Fire Retardancy Behavior Of Polymer Clay Nanocomposites
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| Author | : Indraneel Suhas Zope |
| Publisher | : Springer |
| Total Pages | : 190 |
| Release | : 2018-05-16 |
| Genre | : Technology & Engineering |
| ISBN | : 9811083274 |
This thesis investigates the early ignition behavior of polymer/clay nanocomposites, which are perceived as potential eco-friendly flame retardant systems. It examines the correlation between clay structural chemistry and high-temperature transformations with clay-assisted decomposition of organic macromolecules. In particular, it investigates the unique effects of metal ions like Mg2+, Al3+ and Fe3+ that are inherent in clays (smectite) on the combustion and thermo-oxidative decomposition of polyamide 6. The results indicate that metal ions present on/in montmorillonite platelets have preferential reactivity towards peroxy/alkoxy groups during polyamide 6 thermal decomposition. Lastly, a simple solution in the form of a physical coating on clay surface is proposed, based on the role of polymer–clay interfacial interaction.
| Author | : Khouloud Jlassi |
| Publisher | : Elsevier |
| Total Pages | : 548 |
| Release | : 2017-07-26 |
| Genre | : Technology & Engineering |
| ISBN | : 0323461611 |
Clay–Polymer Nanocomposites is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This book covers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers. Indeed, nanocomposites can be prepared at industrial scale by melt mixing. Regardless the synthesis method, much is said in this book about the importance of theclay pre-modification step, which is demonstrated to be effective, on many occasions, in obtaining exfoliated nanocomposites. Clay–Polymer Nanocomposites reports the background to numerous characterization methods including solid state NMR, neutron scattering, diffraction and vibrational techniques as well as surface analytical methods, namely XPS, inverse gas chromatography and nitrogen adsorption to probe surface composition, wetting and textural/structural properties. Although not described in dedicated chapters, numerous X-ray diffraction patterns of clay–polymer nanocomposites and reference materials are displayed to account for the effects of intercalation and exfoliations of layered aluminosilicates. Finally, multiscale molecular simulation protocols are presenting for predicting morphologies and properties of nanostructured polymer systems with industrial relevance. As far as applications are concerned, Clay–Polymer Nanocomposites examines structural composites such as clay–epoxy and clay–biopolymers, the use of clay–polymer nanocomposites as reactive nanocomposite fillers, catalytic clay-(conductive) polymers and similar nanocomposites for the uptake of hazardous compounds or for controlled drug release, antibacterial applications, energy storage, and more. - The most comprehensive coverage of the state of the art in clay–polymer nanocomposites, from synthesis and design to opportunities and applications - Covers the various methods of characterization of clay–polymer nanocomposites - including spectroscopy, thermal analyses, and X-ray diffraction - Includes a discussion of a range of application areas, including biomedicine, energy storage, biofouling resistance, and more
| Author | : Constantine D. Papaspyrides |
| Publisher | : Newnes |
| Total Pages | : 943 |
| Release | : 2014-08-14 |
| Genre | : Technology & Engineering |
| ISBN | : 0444538097 |
Polymer Green Flame Retardants covers key issues regarding the response of polymers during fire, the mechanisms of their flame retardation, the regulations imposed on their use, and the health hazards arising from their combustion. Presenting the latest research developments, the book focuses in particular on nanocomposites, believed to be the most promising approach for producing physically superior materials with low flammability and ecological impact. The fire properties of nanocomposites of various matrixes and fillers are discussed, the toxicological characteristics of these materials are analyzed, addressing also their environmental sustainability. Edited by distinguished scientists, including an array of international industry and academia experts, this book will appeal to chemical, mechanical, environmental, material and process engineers, upper-level undergraduate and graduate students in these disciplines, and generally to researchers developing commercially attractive and environmentally friendly fire-proof products. - Provides recent findings on the manufacture of environmentally sustainable flame retardant polymeric materials - Covers legislation and regulations concerning flame retarded polymeric material use - Includes tables containing the fire properties of the most common polymeric materials
| Author | : Alexander B. Morgan |
| Publisher | : John Wiley & Sons |
| Total Pages | : 449 |
| Release | : 2007-04-13 |
| Genre | : Technology & Engineering |
| ISBN | : 0471734268 |
Flame Retardant Polymer Nanocomposites takes a comprehensive look at polymer nanocomposites for flame retardancy applications and includes nanocomposite fundamentals (theory, design, synthesis, characterization) as well as polymer flammability fundamentals with emphasis on how nanocomposites affect flammability. The book has practical examples from literature, patents, and existing commercial products. Readers can design new work based upon the material in the book or use it as a handy reference for interpreting existing work and results.
| Author | : Gary W. Beall |
| Publisher | : Cambridge University Press |
| Total Pages | : 195 |
| Release | : 2011-07-07 |
| Genre | : Technology & Engineering |
| ISBN | : 1139500759 |
Written for graduate students, researchers, and practitioners, this book provides a complete introduction to the science, engineering, and commercial applications of polymer-clay nanocomposites. Starting with a discussion of general concepts, the authors define specific terms used in the field, providing newcomers with a strong foundation to the area. The physical and mechanical properties of polymer-clay nanocomposites are then described, with chapters on thermodynamics and kinetics, engineering properties, barrier properties, and flame retardancy. Mechanisms underpinning observed effects, such as UV resistance, solvent resistance, and hardness, are also explained. In-depth discussions of clay and clay surface treatment, fabrication, and characterization of nanocomposites are provided, and particular emphasis is placed on the proper use and interpretation of analytical techniques, helping readers to avoid artifacts in their own work. With commercial applications discussed throughout, and experimental results connected with theory, this is an ideal reference for those working in polymer science.
| Author | : S C Tjong |
| Publisher | : Elsevier |
| Total Pages | : 943 |
| Release | : 2010-10-29 |
| Genre | : Technology & Engineering |
| ISBN | : 0857090240 |
Polymer nanocomposites are polymer matrices reinforced with nano-scale fillers. This new class of composite materials has shown improved mechanical and physical properties. The latter include enhanced optical, electrical and dielectric properties. This important book begins by examining the characteristics of the main types of polymer nanocomposites, then reviews their diverse applications.Part one focuses on polymer/nanoparticle composites, their synthesis, optical properties and electrical conductivity. Part two describes the electrical, dielectric and thermal behaviour of polymer/nanoplatelet composites, whilst polymer/nanotube composites are the subject of Part three. The processing and industrial applications of these nanocomposite materials are discussed in Part four, including uses in fuel cells, bioimaging and sensors as well as the manufacture and applications of electrospun polymer nanocomposite fibers, nanostructured transition metal oxides, clay nanofiller/epoxy nanocomposites, hybrid epoxy-silica-rubber nanocomposites and other rubber-based nanocomposites.Polymer nanocomposites: Physical properties and applications is a valuable reference tool for both the research community and industry professionals wanting to learn about the these materials and their applications in such areas as fuel cell, sensor and biomedical technology. - Examines the characteristics of the main types of polymer nanocomposites and reviews their diverse applications - Comprehensively assesses polymer/nanoparticle composites exploring experimental techniques and data associated with the conductivity and dielectric characterization - A specific section on polymer/nanotube composites features electrical and dielectric behaviour of polymer/carbon nanotube composites
| Author | : Charles A. Wilkie |
| Publisher | : CRC Press |
| Total Pages | : 800 |
| Release | : 2024-07-29 |
| Genre | : Law |
| ISBN | : 1040035256 |
The third edition of Fire Retardancy of Polymeric Materials provides a single source for all aspects of this highly challenging field of applied research. This authoritative book covers design and non-fire requirements that drive how these materials are fire protected. Detailed study and consideration of chemistry, physics, materials science, economic issues and fire safety science is necessary to address considerations of mechanical, thermal, environmental, and end-use requirements on top of fire protection means that the field requires. This thoroughly revised new edition continues to offer comprehensive coverage of the scientific approach for those developing fire safe materials. It covers new topics such as bio-based materials, regulatory issues, recycling, newer flame retardant chemical classes, and more details on how to flame retard materials for specific market applications. Written by a team of experts, this book covers the fundamentals of polymer burning and combustion and how to apply fire protection or flame-retardant chemistries to specific material classes and applications. The book is written for material scientists and fire safety scientists who seek to develop new fire safe materials or understand why materials burn in our modern environment. Features Connects fundamentals of material flammability to practical fire safety needs Covers current fire safety requirements and regulations affecting flame retardant selection Provides information on chemical structure-property relationships for flame retardancy Provides practical guidance on how to design fire safe materials for specific fire risk scenarios The new edition is expanded to 32 chapters and all chapters are updated and revised with the newest information
| Author | : Abderrahim Boudenne |
| Publisher | : John Wiley & Sons |
| Total Pages | : 1322 |
| Release | : 2011-06-09 |
| Genre | : Technology & Engineering |
| ISBN | : 1119972884 |
Multiphase polymeric systems include a wide range of materials such as composites, blends, alloys, gels, and interpenetrating polymer networks (IPNs). A one-stop reference on multiphase polymer systems, this book fully covers the preparation, properties, and applications of advanced multiphase systems from macro to nano scales. Edited by well-respected academics in the field of multiphase polymer systems, the book includes contributions from leading international experts. An essential resource for plastic and rubber technologists, filler specialists and researchers in fields studying thermal and electrical properties.
| Author | : T. J. Pinnavaia |
| Publisher | : Wiley |
| Total Pages | : 0 |
| Release | : 2001-01-19 |
| Genre | : Technology & Engineering |
| ISBN | : 9780471637004 |
Polymer-clay nanocomposites are formed through the union of two very different materials with organic and mineral pedigrees. The hybrid compositions, however, exhibit large increases in tensile strength, modulus, and heat distortion temperature as compared with the pristine polymer. The composites also have lower water sensitivity, reduced permeability to gases, and a similar thermal coefficient of expansion. All of these property improvements can be realized without a loss of clarity in the polymer. Further, it has been found that nanocomposites impart a level of flame retardance and UV resistance not present in the pure polymer. These improvements in performance properties at relatively low clay loading (typically 2 -10wt %) have stimulated intensive research in both industry and academia over the past decade. Polymer-Clay Nanocomposites presents the first comprehensive overview of the state of the art of these materials since they were first reported a decade ago. Covering both the theory and practical applications, this volume in the 'Wiley Series in Polymer Science' covers the key aspects of these important materials including: * Polymer-clay intercalates * The preparation and general properties of special practical and commercial significance (including strength, stiffness, toughness, permeability, fire retardation and chemical stability) * The elucidation of the structural and rheological factors influencing performance and processing properties Polymer-Clay Nanocomposites is an indispensable text for polymer scientists, composites formulators, materials engineers, resin producers, filters and additive producers as well as university lecturers, and organic and inorganic chemists working in this important and fascinating area.
| Author | : Carlos P. Bergmann |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 174 |
| Release | : 2011-08-28 |
| Genre | : Technology & Engineering |
| ISBN | : 3642191312 |
This book gives an introduction to nanostructured materials and guides the reader through their different engineering applications. It addresses the special phenomena and potentials involved in the applications without going into too much scientific detail of the physics and chemistry involved, which makes the reading interesting for beginners in the field. Materials for different applications in engineering are described, such as those used in opto-electronics, energy, tribology, bio-applications, catalysis, reinforcement and many more. In each application chapter, the reader will learn about the phenomena involved in the application, the nanostructured materials used in the field and their processing, besides finding some practical examples of their use in laboratories and in industry.The clear language and the application-oriented perspective of the book makes it suitable for both engineers and students who want to learn about applications of nanostructured materials in Engineering.
