Polymer Melt Rheology and Flow Birefringence

Polymer Melt Rheology and Flow Birefringence
Author: Hermann Janeschitz-Kriegl
Publisher: Springer Science & Business Media
Total Pages: 538
Release: 2012-12-06
Genre: Technology & Engineering
ISBN: 3642688225

The present monograph is intended as an introduction into a field which certainly did not receive proper attention in the past. It is one of the aims of this book to verify this suppo sition. The author hopes to show that the technique of the measurement of flow birefringence can fulfil an important com plementary task in polymer melt rheology. From this point it is expected that the present monograph will attract the atten tion of polymer scientists in general, and of rheologists and process engineers in particular. Certainly, the fourth chapter will appeal to the latter group. As a teacher in polymer science and technology the author wants to address also the group of the graduate students. In fact, the standard knowledge acquired during usual university studies in chemistry, physics or engineering does not enable a quick start of research activities in the field of polymer melt rheology. Certainly, in this typically interdisciplinary field everyone can lay emphasis on matters which are familar to hirn because of his preceding education. Significant research activities, however, can only be generated on the basis of a more universal knowledge. In the absence of this knowledge beginners have to rely upon the guidance of their supervisors for an unduly long period. Otherwise they take the risk of losing too much of their costly time. This holds in particular for the experimentalists who cannot be dispensed from being familiar with the necessary theoretical background.

Polymer Melt Rheology

Polymer Melt Rheology
Author: F N Cogswell
Publisher: Elsevier
Total Pages: 195
Release: 1981-01-01
Genre: Science
ISBN: 0857092987

This book explores the ways in which melt flow behaviour can be exploited by the plastics engineer and technician for increased efficiency of processing operation, control of end product properties and selection and development of polymers for specific purposes. (reissued with minor corrections 1994)

Rheology for Polymer Melt Processing

Rheology for Polymer Melt Processing
Author: J.-M. Piau
Publisher: Elsevier
Total Pages: 435
Release: 1996-10-10
Genre: Technology & Engineering
ISBN: 0080540562

This book presents the main results obtained by different laboratories involved in the research group Rheology for polymer melt processing which is associated with French universities, schools of engineering, and the CNRS (Centre National de la Recherche Scientifique - France). The group comprises some 15 research laboratories of varied disciplines (chemistry, physics, material sciences, mechanics, mathematics), but with a common challenge viz. to enhance the understanding of the relationships between macromolecular species, their rheology and their processing. Some crucial issues of polymer science have been addressed: correlation of viscoelastic macroscopic bulk property measurements and models, slip at the wall, extrusion defects, correlation between numerical flow simulations and experiments. Features of the book: • The book is unique in that it allows one to grasp the key issues in polymer rheology and processing at once through a series of detailed state-of-the-art contributions, which were previously scattered throughout the literature. • Each paper was reviewed by experts and the book editors and some coordination was established in order to achieve a readable and easy access style. • Papers have been grouped in sections covering successively: Molecular dynamics, Constitutive equations and numerical modelling, Simple and complex flows. • Each paper can be read independently. Since the book is intended as an introduction to the main topics in polymer processing, it will be of interest to graduate students as well as to scientists in academic and industrial laboratories.

Constitutive Equations for Polymer Melts and Solutions

Constitutive Equations for Polymer Melts and Solutions
Author: Ronald G. Larson
Publisher: Butterworth-Heinemann
Total Pages: 381
Release: 2013-10-22
Genre: Science
ISBN: 1483162869

Constitutive Equations for Polymer Melts and Solutions presents a description of important constitutive equations for stress and birefringence in polymer melts, as well as in dilute and concentrated solutions of flexible and rigid polymers, and in liquid crystalline materials. The book serves as an introduction and guide to constitutive equations, and to molecular and phenomenological theories of polymer motion and flow. The chapters in the text discuss topics on the flow phenomena commonly associated with viscoelasticity; fundamental elementary models for understanding the rheology of melts, solutions of flexible polymers, and advanced constitutive equations; melts and concentrated solutions of flexible polymer; and the rheological properties of real liquid crystal polymers. Chemical engineers and physicists will find the text very useful.

Melt Rheology and Its Role in Plastics Processing

Melt Rheology and Its Role in Plastics Processing
Author: K. Wissbrun
Publisher: Springer Science & Business Media
Total Pages: 684
Release: 2013-11-27
Genre: Science
ISBN: 1461597382

This book is designed to fulfill a dual role. On the one hand it provides a description of the rheological behavior of molten poly mers. On the other, it presents the role of rheology in melt processing operations. The account of rheology emphasises the underlying principles and presents results, but not detailed deriva tions of equations. The processing operations are described qualita tively, and wherever possible the role of rheology is discussed quantitatively. Little emphasis is given to non-rheological aspects of processes, for example, the design of machinery. The audience for which the book is intended is also dual in It includes scientists and engineers whose work in the nature. plastics industry requires some knowledge of aspects of rheology. Examples are the polymer synthetic chemist who is concerned with how a change in molecular weight will affect the melt viscosity and the extrusion engineer who needs to know the effects of a change in molecular weight distribution that might result from thermal degra dation. The audience also includes post-graduate students in polymer science and engineering who wish to acquire a more extensive background in rheology and perhaps become specialists in this area. Especially for the latter audience, references are given to more detailed accounts of specialized topics, such as constitutive relations and process simulations. Thus, the book could serve as a textbook for a graduate level course in polymer rheology, and it has been used for this purpose.

The application of flow birefringence to rheological studies of polymer melts

The application of flow birefringence to rheological studies of polymer melts
Author: J.L.S. Wales
Publisher: Springer
Total Pages: 111
Release: 1976-03-31
Genre: Science
ISBN: 9789029801027

1. 1 Preamble The science to which this work is appended is termed rheology and rheology means the study of flow and deformation of liquids and solids with emphasis on the underlying physical processes. Characteristic for solids is that they respond to a force by deforming, and, on removal of the force, by returning to their original shape. This type of re sponse is termed elastic. Characteristic for liquids is that they deform and continue to deform as long as the force is present. This type of response is termed viscous. The two definitions just given for viscous and elastic response represent ~wo extremes of response to an external force. Materials do not always fall readily into one or the other of the above-mentioned categories. An additional parameter is needed to describe material response more fully. The extra param eter is time. As a general rule the faster the deformation the closer the re sponse is to being elastic, the slower the deformation the closer the response is to being viscous. Slow and fast . are factors relative to some natural time, T, of the material. This natural time may be thought connected with the rates of spontaneous diffusion of its molecular and atomic constituents. For every day fluids as water, the natural time is very short, of the order of 10-10s 1) and hence for most purposes is considered as being viscous.

Thermoplastic Melt Rheology and Processing

Thermoplastic Melt Rheology and Processing
Author: Aroon Shenoy
Publisher: CRC Press
Total Pages: 477
Release: 1996-08-23
Genre: Science
ISBN: 1482295539

Presents rheological data on a number of polymers, making use of the master curve approach to determine unified curves for each generic type of polymer. The text offers a step-by-step procedure for developing a speadsheet computer program to obtain accurate thermoplastic rheograms at any tempertature without using sophisticated rheometres. It inclu

The application of flow birefringence to rheological studies of polymer melts

The application of flow birefringence to rheological studies of polymer melts
Author: J.L.S. Wales
Publisher: Springer
Total Pages: 0
Release: 1976-04-14
Genre: Science
ISBN: 9789401015561

1. 1 Preamble The science to which this work is appended is termed rheology and rheology means the study of flow and deformation of liquids and solids with emphasis on the underlying physical processes. Characteristic for solids is that they respond to a force by deforming, and, on removal of the force, by returning to their original shape. This type of re sponse is termed elastic. Characteristic for liquids is that they deform and continue to deform as long as the force is present. This type of response is termed viscous. The two definitions just given for viscous and elastic response represent ~wo extremes of response to an external force. Materials do not always fall readily into one or the other of the above-mentioned categories. An additional parameter is needed to describe material response more fully. The extra param eter is time. As a general rule the faster the deformation the closer the re sponse is to being elastic, the slower the deformation the closer the response is to being viscous. Slow and fast . are factors relative to some natural time, T, of the material. This natural time may be thought connected with the rates of spontaneous diffusion of its molecular and atomic constituents. For every day fluids as water, the natural time is very short, of the order of 10-10s 1) and hence for most purposes is considered as being viscous.