Feasibility of CO2 desorption and electrolytic regeneration of potassium carbonate solution in an anion exchange membrane cell

Feasibility of CO2 desorption and electrolytic regeneration of potassium carbonate solution in an anion exchange membrane cell
Author: Daxue Fu
Publisher: OAE Publishing Inc.
Total Pages: 10
Release: 2023-10-23
Genre: Science
ISBN:

In this work, an electrolytic process was introduced for coupled regeneration of potassium carbonate (K2CO3) solution and water electrolysis by using an anion exchange membrane cell. The process made the CO2 separation from O2 much easier with respect to the existing cationic exchange membrane process. The solution of K2CO3 was used in the cathode chamber to simulate the solution after absorbing CO2. The solution of sulfuric acid (0.1 mol/L H2SO4) was charged in the anode chamber. The feasibility of the process was discussed. The effects of various operation parameters, including temperature, current density, and electrolysis time, were studied. The results indicate that both the yield rate of CO2 and the current efficiency increase initially and decrease afterward with temperature. The yield rate of CO2 increases while the current efficiency decreases with the current density. A low current density can reduce the energy consumption for producing the same amount of CO2. The processes using anion exchange membrane electrolysis can regenerate the absorbent solution to achieve 89% current efficiency, and the simultaneous production of three pure gases, CO2, H2, and O2, makes this method promising.

Climate Change 2014

Climate Change 2014
Author: Groupe d'experts intergouvernemental sur l'évolution du climat. Working group 3
Publisher:
Total Pages: 141
Release:
Genre:
ISBN: 9789291691425

Energy Efficient Solvents for CO2 Capture by Gas-Liquid Absorption

Energy Efficient Solvents for CO2 Capture by Gas-Liquid Absorption
Author: Wojciech M. Budzianowski
Publisher: Springer
Total Pages: 282
Release: 2016-12-01
Genre: Technology & Engineering
ISBN: 3319472623

This book reviews and characterises promising single-compound solvents, solvent blends and advanced solvent systems suitable for CO2 capture applications using gas-liquid absorption. Focusing on energy efficient solvents with minimal adverse environmental impact, the contributions included analyse the major technological advantages, as well as research and development challenges of promising solvents and solvent systems in various sustainable CO2 capture applications. It provides a valuable source of information for undergraduate and postgraduate students, as well as for chemical engineers and energy specialists.

Thermodynamics Of Fluids: Measurement And Correlation

Thermodynamics Of Fluids: Measurement And Correlation
Author: A Anderko
Publisher: World Scientific
Total Pages: 526
Release: 1990-03-01
Genre:
ISBN: 9814611778

This volume is a collection of papers, mostly state-of-the-art reviews, describing main topics of current research in Applied Thermodynamics. The papers deal with measurements of thermodynamic properties which are important for process design in chemical and related industries as well as for theoretical investigations of pure fluids and mixtures. Besides measuring techniques, methods are reviewed for the processing and correlation of experimental data.

Ion Exchange Membranes

Ion Exchange Membranes
Author: Yoshinobu Tanaka
Publisher: Elsevier Science
Total Pages: 0
Release: 2015-01-20
Genre: Technology & Engineering
ISBN: 9780444633194

Fundamental study and industrial application of ion exchange membranes started over half a century ago. Through ongoing research and development, ion exchange membrane technology is now applied to many fields and contributes to the improvement of our standard of living. Ion Exchange Membranes, 2nd edition states the ion exchange membrane technology from the standpoint of fundamentals and applications. It discusses not only various phenomena exhibited by membranes but also their applications in many fields with economical evaluations. This second edition is updated and revised, featuring ten expanded chapters. New to this edition is a computer simulation program of ion-exchange membrane electrodialysis for water desalination that provides a guideline for designing, manufacturing and operating a practical-scale electrodialyzer. Meant to replace experiments, this program will be an important asset to those with time and monetary budgets.

Carbon Dioxide Equilibria and Their Applications

Carbon Dioxide Equilibria and Their Applications
Author: James N. Butler
Publisher: Routledge
Total Pages: 276
Release: 2019-01-22
Genre: Science
ISBN: 135146258X

Carbon dioxide, bicarbonate ion, and carbonate ion comprise the most important acid-base system in natural waters, and the equilibria between them regulate the pH of seawater, as well as most rainwater, stream water, river water, and groundwater. Carbon Dioxide Equilibria and Their Applications provides a clear, compact presentation of this topic,

Electro-Fenton Process

Electro-Fenton Process
Author: Minghua Zhou
Publisher: Springer
Total Pages: 437
Release: 2017-11-25
Genre: Science
ISBN: 9811064067

This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.

Hollow Fiber Membrane Contactors

Hollow Fiber Membrane Contactors
Author: Anil K. Pabby
Publisher: CRC Press
Total Pages: 325
Release: 2020-11-23
Genre: Science
ISBN: 0429677456

This book on hollow fiber contractors presents an up-to-date compilation of the latest developments and milestones in this membrane technology. Hollow Fiber Membrane Contactors: Module Fabrication, Design and Operation, and Potential Applications provides a comprehensive discussion of hollow fiber membrane applications (including a few case studies) in biotechnology, chemical, food, and nuclear engineering. The chapters in this book have been classified using the following, based on different ways of contacting fluids with each other: Gas-liquid contacting; Liquid-liquid contacting; Supported liquid membrane; Supported gas membrane; Fluid-fluid contacting. Other features include: Discusses using non-dispersive solvent extraction, hollow fiber strip dispersion, hollow fiber supported liquid membranes and role of process intensification in integrated use of these processes Provides technical and economic perspectives with several case studies related to specific scenarios Demonstrates module fabrication, design, operation and maintenance of hollow fiber contactors for different applications and performance Presents discussion on newer concepts like membrane emulsification, membrane nanoprecipitation, membrane crystallization and membrane condenser Special focus on emerging areas such as the use of hollow fiber contactor in back end of nuclear fuel cycle, membrane distillation, dehumidification of air and gas absorption and stripping Discusses theoretical analysis including computational modeling of different hollow fiber membrane processes, and presents emphasis on newly developed area of hollow fiber membrane based analytical techniques Presents discussion on upcoming area dealing with hollow fiber contactors-based technology in fermentation and enzymatic transformation and in chiral separations This book is equally suited for newcomers to the field, as well as for engineers and scientists that have basic knowledge in this field but are interested in obtaining more information about specific future applications.

Electrochemical and Electrocatalytic Reactions of Carbon Dioxide

Electrochemical and Electrocatalytic Reactions of Carbon Dioxide
Author: B.P. Sullivan
Publisher: Elsevier
Total Pages: 314
Release: 2012-12-02
Genre: Science
ISBN: 0444596615

The recycling of atmospheric molecules for use as fuels and chemicals is a goal which can only be achieved through a deeper understanding of catalytic processes, particularly electrocatalysis whereby redox transformations can be interfaced with solar or nuclear energy input. Carbon dioxide is a prototypical small molecule in many regards since it is chemically inert. In addition, because of the likely role of carbon dioxide in global temperature cycles, it will be imperative in the future to regulate the output from industrial processes. The purpose of this book is to present a unified discussion of the carbon dioxide chemistry which is necessary for the understanding and design of electrochemically-driven processes for the reduction of carbon dioxide and to provide an impetus for the further development of electrocatalytic carbon dioxide chemistry.

Carbon Capture

Carbon Capture
Author: Jennifer Wilcox
Publisher: Springer Science & Business Media
Total Pages: 337
Release: 2012-03-28
Genre: Science
ISBN: 1461422140

This book approaches the energy science sub-field carbon capture with an interdisciplinary discussion based upon fundamental chemical concepts ranging from thermodynamics, combustion, kinetics, mass transfer, material properties, and the relationship between the chemistry and process of carbon capture technologies. Energy science itself is a broad field that spans many disciplines -- policy, mathematics, physical chemistry, chemical engineering, geology, materials science and mineralogy -- and the author has selected the material, as well as end-of-chapter problems and policy discussions, that provide the necessary tools to interested students.