Heterogenous Photochemical Electron Transfer

Heterogenous Photochemical Electron Transfer
Author: Michael Gratzel
Publisher: CRC Press
Total Pages: 363
Release: 2018-01-18
Genre: Science
ISBN: 1351090100

The present monograph attempts to unify these diverse and exciting new developments within a common framework. First, the physical principles underlying heterogenous electron-transfer processes are outlined in a concise way and are compared to the homogeneous counterpart. This analysis includes the notion of the Fermi level in liquids and solids as well as the distribution of electronic energy levels in solids and liquids. A comparison is made between the salient kinetic features of homogeneous and heterogeneous electron transfer reactions. This establishes the basis for the subsequent treatment of the transduction of excitation energy and photo-initiated electron transfer in organized molecular assemblies, such as micelles, vesicles and monolayers. Transmembrane redox processes are critically reviewed. Particular attention is given to semiconductor electrodes and particles. This includes a discussion of quantum size effects, the nature of space charge layers as well as surface states and the dynamics of charge carrier-induced redox reactions at the semiconductor solution interface. These processes are of fundamental importance in such diverse fields as photochromism, electrochromic displays, electroreprography and photography, information storage, photocatalysis, photodegradation of paints, and solar energy conversion.

Photochemical Conversion and Storage of Solar Energy

Photochemical Conversion and Storage of Solar Energy
Author: E. PELIZZETTI
Publisher: Springer Science & Business Media
Total Pages: 652
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 9401133964

The book collects the lectures and the status reports delivered during the "Eighth International Conference on Photochemical Conversion and Storage of Solar Energy", IPS-8, held in Palermo (Italy) from 15th to 20th of July 1990. As usual, the main theme of the Conference was that of making the point about the trends and the developments of the studies related to the photochemical exploitation of solar energy and also to report the main lines of potential applications. Therefore the contributions reflect this point; they vary from those reporting basic and fundamental theories to those reporting cases of possible applications. For the sake of following the logical line which links each other the various contributions, we report the six areas in which the main theme of the conference was devided: (a) Electron and energy transfer in homogeneous and heterogeneous systems; (b) Photosynthesis: organized assemblies and biomimetic systems; (c) Photoelectrochemistry; (d) Photocatalysis: homogeneous and heterogeneous regime; (e) Environment: photochemical and photocatalytic processes; (f) Solar energy materials and photochemical engineering. It remains now to thank persons and institutions which made possible the organization of the Conference. The persons to thank are all the members of the International and National Organizing Committees and in particular Prof. A.Sclafani and Dr. L.Palmisano whose efforts were essential for the success of the Conference.

Nanostructured and Photoelectrochemical Systems for Solar Photon Conversion

Nanostructured and Photoelectrochemical Systems for Solar Photon Conversion
Author: Mary D. Archer
Publisher: Imperial College Press
Total Pages: 781
Release: 2008
Genre: Science
ISBN: 1848161549

In this book, expert authors describe advanced solar photon conversion approaches that promise highly efficient photovoltaic and photoelectrochemical cells with sophisticated architectures on the one hand, and plastic photovoltaic coatings that are inexpensive enough to be disposable on the other. Their leitmotifs include light-induced exciton generation, junction architectures that lead to efficient exciton dissociation, and charge collection by percolation through mesoscale phases. Photocatalysis is closely related to photoelectrochemistry, and the fundamentals of both disciplines are covered in this volume.

Solar Power And Fuels

Solar Power And Fuels
Author: James R. Bolton
Publisher: Elsevier
Total Pages: 271
Release: 2012-12-02
Genre: Technology & Engineering
ISBN: 0323158420

Solar Power and Fuels presents the proceedings of the First International Conference on the Photochemical Conversion and Storage of Solar Energy, held at the University of Western Ontario on August 24–28, 1976. This book explores the various possibilities for the photochemical conversion and storage of solar energy. Organized into eight chapters, this compilation of papers begins with an overview of the chemical utilization of solar energy through systems in which the quanta of radiation from the sun are utilized in atomic or molecular systems that undergo chemical changes. This text then examines the various ways in which biological/solar systems could be realized to varying degrees over the short and long term. Other chapters consider the electron-transfer processes in which excited states of molecules react with molecules. This book discusses as well the systems where the photochemical reaction occurs in the electrolyte. The final chapter deals with the intermittent availability of solar radiation. This book is a valuable resource for photochemists, photobiologists, and scientists.

Mineral-Water Interface Geochemistry

Mineral-Water Interface Geochemistry
Author: Michael F. Hochella
Publisher: Walter de Gruyter GmbH & Co KG
Total Pages: 620
Release: 2018-12-17
Genre: Science
ISBN: 1501509136

Volume 23 of Reviews in Mineralogy and accompanying MSA short course covers chemical reactions that take place at mineral-water interfaces. We believe that this book describes most of the important concepts and contributions that have driven mineral-water interface geochemistry to its present state. We begin in Chapter 1 with examples of the global importance of mineral-water interface reactions and a brief review of the contents of the entire book. Thereafter, we have divided the book into four sections, including atomistic approaches (Chapters 2- 3), adsorption (Chapters 4-8), precipitation and dissolution (Chapters 9-11), and oxidation-reduction reactions (Chapters 11-14).

Alternative Fuels and the Environment

Alternative Fuels and the Environment
Author: Frances S. Sterrett
Publisher: CRC Press
Total Pages: 290
Release: 1994-10-12
Genre: Science
ISBN: 9780873719780

Alternative Fuels and the Environment evaluates the timely issue of renewable, alternative resources to fossil fuels and nuclear energy, such as solar, anemoelectric, hydroelectric, and geothermal energy. These alternative power sources not only have the advantage of being renewable, but they are also economically attractive and have minimal adverse environmental impact, such as the waste emission of SO2, NOx, or greenhouse gases. This book analyzes the harnessing of the sun's energy by photochemical reactions, artificial photosynthesis, and photovoltaic electric power generation. It further discusses how hydrogen as fuel is produced by solar photoelectrolysis of water and how wind turbines generate electricity, while ocean thermal energy produces electric power and fresh water. Geothermal energy and hydroelectric power are also renewable sources of electricity. Biofuels and biomass are useful as energy sources, and surplus land is usable for woody, herbaceous, high-yield energy crop production. The book also investigates reformulated gasoline with oxygenated fuels, such as ethanol or methanol.

Comprehensive Coordination Chemistry II

Comprehensive Coordination Chemistry II
Author: J. A. McCleverty
Publisher: Newnes
Total Pages: 11845
Release: 2003-12-03
Genre: Science
ISBN: 0080913164

Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Photochemistry

Photochemistry
Author: D Bryce-Smith
Publisher: Royal Society of Chemistry
Total Pages: 606
Release: 2007-10-31
Genre: Science
ISBN: 1847554687

The breadth of scientific and technological interests in the general topic of photochemistry is truly enormous and includes, for example, such diverse areas as microelectronics, atmospheric chemistry, organic synthesis, non-conventional photoimaging, photosynthesis, solar energy conversion, polymer technologies, and spectroscopy. This Specialist Periodical Report on Photochemistry aims to provide an annual review of photo-induced processes that have relevance to the above wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology. In order to provide easy access to this vast and varied literature, each volume of Photochemistry comprises sections concerned with photophysical processes in condensed phases, organic aspects which are sub-divided by chromophore type, polymer photochemistry, and photochemical aspects of solar energy conversion. Volume 34 covers literature published from July 2001 to June 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.