advancements in Biomass Recalcitrance: The Use of Lignin for the Production of Fuels and Chemicals
Author: Arthur J. Ragauskas
Publisher: Frontiers Media SA
Total Pages: 103
Release: 2019-01-21
Genre:
ISBN: 2889457060

Lignocellulosic biomass has great potentials as an alternative feedstock for fuels and chemicals. For effective utilization of biomass, biomass recalcitrance, which is inherent resistance of plant cell walls to biological deconstruction, needs to be reduced. Among many factors in biomass, lignin is significantly related to biomass recalcitrance. Lignin, a complex aromatic polymer, is the largest non-carbohydrate component (15-40% dry weight) in most terrestrial plants. In nature, it provides a structural integrity, facilitates water and nutrient transport, and protects plants from microbial attack. From a different angle, lignin significantly contributes to biomass recalcitrance, so it is necessary to reduce and/or modify the lignin for effective conversion of biomass. Genetic modifications of the lignin biosynthetic pathway and lignin-targeting pretreatments have been developed to minimize the lignin-induced biomass recalcitrance. High carbon content of lignin also renders it an attractive feedstock for many applications. About 100,000 to 200,000 tons of lignin can be generated per year as a byproduct from cellulosic ethanol production, so valorization of these lignins could be one of keys for achieving economic biorefinery. However, investigations of lignin conversion have not been accomplished as the utilization of carbohydrates in biomass. Depolymerization of lignin is still challenging because of its broad distribution of bond strengths, recondensation of low-molecular species, and poor product selectivity. Diverse biological and thermochemical depolymerization methods have been investigated to overcome these barriers. In this Research Topic, recent advancements in biomass recalcitrance by effective utilization of lignin are introduced.

Lignin

Lignin
Author: Matheus Poletto
Publisher: BoD – Books on Demand
Total Pages: 310
Release: 2018-03-21
Genre: Science
ISBN: 9535139010

Lignin - Trends and Applications consists of 11 chapters related to the lignin structure, modification, depolymerization, degradation process, computational modeling, and applications. This is a useful book for readers from diverse areas, such as physics, chemistry, biology, materials science, and engineering. It is expected that this book may expand the reader's knowledge about this complex natural polymer.