Wetting and Wettability

Wetting and Wettability
Author: Mahmood Aliofkhazraei
Publisher: BoD – Books on Demand
Total Pages: 386
Release: 2015-12-16
Genre: Science
ISBN: 9535122150

On the liquid 's surface, the molecules have fewer neighbors in comparison with the bulk volume. As a result, the energy interaction shows itself in the surface tension. Traditionally, the surface tension can be assumed as a force in the unit of the length which can be counted by the unit of Newton on squared meter, or energy on the units of the surface. The surface tension, implies the interface between liquid and vapor, which is an example of the surface tensions. The equilibrium between these surface tensions, decides that a droplet on a solid surface, would have a droplet form or will change to layer form. This book collects new developments in wetting and wettability science.

Interfacial Phenomena in Coal Technology

Interfacial Phenomena in Coal Technology
Author: Gregory D. Botsaris
Publisher: CRC Press
Total Pages: 468
Release: 2022-09-16
Genre: Science
ISBN: 1000723399

A different face of coal than that seen by miners. Focusses on the conversion of coal to a liquid and the clean utilization of coal. Among topics discussed are surface phenomena involved in the beneficiation processes, flotation and spherical agglomeration, and the modification of coal-fluid interfaces.

TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies During Pulverized Coal Injection (PCI) at High Rates

TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies During Pulverized Coal Injection (PCI) at High Rates
Author:
Publisher:
Total Pages: 412
Release: 2005
Genre:
ISBN:

Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

Injectant Coal Gasification, Char Formation and Char Utilisation at High Injection Rates

Injectant Coal Gasification, Char Formation and Char Utilisation at High Injection Rates
Author: European Communities
Publisher:
Total Pages:
Release: 2004
Genre:
ISBN:

The aim of this project was to carry out an integrated laboratory, pilot and plant scale investigation of injectant coal gasification, char formation and properties, the effect of char on melting zone behaviour and the utilisation of char in terms of top gas dust carryover at high levels of injection. Laboratory-scale studies undertaken by Corus and Imperial College of Science, Technology and Medecine (ICSTM), focused on the degree of burnout of injectant coals, morphology and reactivity of resultant chars and an evaluation of the potential for the formation of soot precursors. Extents of gasification were related to parent coal properties and correlations between char morphology and parent coal VM content were established. The experiments also determined rates of particle mass loss under the variety of conditions that exist within the coal injection plume and made a significant contribution to the understanding of how and where volatiles are released and whether chars will be completely gasified. Centra Sviluppo Materiali (CSM) concentrated on the influence of char particles on the rheological properties of the ferrous materials in the blast furnace burden. Laboratory-scale tests under simulated blast furnace conditions on mixtures of ferrous burden, coke and char were conducted in the SMEDRA (Softening MElting DRipping Apparatus). The presence of char in the ferrous materials caused changes to the extent of initial dripping and to the starting temperature of this phenomenon. These changes correlated to the amount of char added and to the characteristics of the parent coal (the VM content and whether pulverised or granular grade) and would affect the position and the shape of the melting zone in the blast furnace. At the plant scale , ThyssenKrupp Stahl sampled blast furnaces operating with coal injection and characterised the dust collected. Tests were carried out based on the knowledge that increased graphitisation of carbon occurs with rising temperature, allowing the source of the carbon to be identified. With a new analytical method, Microwave-Assisted Dissolution, it was possible to exactly quantify the smallest quantities of graphite in top gas dust. The amount of dust discharged through the furnace top was largely determined by the percentage of non-carbonaceous components, but a clear correlation between the quantity of discharged dust and the quantity of carbonaceous components was also found. The findings also indicated that the carbon in the dust from the centre of the furnace comes mainly from ungasified injectant coal char.

An Investigation of the Structure and Reactivity of Coals for Injection During Blast Furnace Ironmaking

An Investigation of the Structure and Reactivity of Coals for Injection During Blast Furnace Ironmaking
Author: Jonathan Chen
Publisher:
Total Pages: 158
Release: 2006
Genre:
ISBN: 9780494213001

For more efficient combustion of coal an understanding of the physical and chemical properties of char is required. In this study the effects of pyrolysis conditions on the chemical and physical properties of several North American coals were examined. Chars were prepared in conditions similar to those experienced in the blast furnace during pulverized coal injection. Amorphous fraction and average crystallite height were determined using a quantitative X-ray diffraction technique. Chemical reactivity was measured in terms of intrinsic reactivity. It can be concluded that coals most suitable for pulverized injection in the blast furnace will possess a specific chemical/physical profile as represented by the following parameters: a high and stable amorphous fraction of carbon during pyrolysis and a high reactivity. The effects of a chemical enhancer containing copper sulfate and boric acid were also examined and it is suggested that this addition lowered the ignition temperature and accelerated coal pyrolysis.

Coal Combustion Under Conditions of Blast Furnace Injection. [Quarterly] Technical Report, 1 March 1993--31 May 1993

Coal Combustion Under Conditions of Blast Furnace Injection. [Quarterly] Technical Report, 1 March 1993--31 May 1993
Author:
Publisher:
Total Pages: 16
Release: 1993
Genre:
ISBN:

A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. The basic program is designed to determine the reactivity of both coal and its derived char under blast furnace conditions and to compare the results to similar properties of blast furnace coke. The results of the first two experiments in which coal char pyrolyzed in nitrogen at 1000°C in an EPR were reacted isothermally in air at 1000°C and 1200°C. The reactivity values of the same char in these two experiments were different by an order of magnitude. The char reactivity at 1000°C was 9.7 x 10−4 grams per minute while the reactivity. of the char at 1200°C was 1.6 x 10−3 grams per minute. These results suggest that the temperature of the blast air in the tuyere may be critical in achieving complete carbon burnout.