Equilibrium And Non Equilibrium Aspects Of Gibbs Measures
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Author | : Sacha Friedli |
Publisher | : Cambridge University Press |
Total Pages | : 643 |
Release | : 2017-11-23 |
Genre | : Mathematics |
ISBN | : 1107184827 |
A self-contained, mathematical introduction to the driving ideas in equilibrium statistical mechanics, studying important models in detail.
Author | : Avijit Lahiri |
Publisher | : Avijit Lahiri |
Total Pages | : 1623 |
Release | : 2023-10-14 |
Genre | : Science |
ISBN | : |
Equilibrium and Non-equilibrium Statistical Mechanics is a source-book of great value to college and university students embarking upon a serious reading of Statistical Mechanics, and is likely to be of interest to teachers of the subject as well. Written in a lucid style, the book builds up the subject from basics, and goes on to quite advanced and modern developments, giving an overview of the entire framework of statistical mechanics. The equilibrium ensembles of quantum and classical statistical mechanics are introduced at length, indicating their relation to equilibrium states of thermodynamic systems, and the applications of these ensembles in the case of the ideal gas are worked out, pointing out the relevance of the ideal gas in respect of a number of real-life systems. The application to interacting systems is then taken up by way of explaining the virial expansion of a dilute gas. The book then deals with a number of foundational questions relating to the existence of the thermodynamic limit and to the equivalence of the various equilibrium ensembles. The relevance of the thermodynamic limit in explaining phase transitions is indicated with reference to the Yang-Lee theory and the Kirkwood-Salsburg equations for correlation functions. The statistical mechanics of interacting systems is then taken up again, with reference to the 1D and 2D Ising model and to the spin glass model of disordered systems. Applications of the Mean field theory are worked out, explaining the Landau-Ginzburg theory, which is then followed by the renormalization group approach to phase transitions. Interacting systems in the quantum context are referred to, addressing separately the cases of interacting bosons and fermions. The case of the weakly interacting bosons is explained in details, while the Landau theory for fermi liquids is also explained in outline. The book then goes on to a modern but readable account of non-equilibrium statistical mechanics, explaining the link with irreversible thermodynamcs. After an exposition of the Boltzmann equations and the linear response theory illustrated with reference to the hydrodynamic model, it explains the statistical mechanics of reduced systems, in the context of a number of reduction schemes. This is followed by an account of the relevance of dynamical chaos in laying down the foundations of classical statistical mechanics, where the SRB distributon is introduced in the context of non-equilibrium steady states, with reference to which the principle of minimum entropy production is explaned. A number of basic fluctuation relations are then worked out, pointing out their relation to irreversible thermodynamics. Finally, the book explains the relevance of quantum chaos in addressing foundational issues in quantum statistical mechanics, beginning with Berry’s conjecture and then going on to an exposition of the eigenstate thermalization (ETH) hypothesis, indicating how the latter is relevant in explaining the processes of equilibriation and thermalization in thermodynamic systems and their sub-systems.
Author | : Giambattista Giacomin |
Publisher | : Springer |
Total Pages | : 654 |
Release | : 2019-06-30 |
Genre | : Mathematics |
ISBN | : 3030150968 |
Stemming from the IHP trimester "Stochastic Dynamics Out of Equilibrium", this collection of contributions focuses on aspects of nonequilibrium dynamics and its ongoing developments. It is common practice in statistical mechanics to use models of large interacting assemblies governed by stochastic dynamics. In this context "equilibrium" is understood as stochastically (time) reversible dynamics with respect to a prescribed Gibbs measure. Nonequilibrium dynamics correspond on the other hand to irreversible evolutions, where fluxes appear in physical systems, and steady-state measures are unknown. The trimester, held at the Institut Henri Poincaré (IHP) in Paris from April to July 2017, comprised various events relating to three domains (i) transport in non-equilibrium statistical mechanics; (ii) the design of more efficient simulation methods; (iii) life sciences. It brought together physicists, mathematicians from many domains, computer scientists, as well as researchers working at the interface between biology, physics and mathematics. The present volume is indispensable reading for researchers and Ph.D. students working in such areas.
Author | : Signe Kjelstrup |
Publisher | : World Scientific |
Total Pages | : 451 |
Release | : 2008 |
Genre | : Technology & Engineering |
ISBN | : 9812779132 |
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems.The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight.
Author | : R. P. Rastogi |
Publisher | : Elsevier |
Total Pages | : 357 |
Release | : 2007-10-16 |
Genre | : Technology & Engineering |
ISBN | : 0080551807 |
Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. - The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium - Experimental studies have been reported which provide test of the theories and their limitations - Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed
Author | : Joel Keizer |
Publisher | : Springer Science & Business Media |
Total Pages | : 517 |
Release | : 2012-12-06 |
Genre | : Science |
ISBN | : 1461210542 |
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.
Author | : Barry Simon |
Publisher | : Princeton University Press |
Total Pages | : 534 |
Release | : 2014-07-14 |
Genre | : Science |
ISBN | : 1400863430 |
A state-of-the-art survey of both classical and quantum lattice gas models, this two-volume work will cover the rigorous mathematical studies of such models as the Ising and Heisenberg, an area in which scientists have made enormous strides during the past twenty-five years. This first volume addresses, among many topics, the mathematical background on convexity and Choquet theory, and presents an exhaustive study of the pressure including the Onsager solution of the two-dimensional Ising model, a study of the general theory of states in classical and quantum spin systems, and a study of high and low temperature expansions. The second volume will deal with the Peierls construction, infrared bounds, Lee-Yang theorems, and correlation inequality. This comprehensive work will be a useful reference not only to scientists working in mathematical statistical mechanics but also to those in related disciplines such as probability theory, chemical physics, and quantum field theory. It can also serve as a textbook for advanced graduate students. Originally published in 1993. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.
Author | : J. R. Dorfman |
Publisher | : Cambridge University Press |
Total Pages | : 303 |
Release | : 1999-08-28 |
Genre | : Science |
ISBN | : 0521655897 |
Introduction to applications and techniques in non-equilibrium statistical mechanics of chaotic dynamics.
Author | : Hans-Otto Georgii |
Publisher | : Walter de Gruyter |
Total Pages | : 561 |
Release | : 2011-05-31 |
Genre | : Mathematics |
ISBN | : 3110250322 |
"This book is much more than an introduction to the subject of its title. It covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics and as an up to date reference in its chosen topics it is a work of outstanding scholarship. It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert. In its latter function it informs the reader about the state of the art in several directions. It is introductory in the sense that it does not assume any prior knowledge of statistical mechanics and is accessible to a general readership of mathematicians with a basic knowledge of measure theory and probability. As such it should contribute considerably to the further growth of the already lively interest in statistical mechanics on the part of probabilists and other mathematicians." Fredos Papangelou, Zentralblatt MATH The second edition has been extended by a new section on large deviations and some comments on the more recent developments in the area.
Author | : Freddy Bouchet |
Publisher | : Oxford University Press, USA |
Total Pages | : 247 |
Release | : 2020 |
Genre | : Business & Economics |
ISBN | : 0198855214 |
"This book collects the text of the lectures given at the Les Houches Summer School on "Fundamental aspects of turbulent flows in climate dynamics", held in August 2017. Leading scientists in the fields of climate dynamics, atmosphere and ocean dynamics, geophysical fluid dynamics, physics and non-linear sciences present their views on this fast growing and interdisciplinary field of research, by venturing upon fundamental problems of atmospheric convection, clouds, large scale circulation, and predictability. Climate is controlled by turbulent flows. Turbulent motions are responsible for the bulk of the transport of energy, momentum, and water vapor in the atmosphere, which determine the distribution of temperature, winds, and precipitation on Earth. Clouds, weather systems, and boundary layers in the oceans and atmosphere are manifestations of turbulence in the climate system. Because turbulence remains as the great unsolved problem of classical physics, we do not have a complete physical theory of climate. The aim of this summer school was to survey what is known about how turbulent flows control climate, what role they may play in climate change, and to outline where progress in this important area can be expected, given today's computational and observational capabilities. This book reviews the state-of-the-art developments in this field and provides an essential background to future studies. All chapters are written from a pedagogical perspective, making the book accessible to masters and PhD students and all researchers wishing to enter this field. It is complemented by online video of several lectures and seminars recorded during the summer school"