Free Radical Chain Reactions In Organic Synthesis
Download Free Radical Chain Reactions In Organic Synthesis full books in PDF, epub, and Kindle. Read online free Free Radical Chain Reactions In Organic Synthesis ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Author | : |
Publisher | : Elsevier |
Total Pages | : 271 |
Release | : 2004-01-14 |
Genre | : Science |
ISBN | : 0080524257 |
Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature
Author | : Bernd Giese |
Publisher | : C R C Press Reprints |
Total Pages | : 316 |
Release | : 1986 |
Genre | : Science |
ISBN | : |
Author | : William B. Motherwell |
Publisher | : Elsevier |
Total Pages | : 289 |
Release | : 2013-10-22 |
Genre | : Science |
ISBN | : 0080924956 |
Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field
Author | : V V Azatyan |
Publisher | : CRC Press |
Total Pages | : 360 |
Release | : 2000-07-06 |
Genre | : Science |
ISBN | : 9789069940021 |
This text explores nonbranching reactions, including in-depth information on the inhibitors of free radical polymerisation and the mechanisms of antioxidants on oxidationprocesses. Auto-initiated chain reactions are also explored, with detailed descriptions on the kinetics, mechanisms, and inhibition of the autoxidation of organic compounds, A special chapter deals with the synergism of antioxidant actions. The theory of chain-branching reactions is investigated, and a large amount of new experimental data concerning the use of chemical additives to regulate combustion processes is also presented, including the mode of chain thermal explosion.
Author | : Graeme Moad |
Publisher | : Elsevier |
Total Pages | : 667 |
Release | : 2006 |
Genre | : Science |
ISBN | : 0080442889 |
This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Author | : Chao-Jun Li |
Publisher | : John Wiley & Sons |
Total Pages | : 435 |
Release | : 2007-06-04 |
Genre | : Science |
ISBN | : 0470131438 |
An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.
Author | : E. T. Denisov |
Publisher | : John Wiley & Sons |
Total Pages | : 903 |
Release | : 2005-01-14 |
Genre | : Science |
ISBN | : 0471281832 |
Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.
Author | : Richard A. Jackson |
Publisher | : Royal Society of Chemistry |
Total Pages | : 212 |
Release | : 2004 |
Genre | : Education |
ISBN | : 9780854046423 |
An increasing knowledge and understanding of organic reaction mechanisms has been a major factor in the rapid advance of organic chemistry, biochemistry and pharmacology in the last century. It therefore forms a vital part of today's chemistry courses. Mechanisms in Organic Reactions helps students to make sensible proposals for the mechanisms of particular organic reactions, and then how to distinguish between different possible mechanisms. Techniques for this include product studies, kinetics, and the identification of intermediates. Three chapters on intermediates discuss likely points of attack on molecules by anions, radicals and cations, and the important role of acid- and base-catalysed reactions and radical chain reactions. The prediction of reaction rates and the effects of structural changes on reaction rate are also covered. It concludes with a discussion of molecular reactions, both thermal and photochemical - reactions which provide deep and beautiful insights into the reasons why some reactions go and others do not, and why the majority of real-life reactions involve multi-step processes. The book provides both illuminating insights into fundamental chemistry, and also practical value for students who will go on to teach, research, or be involved in other scientific roles (administration, policy making or journalism). Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.
Author | : Robert B. Grossman |
Publisher | : Springer Science & Business Media |
Total Pages | : 371 |
Release | : 2007-07-31 |
Genre | : Science |
ISBN | : 0387954686 |
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.
Author | : Cheves Walling |
Publisher | : |
Total Pages | : 644 |
Release | : 2013-02 |
Genre | : |
ISBN | : 9781258583422 |