Hansen Solubility Parameters
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Author | : Charles M. Hansen |
Publisher | : CRC Press |
Total Pages | : 546 |
Release | : 2007-06-15 |
Genre | : Science |
ISBN | : 1420006835 |
Hansen solubility parameters (HSPs) are used to predict molecular affinities, solubility, and solubility-related phenomena. Revised and updated throughout, Hansen Solubility Parameters: A User's Handbook, Second Edition features the three Hansen solubility parameters for over 1200 chemicals and correlations for over 400 materials including p
Author | : Charles M. Hansen |
Publisher | : CRC Press |
Total Pages | : 224 |
Release | : 2002-01-01 |
Genre | : Science |
ISBN | : 9781420049312 |
Charles Hansen began his work with solvents in 1962, and almost immediately began producing new and groundbreaking results. Since then, his Hansen Solubility Parameters have been extensively used and proven valuable to a variety of industries, including coatings, adhesives, plastics, protective clothing, and environmental protection. They allow correlations and systematic comparisons previously not possible, such as polymer solubility, swelling and permeation, surface wetting and dewetting, the solubility of organic salts, and many biological applications. Until now, however, their seemingly universal ability to predict molecular affinities has been generally taken as semiempirical. Moving beyond the Hildebrand and Flory theories, Hansen found that his approach not only quantitatively describes hydrogen bonding and polar bonding in many types of systems, but in fact agrees with and extends the very general Prigogine theory. This explains why the correlations all seem to fit with an apparently "universal" 4: it results from the validity of applying the geometric mean rule to describe dispersion, permanent dipole-permanent dipole, and hydrogen bonding interaction in mixtures of unlike molecules. Hansen Solubility Parameters provides new tables of previously unpublished correlations and parameters. The author illuminates his text with practical examples related to coatings, biological systems, pigments, and fibers, and takes a general approach that makes this reference ideal for predicting compatibility, adsorption on surfaces, orientation toward materials of similar affinities (self-assembly), and other phenomena associated with solubility and affinity. Chemists, chemical engineers, and biochemists will find this book-the collected work and experience of the father of its concept-intriguing for its theory and invaluable for its data.
Author | : Charles M. Hansen |
Publisher | : CRC Press |
Total Pages | : 0 |
Release | : 2007-06-15 |
Genre | : Science |
ISBN | : 9780849372483 |
Hansen solubility parameters (HSPs) are used to predict molecular affinities, solubility, and solubility-related phenomena. Revised and updated throughout, Hansen Solubility Parameters: A User's Handbook, Second Edition features the three Hansen solubility parameters for over 1200 chemicals and correlations for over 400 materials including polymers, inorganic salts, and biological materials. To update his groundbreaking handbook with the latest advances and perspectives, Charles M. Hansen has invited five renowned experts to share their work, theories, and practical applications involving HSPs. New discussions include a new statistical thermodynamics approach for confirming existing HSPs and how they fit into other thermodynamic theories for polymer solutions. Entirely new chapters examine the prediction of environmental stress cracking as well as absorption and diffusion in polymers. Highlighting recent findings on interactions with DNA, the treatment of biological materials also includes skin tissue, proteins, natural fibers, and cholesterol. The book also covers the latest applications of HSPs, such as ozone-safe “designer” solvents, protective clothing, drug delivery systems, and petroleum applications. Presenting a comprehensive survey of the theoretical and practical aspects of HSPs, Hansen Solubility Parameters, Second Edition concludes with a detailed discussion on the necessary research, future directions, and potential applications for which HSPs can provide a useful means of prediction in areas such as biological materials, controlled release applications, nanotechnology, and self-assembly.
Author | : Allan F.M. Barton |
Publisher | : CRC Press |
Total Pages | : 774 |
Release | : 1991-10-29 |
Genre | : Science |
ISBN | : 9780849301766 |
The CRC Handbook of Solubility Parameters and Other Cohesion Parameters, Second Edition, which includes 17 new sections and 40 new data tables, incorporates information from a vast amount of material published over the last ten years. The volume is based on a bibliography of 2,900 reports, including 1,200 new citations. The detailed, careful construction of the handbook develops the concept of solubility parameters from empirical, thermodynamic, and molecular points of view and demonstrates their application to liquid, gas, solid, and polymer systems.
Author | : |
Publisher | : Hansen-Solubility |
Total Pages | : 115 |
Release | : |
Genre | : |
ISBN | : 0955122023 |
Author | : John Durkee |
Publisher | : William Andrew |
Total Pages | : 779 |
Release | : 2013-11-29 |
Genre | : Science |
ISBN | : 1455731617 |
High-precision cleaning is required across a wide range of sectors, including aerospace, defense, medical device manufacturing, pharmaceutical processing, semiconductor/electronics, etc. Cleaning parts and surfaces with solvents is simple, effective and low-cost. Although health and safety and environmental concerns come into play with the use of solvents, this book explores how safe and compliant solvent-based cleaning techniques can be implemented. A key to this is the selection of the right solvent. The author also examines a range of newer "green" solvent cleaning options. This book supplies scientific fundamentals and practical guidance supported by real-world examples. Durkee explains the three principal methods of solvent selection: matching of solubility parameters, reduction of potential for smog formation, and matching of physical properties. He also provides guidance on the safe use of aerosols, wipe-cleaning techniques, solvent stabilization, economics, and many other topics. A compendium of blend rules is included, covering the physical, chemical, and environmental properties of solvents. - Three methods explained in detail for substitution of suitable solvents for those unsuitable for any reason: toxic solvents don't have to be tolerated; this volume explains how to do better - Enables users to make informed judgments about their selection of cleaning solvents for specific applications, including solvent replacement decisions - Explains how to plan and implement solvent cleaning systems that are effective, economical and compliant with regulations
Author | : Joel Henry Hildebrand |
Publisher | : |
Total Pages | : 488 |
Release | : 1964 |
Genre | : Solubility |
ISBN | : |
Author | : Richard G. Weiss |
Publisher | : Springer Science & Business Media |
Total Pages | : 969 |
Release | : 2006-06-30 |
Genre | : Science |
ISBN | : 1402036892 |
"Molecular Gels: Materials with Self-Assembled Fibrillar Networks" is a comprehensive treatise on gelators, especially low molecular-mass gelators and the properties of their gels. The structures and modes of formation of the self-assembled fibrillar networks (SAFINs) that immobilize the liquid components of the gels are discussed experimentally and theoretically. The spectroscopic, rheological, and structural features of the different classes of low molecular-mass gelators are also presented. Many examples of the application of the principal analytical techniques for investigation of molecular gels (including SANS, SAXS, WAXS, UV-vis absorption, fluorescence and CD spectroscopies, scanning electron, transmission electron and optical microscopies, and molecular modeling) are presented didactically and in-depth, as are several of the theories of the stages of aggregation of individual low molecular-mass gelator molecules leading to SAFINs. Several actual and potential applications of molecular gels in disparate fields (from silicate replication of nanostructures to art conservation) are described. Special emphasis is placed on perspectives for future developments. This book is an invaluable resource for researchers and practitioners either already researching self-assembly and soft matter or new to the area. Those who will find the book useful include chemists, engineers, spectroscopists, physicists, biologists, theoreticians, and materials scientists.
Author | : Abolghasem Jouyban |
Publisher | : CRC Press |
Total Pages | : 554 |
Release | : 2009-08-26 |
Genre | : Medical |
ISBN | : 1439804885 |
Aqueous solubility is one of the major challenges in the early stages of drug discovery. One of the most common and effective methods for enhancing solubility is the addition of an organic solvent to the aqueous solution. Along with an introduction to cosolvency models, the Handbook of Solubility Data for Pharmaceuticals provides an extensive datab
Author | : Dusan Stulik |
Publisher | : Getty Publications |
Total Pages | : 184 |
Release | : 2004 |
Genre | : Art |
ISBN | : 9780892367597 |
The cleaning of a work of art often involves removing not only dirt and grime but also unwanted layers of varnish, gilding, and paint from the work's surface. The challenge for conservators lies in finding a cleaning agent that will act on one layer without affecting the layer being preserved and without leaving any harmful residues on the cleaned work. This book, which examines gel cleaning in the treatment of paintings and painted works of art, presents the methodologies, data, and results of a collaborative project of the Getty Conservation Institute and Winterthur Museum. Among the issues covered are the theory and application of gel cleaning systems, the detection of residues left on the surfaces of objects cleaned with these systems, research into solvent-gel and solvent residues, stability of surfactants during natural and artificial aging, and recommendations for formulating gels for specific cleaning tasks.