In realistic reactor scenarios, high temperature plasmas will be composed of not only the fusion reactants and products, but also impurities introduced purposefully or unintentionally from plasma facing materials. In tokamaks it is often assumed, sometimes erroneously, that surfaces of constant main ion pressure are also surfaces of constant impurity pressure. Although the same underlying physics determine impurity momentum balance along closed magnetic field lines, the increased mass and charge of high-Z impurities weights terms differently. Their large mass enhances inertial effects like the centrifugal force from toroidal rotation, and( can lead to accumulation of heavy impurities on the outboard side of a flux surface. Their high charge enhances ion-impurity friction and makes impurities sensitive to small poloidal variations in the electrostatic potential. In Alcator C-Mod, 2D (R,Z) measurements of photon emission from high-Z impurities reveal significant variations of impurity density on a flux surface. Poloidal variations, normalized to the flux surface average, I 2/(n ) , have been measured up to ~ 1/3, and separate cases of impurities accumulating on the inboard and outboard side of a flux surface are observed, depending on local plasmas conditions. Experiments demonstrate that these asymmetries are due to a combination of inertia., poloidal electric fields and ion-impurity friction, and measurements are compared to existing neoclassical parallel impurity transport theory. This is the first time centrifugal force has been observed to cause a substantial asymmetry in a plasma with no external momentum input and where the flow is entirely self-generated. Magnetically trapped fast ions, sustained by ion cyclotron waves, create a poloidally varying electrostatic potential which causes high-Z impurities to accumulate on the inboard side. Existing theory is extended to include this effect by incorporating a species that has an anisotropic pressure tensor. Experimental measurements in plasmas where the minority resonance layer is scanned show good qualitative and quantitative agreement with this extended theory. The sensitivity of 51/(nz) to fast-ions demonstrates the opportunity for the impurity asymmetry to be used as a novel diagnostic tool and calls into question prior work on in/out asymmetries in neutral beam heated plasmas. /down asymmetries in the banana regime are unable to be explained by ion/impurity friction in the trace limit, nZZ 2 /n