Influence of the Borane Reagent Structure on Catalytic Synthesis of Organoboranes
| Author | : Henrik Gulyás |
| Publisher | : |
| Total Pages | : 0 |
| Release | : 2011 |
| Genre | : Boron compounds |
| ISBN | : 9781612093406 |
Influence Of The Borane Reagent Structure On Catalytic Synthesis Of Organoboranes
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Synthesis and Application of Organoboron Compounds
| Author | : Elena Fernández |
| Publisher | : Springer |
| Total Pages | : 334 |
| Release | : 2015-03-04 |
| Genre | : Science |
| ISBN | : 3319130544 |
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Boron Reagents in Synthesis
| Author | : Adiel Coca |
| Publisher | : ACS Symposium |
| Total Pages | : 544 |
| Release | : 2018-02-02 |
| Genre | : Science |
| ISBN | : 9780841231832 |
Boron compounds have been used extensively in organic synthesis for more than sixty years. Some of the best known reactions in synthesis, such as the Suzuki-Miyaura cross-coupling and the hydroboration reaction, involve boron compounds. Several natural products containing boron have been isolated in the last fifty years, including ionophoric macrodiolide antibiotics boromycin, borophycin, aplasmomycins A, B, and C, and tartrolons B, C, and E, as well as autoinducer-2. The study of compounds containing boronic acids for application in pharmaceuticals and materials science has grown tremendously over the last few decades. These include bortezomib, ixazomib, and tavaborole. Several more boron-based drugs are currently in clinical trials. Boron neutron capture therapy has the potential to provide a treatment for various cancers. In addition, materials bearing boronic acids are been studied as potential sensors for biological molecules, such as saccharides and glycoproteins that possess cis-1,2- or cis-1,3-diols.
Hydroboration and Organic Synthesis
| Author | : Ranjit S. Dhillon |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 582 |
| Release | : 2007-05-01 |
| Genre | : Science |
| ISBN | : 3540490760 |
This book offers a systematic compilation of the vast data available to synthetic chemists. It provides easy access to the necessary information required for chemical transformations.
Boronic Acids
| Author | : Dennis G. Hall |
| Publisher | : John Wiley & Sons |
| Total Pages | : 571 |
| Release | : 2006-05-12 |
| Genre | : Science |
| ISBN | : 3527606823 |
For the first time, the whole field of organoboronic acids is presented in one comprehensive handbook. Professor Dennis Hall, a rising star within the community, covers all aspects of this important substance class, including applications in chemistry, biology and medicine. Starting with an introduction to the structure, properties, and preparation of boronic acid derivatives, together with an overview of their reactions and applications, the book goes on to look at metal-catalyzed borylation of alkanes and arenas, coupling reactions and rhodium-catalyzed additions of boronic acids to alkenes and carbonyl compounds. There follows chapters on copper-promoted C-O and C-N cross-coupling of boronic acids, recent applications in organic synthesis, as well as alpha-haloalkylboronic esters in asymmetric synthesis. Later sections deal with cycloadditions, organoboronic acids, oxazaborolidines as asymmetric inducers, and boronic acid based receptors and sensors. The whole is rounded off with experimental procedures, making this invaluable reading for organic, catalytic and medicinal chemists, as well as those working in organometallics.
Stereodirected Synthesis with Organoboranes
| Author | : Donald S. Matteson |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 417 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 3642797091 |
This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.
Frustrated Lewis Pairs II
| Author | : Gerhard Erker |
| Publisher | : Springer |
| Total Pages | : 321 |
| Release | : 2013-12-12 |
| Genre | : Science |
| ISBN | : 3642377599 |
Frustrated Lewis Pairs: From Dihydrogen Activation to Asymmetric Catalysis, by Dianjun Chen, Jürgen Klankermayer Coexistence of Lewis Acid and Base Functions: A Generalized View of the Frustrated Lewis Pair Concept with Novel Implications for Reactivity, by Heinz Berke, Yanfeng Jiang, Xianghua Yang, Chunfang Jiang, Subrata Chakraborty, Anne Landwehr New Organoboranes in "Frustrated Lewis Pair" Chemistry, by Zhenpin Lu, Hongyan Ye, Huadong Wang Paracyclophane Derivatives in Frustrated Lewis Pair Chemistry, by Lutz Greb, Jan Paradies Novel Al-Based FLP Systems, by Werner Uhl, Ernst-Ulrich Würthwein N-Heterocyclic Carbenes in FLP Chemistry, by Eugene L. Kolychev, Eileen Theuergarten, Matthias Tamm Carbon-Based Frustrated Lewis Pairs, by Shabana Khan, Manuel Alcarazo Selective C-H Activations Using Frustrated Lewis Pairs. Applications in Organic Synthesis, by Paul Knochel, Konstantin Karaghiosoff, Sophia Manolikakes FLP-Mediated Activations and Reductions of CO2 and CO, by Andrew E. Ashley, Dermot O’Hare Radical Frustrated Lewis Pairs, by Timothy H. Warren and Gerhard Erker Polymerization by Classical and Frustrated Lewis Pairs, by Eugene Y.-X. Chen Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems, by D. Wass Reactions of Phosphine-Boranes and Related Frustrated Lewis Pairs with Transition Metal Complexes, by Abderrahmane Amgoune, Ghenwa Bouhadir, Didier Bourissou
Organoboranes for Syntheses
| Author | : P. Veeraraghavan Ramachandran |
| Publisher | : |
| Total Pages | : 272 |
| Release | : 2001 |
| Genre | : Medical |
| ISBN | : |
This book examines the recent advances in the art of organic synthesis via organoboranes. The volume includes a wide range of topics in asymmetric synthesis, such as reduction, aldol reaction, allyboration, homologation, and cyclopropanation. Additional subjects include Suzuki coupling, amino acid synthesis, fluoro-organic synthesis, boron catalysts for stereoselective transformations, heterocyclic synthesis and novel borohydride reagents.
Advanced Organic Chemistry
| Author | : Francis A. Carey |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 1216 |
| Release | : 2007-06-27 |
| Genre | : Science |
| ISBN | : 0387448993 |
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.
