Fundamentals of Controlled/Living Radical Polymerization

Fundamentals of Controlled/Living Radical Polymerization
Author: Nicolay V Tsarevsky
Publisher: Royal Society of Chemistry
Total Pages: 379
Release: 2013-04-25
Genre: Science
ISBN: 1849737428

Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.

Controlled/living Radical Polymerization

Controlled/living Radical Polymerization
Author: Krzysztof Matyjaszewski
Publisher: Academic
Total Pages: 444
Release: 2009
Genre: Language Arts & Disciplines
ISBN:

Recent progress in the field of controlled/living radical polymerization.

Fundamentals of Controlled/living Radical Polymerization

Fundamentals of Controlled/living Radical Polymerization
Author: Nicolay V. Tsarevsky
Publisher: Royal Society of Chemistry
Total Pages: 379
Release: 2013
Genre: Science
ISBN: 1849734259

Provides an in-depth history, description, and mechanistic understanding of each of the controlled/living radical polymerization techniques and practical details necessary to carry out the reactions.

Handbook of Radical Polymerization

Handbook of Radical Polymerization
Author: Krzysztof Matyjaszewski
Publisher: John Wiley & Sons
Total Pages: 934
Release: 2003-04-14
Genre: Technology & Engineering
ISBN: 0471461571

Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.

Fundamentals of Polymerization

Fundamentals of Polymerization
Author: Broja Mohan Mandal
Publisher: World Scientific
Total Pages: 468
Release: 2013
Genre: Science
ISBN: 9814322466

Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.

Controlled/living Radical Polymerization

Controlled/living Radical Polymerization
Author: Krzysztof Matyjaszewski
Publisher:
Total Pages: 506
Release: 2000
Genre: Language Arts & Disciplines
ISBN:

This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Metal-Catalyzed Polymerization

Metal-Catalyzed Polymerization
Author: Samir Chikkali
Publisher: CRC Press
Total Pages: 188
Release: 2017-08-03
Genre: Science
ISBN: 1351649957

The proposed book focusses on metal mediated/catalyzed “controlled/living radical polymerization” (CRP/LRP) methods. It surveys a wide variety of catalyzed polymerization reactions, making it essentially a “one stop” review in the field. A significant contribution to polymer science is “metathesis polymerization” discovered by Grubbs and others. The book will cover various metathesis polymerization methods and implications in polymer industry.

Controlled/Living Radical Polymerization

Controlled/Living Radical Polymerization
Author: Krzysztof Matyjaszewski
Publisher: OUP USA
Total Pages: 0
Release: 2007-01-04
Genre: Science
ISBN: 9780841239913

The preparation and characterization of new materials with precisely controlled macromolecular dimensions, functionalities, and decomposition, as well as with well-defined topologies, is perhaps the main focus of contemporary polymer synthesis. The best control of molecular functions can be achieved in a controlled/living polymerization -- a chain growth process without chain breaking reactions. Recently, controlled/living polymerizations have extended to radical systems which are not only commercially important, but also have the largest potential due to the availability of radically polymerizable monomers, facile copolymerization and undemanding experimental conditions. Controlled Radical Polymerization will examine recent advances in mechanistic and synthetic aspects of controlled/living radical (co)polymerization systems. Not only will this book be focused on recent progress in the dynamically developing field of controlled/living radical polymerization, but it will be a sequel to the very popular ACS Symposium Series 685, 768, and 854. The book will consist of >30 chapters separated into seven subsections: Fundamentals, Mechanism of ATRP, Mechanisms of SFRP and Degenerative Transfer Processes, Controlled Architecture by CRP, Organic-inorganic Hybrids by CRP, Biomaterials by CRP and Industrial Applications. This book targets chemists and polymer scientists in academia and in industry.

Sequence-Controlled Polymers

Sequence-Controlled Polymers
Author: Jean-François Lutz
Publisher: John Wiley & Sons
Total Pages: 532
Release: 2018-04-09
Genre: Technology & Engineering
ISBN: 3527342370

Edited by a leading authority in the field, the first book on this important and emerging topic provides an overview of the latest trends in sequence-controlled polymers. Following a brief introduction, the book goes on to discuss various synthetic approaches to sequence-controlled polymers, including template polymerization, genetic engineering and solid-phase chemistry. Moreover, monomer sequence regulation in classical polymerization techniques such as step-growth polymerization, living ionic polymerizations and controlled radical polymerizations are explained, before concluding with a look at the future for sequence-controlled polymers. With its unique coverage of this interdisciplinary field, the text will prove invaluable to polymer and environmental chemists, as well as biochemists and bioengineers.

Monitoring Polymerization Reactions

Monitoring Polymerization Reactions
Author: Wayne F. Reed
Publisher: John Wiley & Sons
Total Pages: 493
Release: 2014-01-21
Genre: Technology & Engineering
ISBN: 0470917385

Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.