GABCOM & GABMET

GABCOM & GABMET
Author: Gmelin Institut
Publisher: Springer Science & Business Media
Total Pages: 724
Release: 1993-07-02
Genre: Science
ISBN: 9783540936534

The scientific literature in chemistry and physics abounds with abbreviations of chemical compounds, physical methods and mathematical procedures. Unfortunately, many authors take it for granted that the reader knows the meaning of an abbreviation, something quite trivial for a specialist. For the less informed reader, these abbreviations thus present definite communication problems. The Gmelin Institute of Inorganic Chemistry of the Max Planck Society has collected more than 4000 abbreviations for methods and terms from chemistry, physics and mathematics and more than 4000 chemical compounds (mostly ligands in coordination chemistry and standard reagents for physical and analytical methods). GABCOM and GABMET provide an overview enabling readers and authors to check the definition of an abbreviation used by an author and to see whether this abbreviation is already being used for other purposes. GABCOM and GABMET are also in preparation in electronic form (data file and search software) for IBM-PC or compatible computers.

Gabcom & Gabmet

Gabcom & Gabmet
Author: Gmelin Institut
Publisher: Springer Verlag
Total Pages: 381
Release: 1993-01-01
Genre: Science
ISBN: 9780387936536

In der chemischen und physikalischen Fachliteratur werden hdufig Abk]rzungen f]r chemische Verbindungen sowie f]r Arbeitsmethoden, mathematische Rechenverfahren u.a. verwendet. Leider ist es eine verbreitete Arbeitsweise, da_ die Autoren als Spezialisten die f]r sie triviale Kenntnis dieser Abk]rzungen voraussetzen. F]r den nicht spezialisierten Leser bereiten diese Abk]rzungen daher gewisse Verstdndnisprobleme. Das Gmelin-Institut f]r Anorganische Chemie der Max-Planck-Gesellschaft hat aus der Literatur des Zeitraums 1950-1990 eine Sammlung solcher Abk]rzungen erarbeitet. Im vorliegenden Buch sind mehr als 4000 Abk]rzungen f]r Methoden und Begriffe aus Chemie, Physik und Mathematik und ]ber 4000 Abk]rzungen f]r chemische Verbindungen (insbesondere Komplexbildner und Standard-Substanzen physikalischer Me_methoden) zusammengestellt. Mit GABCOM und GABMET kvnnen Leser und Autoren feststellen, was mit einer speziellen Abk]rzung gemeint ist, bzw. ob die von ihnen gewdhlte Abk]rzung nicht schon f]r andere Verfahren oder Verbindungen benutzt wird. GABCOM und GABMET sind auch in elektronisch lesbarer Form (Daten und Suchoberfldche) f]r IBM-PCs oder kompatible Rechner in Vorbereitung.

Compounds with Noble Gases, H, O, N, F, and Cl

Compounds with Noble Gases, H, O, N, F, and Cl
Author: Gertrud Hönes
Publisher: Springer
Total Pages: 0
Release: 1992-12-04
Genre: Science
ISBN: 9783540936558

The volume covers the interactions and compounds of gold with noble gases, hydrogen, oxygen, nitrogen, fluorine, and chlorine. Along with the expanding use of gold in recent years, for example in electronics and in aerospace equipment, there has been an impressive series of advances in the chemistry of gold compounds and of discoveries of unusual oxidation states. Hydrogen forms a nonstoichiometric solid phase, AuHn at high pressures with a maximum value of n=0.43. Hydrides such as AuH exist only in the gaseous state. The predominant oxide is that of gold(III), Au2O3. The lower-valent oxides Au2O and AuO form during anodic oxidation of gold. There still is no evidence for definite gold(I) and gold(II) fluorides, whereas AuF3 is stable below 500oC, while it is immediately decomposed by water. The first pentavalent gold compound, (Xe2F11)AuF6, was synthesized in the early 1970's. Later, a number of new Auv compounds were prepared, among them AuF5. The highest oxidation state of gold ever realized is +7 in the recently synthesized AuF7. The major portion of this volume deals with gold chlorine-compounds. Solid AuCl has a polymeric structure with Au and Cl atoms forming zigzag chains, while the gaseous compound consists of dimeric Au2Cl2 molecules. AuCl2, which was first thought to be a compound of gold(II), actually is a mixed-valence gold(I)-gold(III) compound with the net formula Au4Cl8. The crystal structure of AuCl3 comprises discrete, planar Au2Cl6 molecules. The most important water-soluble gold compounds are the tetrachloroauric acid, HAuCl4, and its sodium and potassium salts, easy to obtain by dissolution of gold in aqua regia. They are used besides AuCl3 to prepare nearly all other gold compounds, mostly in solution via the tetrachloroaurate (III) ion ÄAuCl4Ü-.

Binary Species of Silicon and Fluorine

Binary Species of Silicon and Fluorine
Author: Friedrich Schröder
Publisher: Springer
Total Pages: 376
Release: 1992
Genre: Science
ISBN: 9783540936510

The volume is concerned exclusively with all the binary species formed between the elements silicon and fluorine such as SiF, SiF2, SiF3, SiF4, and Sif62-. Most of the volume, i.e. 144 pages, is devoted to the description of the well known physical and chemical properties of the SiF4 as well as to its preparation. This is followed in length by the report on SiF2 with its interesting chemistry, along with a section on the diatomic radical SiF. Species with fivefold and sixfold coordination of silicon are exemplified by SiF5- and by the well known SiF62-. Interestingly, the detailed models for describing the bonding situation in both ions are still a matter of discussion. While for Si2F6 most of the basic data are known, information on the chemical and physical properties of the higher members of the acylic perfluorosilanes, SinF2n+2, is scarce. All available information on the unstable cyclic perfluorosilanes of composition (SiF2)n and some even more exotic species is also included.