Functionalization of Polyolefins

Functionalization of Polyolefins
Author: T. C. Chung
Publisher: Academic Press
Total Pages: 296
Release: 2002-02-28
Genre: Science
ISBN: 9780121746513

Summarizes the significant experimental results on the functionalization of polyolefins and classifies them into several chemical methods. This book also provides information on the functional polyolefin materials. It covers: chemical approaches in the functionalization of polyolefins, and polyolefin materials and their potential applications.

Polyolefin Blends

Polyolefin Blends
Author: Domasius Nwabunma
Publisher: John Wiley & Sons
Total Pages: 689
Release: 2008-01-02
Genre: Technology & Engineering
ISBN: 0470198974

The definitive reference on the properties and applications of polyolefin blends Polyolefins account for more than half of total plastics consumption in the world. In recent years, usage of and research on polyolefin blends have increased significantly due to new applications in medicine, packaging, and other fields and the development of novel polyolefins. With a special emphasis on nano- and micro-structures of crystals and phase morphology, Polyolefin Blends condenses and consolidates current information on polyolefins so that the reader can compare, select, and integrate a material solution. Focusing exclusively on the fundamental aspects as well as applications of polyolefin blends, this authoritative reference: * Features an introductory chapter that serves as a guide to polyolefin blends * Includes chapters covering formulation design, processing, characterization, modeling and simulation, engineering performance properties, and applications * Covers polyolefin/polyolefin blends and polyolefin/non-polyolefin blends * Discusses miscibility, phase behavior, functionalization, compatibilization, microstructure, crystallization, hierarchical morphology, and physical and mechanical properties * Covers new research trends including in-situ reactor blending and reactive processing, such as compatibilization/functionalization in the melt * Contains practical examples from open literature sources and commercial products With chapters contributed by leading experts from several countries, this is a must-have reference for scientists and engineers conducting research on polyolefin blends and for professionals in medical, packaging, and other commodity fields. It is also an excellent text for graduate students studying polymer science and polymer processing.

Reactive Extrusion

Reactive Extrusion
Author: Günter Beyer
Publisher: John Wiley & Sons
Total Pages: 434
Release: 2018-01-03
Genre: Science
ISBN: 352734098X

This first comprehensive overview of reactive extrusion technology for over a decade combines the views of contributors from both academia and industry who share their experiences and highlight possible applications and markets. They also provide updated information on the underlying chemical and physical concepts, summarizing recent developments in terms of the material and machinery used. As a result, readers will find here a compilation of potential applications for reactive extrusion to access new and cost-effective polymeric materials, while using existing compounding machines.

Reactive Modifiers for Polymers

Reactive Modifiers for Polymers
Author: S. Al-Malaika
Publisher: Springer Science & Business Media
Total Pages: 416
Release: 2012-12-06
Genre: Science
ISBN: 9400914490

Chemical modification of polymers by reactive modifiers is no longer an academic curiosity but a commercial reality that has delivered a diverse range of speciality materials for niche markets: reactively grafted styrenic alloys, maleated polyolefins, super-tough nylons, silane modified and moisture-cured polyolefins, and thermoplastic elastomers, are but few exam ples of commercial successes. Although the approach of reactive modification of polymers has been largely achieved either in solution or in the solid state (through in situ reactions in polymer melts), it is the latter route that has attracted most attention in the last two decades owing to its flexibility and cost-effective ness. This route, referred to as reactive processing, focuses on the use of suitable reactive modifier(s) and the adoption of conventional polymer processing machinery, an extruder or a mixer, as a chemical reactor, to perform in situ targeted reactions for chemical modification of preformed polymers. This relatively simple, though scientifically highly challenging, approach to reactive modification offers unique opportunities in exploiting various reactive modifiers for the purpose of altering and transforming in a controlled manner the properties of preformed commercial polymers into new/speciality materials with tailor-made properties and custom-designed performance for target applications. Such an economically attractive route constitutes a radical diversion away from the traditional practices of manufacturing new polymers from monomers which involves massive in vestments in sophisticated technologies and chemical plants.

Introduction to Industrial Polypropylene

Introduction to Industrial Polypropylene
Author: Dennis B. Malpass
Publisher: John Wiley & Sons
Total Pages: 290
Release: 2012-07-02
Genre: Technology & Engineering
ISBN: 111846320X

This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output. The book considers the following topics: What are the principal types of polypropylene and how do they differ? What catalysts are used to produce polypropylene and how do they function? What is the role of cocatalysts and how have they evolved over the years? How are industrial polypropylene catalysts tested and the resultant polymer evaluated? What processes are used in the manufacture of polypropylene? What are the biopolymer alternatives to polypropylene? What companies are the major industrial manufacturers of polypropylene? What is the environmental fate of polypropylene?

Polymer Modification

Polymer Modification
Author: Graham G. Swift
Publisher: Springer Science & Business Media
Total Pages: 207
Release: 2013-06-29
Genre: Technology & Engineering
ISBN: 1489914773

Proceedings of an ACS-PMSE Division Symposium held in Orlando, Florida, August 21-25, 1996

Functional Polymers by Post-Polymerization Modification

Functional Polymers by Post-Polymerization Modification
Author: Patrick Theato
Publisher: John Wiley & Sons
Total Pages: 431
Release: 2013-02-12
Genre: Technology & Engineering
ISBN: 3527655441

In modern polymer science a variety of polymerization methods for the direct synthesis of polymers bearing functional groups are known. However, there is still a large number of functional groups that may either completely prevent polymerization or lead to side reactions. Post-polymerization modification, also known as polymer-analogous modification, is an alternative approach to overcome these limitations. It is based on the polymerization of monomers with functional groups that are inert towards the polymerization conditions but allow a quantitative conversion in a subsequent reaction step yielding a broad range of other functional groups. Thus, diverse libraries of functional polymers with identical average degrees of polymerization but variable side chain functionality may easily be generated. Filling the gap for a book dealing with synthetic strategies and recent developments, this volume provides a comprehensive and up-to-date overview of the field of post-polymerization modification. As such, the international team of expert authors covers a wide range of topics, including new synthetic techniques utilizing different reactive groups for post-polymerization modifications with examples ranging from modification of biomimetic and biological polymers to modification of surfaces. With its guidelines this is an indispensable and interdisciplinary reference for scientists working in both academic and industrial polymer research.

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites
Author: Sabu Thomas
Publisher: Elsevier
Total Pages: 578
Release: 2021-03-25
Genre: Technology & Engineering
ISBN: 0128213582

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. - Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends - Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material - Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications

Reactive and Functional Polymers Research Advances

Reactive and Functional Polymers Research Advances
Author: Matheus I. Barroso
Publisher: Nova Publishers
Total Pages: 298
Release: 2008
Genre: Science
ISBN: 9781600218620

Presents research on inorganic and organic functional polymers, both solid and liquid, acting as reagents, catalysts, carriers of protecting groups, templates, ion-exchangers, selective sorbents, chelating agents, supports for enzymes and cells, and the like. This book also covers reactive crosslinkable prepolymers, and degradable polymers.

Plasma Modification of Polyolefins

Plasma Modification of Polyolefins
Author: N. S. Baneesh
Publisher: Springer Nature
Total Pages: 262
Release: 2021-11-22
Genre: Technology & Engineering
ISBN: 3030522644

This book addresses plasma modification of polyolefin surfaces. It comprises 21 chapters divided into three major sections. The first section covers the different techniques used for plasma modification of polyolefin surfaces and the effects of various gases as a surrounding medium, while the second provides a detailed analysis of the physics and chemistry of plasma modification and discusses various innovative characterization techniques, as well as ageing of the modified surface. It focuses on the analysis of changes in polymers’ surface chemistry using various spectroscopic techniques, and of changes in their surface morphology after plasma treatment using optical microscopy, electron microscopy and atomic force microscopy. In addition, it provides detailed information on the characterization of modified polymer surfaces. The book’s third and last section covers a range of applications of plasma-modified polyolefin surfaces varying from the packaging industry to the biomedical field, and shares valuable insights on the lifecycle analysis of plasma modification and modified surfaces.