Homolytic Aromatic Substitution

Homolytic Aromatic Substitution
Author: G. H. Williams
Publisher: Elsevier
Total Pages: 142
Release: 2014-04-08
Genre: Science
ISBN: 1483151131

Homolytic Aromatic Substitution deals with the theoretical aspects of homolytic aromatic substitution reactions. The effect of various kinds of free radicals on the substitution of atoms or groups (usually hydrogen) attached to aromatic nuclei is examined, and the preparative use of homolytic substitution reactions is also considered. This book is comprised of seven chapters and begins with an introduction to the general characteristics of homolysis, along with homolytic and heterolytic aromatic substitution. The discussion then turns to the various theoretical approaches used to rationalize aromatic substitution, particularly those that are germane to a consideration of the problems of orientation and reactivity in homolytic substitution. The following chapters explore homolytic arylation reactions, including those between aryl radicals and aromatic substrates; relative rates of arylation and partial rate factors for phenylation; the reaction mechanism underlying intramolecular arylation; and homolytic alkylation reactions. The final chapter deals with hydroxylation and some other substitution reactions such as benzoyloxylation, acetyloxylation, halogenation, amination and amidation, and mercuration. This monograph will be of interest to organic chemists.

Organic Chemistry

Organic Chemistry
Author: Marye Anne Fox
Publisher: Jones & Bartlett Learning
Total Pages: 1180
Release: 2004
Genre: Science
ISBN: 9780763721978

Accompanying CD-ROM ... "has been enhanced with updated animated illustrations to accompany the presentations [and] Chem3D files for helpful structure visualization."--Page 4 of cover.

Comprehensive Natural Products II

Comprehensive Natural Products II
Author:
Publisher: Elsevier
Total Pages: 7944
Release: 2010-03-05
Genre: Science
ISBN: 0080453821

This work presents a definitive interpretation of the current status of and future trends in natural products—a dynamic field at the intersection of chemistry and biology concerned with isolation, identification, structure elucidation, and chemical characteristics of naturally occurring compounds such as pheromones, carbohydrates, nucleic acids, and enzymes. With more than 1,800 color figures, Comprehensive Natural Products II features 100% new material and complements rather than replaces the original work (©1999). Reviews the accumulated efforts of chemical and biological research to understand living organisms and their distinctive effects on health and medicine Stimulates new ideas among the established natural products research community—which includes chemists, biochemists, biologists, botanists, and pharmacologists Informs and inspires students and newcomers to the field with accessible content in a range of delivery formats Includes 100% new content, with more than 6,000 figures (1/3 of these in color) and 40,000 references to the primary literature, for a thorough examination of the field Highlights new research and innovations concerning living organisms and their distinctive role in our understanding and improvement of human health, genomics, ecology/environment, and more Adds to the rich body of work that is the first edition, which will be available for the first time in a convenient online format giving researchers complete access to authoritative Natural Products content

Organic Chemistry

Organic Chemistry
Author: Jonathan Clayden
Publisher: Oxford University Press
Total Pages: 1261
Release: 2012-03-15
Genre: Science
ISBN: 0199270295

A first- and second-year undergraduate organic chemistry textbook, specifically geared to British and European courses and those offered in better schools in North America, this text emphasises throughout clarity and understanding.

Handbook of Free Radical Initiators

Handbook of Free Radical Initiators
Author: E. T. Denisov
Publisher: John Wiley & Sons
Total Pages: 903
Release: 2005-01-14
Genre: Science
ISBN: 0471281832

Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.

Basic Principles of Organic Chemistry

Basic Principles of Organic Chemistry
Author: John D. Roberts
Publisher:
Total Pages: 1596
Release: 1977
Genre: Chemistry, Organic
ISBN: 9780805383218

Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

Heterogeneous Catalysis

Heterogeneous Catalysis
Author: Georgiĭ Konstantinovich Boreskov
Publisher: Nova Publishers
Total Pages: 254
Release: 2003
Genre: Science
ISBN: 9781590338643

Table of contents

Diazo Chemistry

Diazo Chemistry
Author: Heinrich Zollinger
Publisher:
Total Pages: 552
Release: 1994
Genre: Aromatic compounds
ISBN:

Advanced Organic Chemistry: Reactions and Mechanisms

Advanced Organic Chemistry: Reactions and Mechanisms
Author: Singh, Maya Shankar
Publisher: Pearson Education India
Total Pages: 526
Release: 2004
Genre: Chemistry, Organic
ISBN: 9332500673

Advanced Organic Chemistry: Reactions and Mechanisms covers the four types of reactions — substitution, addition, elimination and rearrangement; the three types of reagents — nucleophiles, electrophiles and radicals; and the two effects — electroni