Electronic Properties of Inorganic Quasi-One-Dimensional Compounds

Electronic Properties of Inorganic Quasi-One-Dimensional Compounds
Author: P. Monceau
Publisher: Springer
Total Pages: 282
Release: 1985-03-31
Genre: Science
ISBN: 9789027718013

The close relationship between experimentalists and theorists – whether solid state chemists or physicists – has, in the last few years, inspired much research in the field of materials with quasi one-dimensional structures. Part I of this two-volume set, reviews the basic theories describing the physical properties of one-dimensional materials including their superconducting characteristics. This description is mainly based on the properties of transition metal trichalcogenides. The novel collective transport mechanism for electronic conduction, exhibited by some of the latter compounds – NbSe3 being considered as the prototype – is surveyed according to a classical theory and a theory including macroscopic quantum effects. In addition, the book contains a description of the properties of non-linear excitations, or solitons, in one-dimensional systems. Part II of this two-volume set deals with the experimental treatment of pseudo-one-dimensional conductors. Included are contributions on platinum chains, (SN)x and (SNBry)x, the optical properties of 1-D inorganic metals, CDW transport in transition metal chalcogenides, and a lattice dynamical study of transition metal trichalcogenides.

Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides

Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides
Author: C. Schlenker
Publisher: Springer Science & Business Media
Total Pages: 461
Release: 2012-12-06
Genre: Science
ISBN: 9400904479

The history of low dimensional conductors goes back to the prediction, more than forty years ago, by Peierls, of the instability of a one dimensional metallic chain, leading to what is known now as the charge density wave state. At the same time, Frohlich suggested that an "ideal" conductivity could be associated to the sliding of this charge density wave. Since then, several classes of compounds, including layered transition metal dichalcogenides, quasi one-dimensional organic conduc tors and transition metal tri- and tretrachalcogenides have been extensively studied. The molybdenum bronzes or oxides have been discovered or rediscovered as low dimensional conductors in this last decade. A considerable amount of work has now been performed on this subject and it was time to collect some review papers in a single book. Although this book is focused on the molybdenum bronzes and oxides, it has a far more general interest in the field of low dimensional conductors, since several of the molybdenum compounds provide, from our point of view, model systems. This is the case for the quasi one-dimensional blue bronze, especially due to the availability of good quality large single crystals. This book is intended for scientists belonging to the fields of solid state physics and chemistry as well as materials science. It should especially be useful to many graduate students involved in low dimensional oxides. It has been written by recognized specialists of low dimensional systems.

Magnetic Properties of Layered Transition Metal Compounds

Magnetic Properties of Layered Transition Metal Compounds
Author: L.J. de Jongh
Publisher: Springer Science & Business Media
Total Pages: 430
Release: 2012-12-06
Genre: Science
ISBN: 9400918607

In the last two decades low-dimensional (low-d) physics has matured into a major branch of science. Quite generally we may define a system with restricted dimensionality d as an object that is infinite only in one or two spatial directions (d = 1 and 2). Such a definition comprises isolated single chains or layers, but also fibres and thin layers (films) of varying but finite thickness. Clearly, a multitude of physical phenomena, notably in solid state physics, fall into these categories. As examples, we may mention: • Magnetic chains or layers (thin-film technology). • Metallic films (homogeneous or heterogeneous, crystalline, amorphous or microcristalline, etc.). • I-d or 2-d conductors and superconductors. • Intercalated systems. • 2-d electron gases (electrons on helium, semiconductor interfaces). • Surface layer problems (2-d melting of monolayers of noble gases on a substrate, surface problems in general). • Superfluid films of ~He or 'He. • Polymer physics. • Organic and inorganic chain conductors, superionic conductors. • I-d or 2-d molecular crystals and liquid crystals. • I-d or 2-d ferro- and antiferro electrics.

Electron Spectroscopies Applied to Low-Dimensional Structures

Electron Spectroscopies Applied to Low-Dimensional Structures
Author: H.P. Hughes
Publisher: Springer Science & Business Media
Total Pages: 513
Release: 2006-04-11
Genre: Science
ISBN: 0306471264

The effect of reduced dimensionality, inherent at the crystallographic level, on the electronic properties of low dimensional materials can be dramatic, leading to structural and electronic instabilities—including supercond- tivity at high temperatures, charge density waves, and localisation—which continue to attract widespread interest. The layered transition metal dichalcogenides have engaged attention for many years, partly arising from the charge density wave effects which some show and the controlled way in which their properties can be modified by intercalation, while the development of epitaxial growth techniques has opened up promising areas based on dichalcogenide heterostructures and quantum wells. The discovery of high-temperature superconducting oxides, and the realisation that polymeric materials too can be exploited in a controlled way for various opto-electronic applications, have further sti- lated interest in the effects of structural dimensionality. It seems timely therefore to draw together some strands of recent research involving a range of disparate materials which share some common char- teristics of low dimensionality. This resulting volume is aimed at researchers with specialist interests in the particular materials discussed but who may also wish to examine the related phenomena observed in different systems, and at a more general solid state audience with broad interests in electronic properties and low dimensional phenomena. Space limitations have required us to be selective as regards particular materials, though we have managed to include those as dissimilar as polymeric semiconductors, superconducting oxides, bronzes and layered chalcogenides.

Theoretical Aspects of Band Structures and Electronic Properties of Pseudo-One-Dimensional Solids

Theoretical Aspects of Band Structures and Electronic Properties of Pseudo-One-Dimensional Solids
Author: Hitomi Kimura
Publisher: Springer Science & Business Media
Total Pages: 294
Release: 2012-12-06
Genre: Science
ISBN: 9400952996

This volume presents a sequence of articles which describe the theoretical treat ments of investigating the fundamental features in the electronic structures and properties of typical quasi-one-dimensional solids; organic conductor TTF-TCNQ, polyacetylene, metallic and superconducting polymer (SN)n and linear chain chal cogenides and halides of transition elements including NbSe3' The aim of this volume is not to present an exhaustive review but rather to touch on a selective class of problems which appear to be fundamental for typical quasi-one-dimensional solids. Thus the topics in this volume are rather confined to the key basic properties of quasi-one-dimensional systems. The quasi-one-dimensional solids are one of the most extensively investigated subjects in current physics, chemistry and materials science. These materials are unique in attracting a broad range of scientists, chemists, experimental and theore tical physicists, materials scientists and engineers. In 1954 Frohlich constructed a theory of superconductivity based on a one-dimensional model of moving charge density waves. In 1955 Peierls predicted that anyone-dimensional metal is unstable against the distortion of a periodic lattice so that a metal-nonmetal transition occurs at a certain temperature for a one-dimensional metal. According to these theories a gap is opened at the Fermi surfaces of one-dimensional conductors at low tempera tures and the charge density wave is created in connection with the occurrence of the gap.

Two-Dimensional Electron Systems

Two-Dimensional Electron Systems
Author: E.Y. Andrei
Publisher: Springer Science & Business Media
Total Pages: 398
Release: 2012-12-06
Genre: Science
ISBN: 9401512868

Recent studies on two-dimensional systems have led to new insights into the fascinating interplay between physical properties and dimensionality. Many of these ideas have emerged from work on electrons bound to the surface of a weakly polarizable substrate such as liquid helium or solid hydrogen. The research on this subject continues to be at the forefront of modern condensed matter physics because of its fundamental simplicity as well as its connection to technologically useful devices. This book is the first comprehensive overview of experimental and theoretical research in this exciting field. It is intended to provide a coherent introduction for graduate students and non-experts, while at the same time serving as a reference source for active researchers in the field. The chapters are written by individuals who made significant contributions and cover a variety of specialized topics. These include the origin of the surface states, tunneling and magneto-tunneling out of these states, the phase diagram, collective excitations, transport and magneto-transport.

Physics and Chemistry of Metal Cluster Compounds

Physics and Chemistry of Metal Cluster Compounds
Author: L.J. de Jongh
Publisher: Springer Science & Business Media
Total Pages: 326
Release: 2013-03-09
Genre: Science
ISBN: 9401512949

On Friday, February 20, 1980, I had the pleasure to be present at the inaugural lecture of my colleague Jan Reedijk, who had just been named at the Chair of Inorganic Chemistry of Leiden University. According to tradition, the ceremony took place in the impressive Hall of the old University Academy Building. In the course of his lecture, Jan mentioned a number of recent developments in chemistry which had struck him as particularly important or interesting. Among those was the synthesis of large metal cluster compounds, and, to my luck, he showed a slide ofthe molecular structure of [PtI9(C)b]4-. (To my luck, since at traditional Leiden University it is quite unusual to show slides at such ceremonies.) This constituted my first acquaintance with this exciting new class of materials. I became immediately fascinated by this molecule, partly because of the esthetic beauty of its fivefold symmetry, partly because as a physicist it struck me that it could be visualized as an "embryonically small" metal particle, embedded in a shell of CO ligands.

The Physics of Fullerene-Based and Fullerene-Related Materials

The Physics of Fullerene-Based and Fullerene-Related Materials
Author: W. Andreoni
Publisher: Springer Science & Business Media
Total Pages: 474
Release: 2000-03-31
Genre: Science
ISBN: 9780792362340

Krätschmer and Huffman's revolutionary discovery of a new solid phase of carbon, solid C60, in 1990 opened the way to an entire new class of materials with physical properties so diverse that their richness has not yet been fully exploited. Moreover, as a by-product of fullerene research, carbon nanotubes were later identified, from which novel nanostructures originated that are currently fascinating materials scientists worldwide. Rivers of words have been written on both fullerenes and nanotubes, in the form of journal articles, conference proceedings and books. The present book offers, in a concise and self-contained manner, the basics of the science of these materials as well as detailed information on those aspects that have so far been better explored. Structural, electronic and dynamical properties are described as obtained from various measurements and state-of-the-art calculations. Their interrelation emerges as well as their possible dependence on, for example, preparation conditions or methods of investigation. By presenting and comparing data from different sources, experiment and theory, this book helps the reader to rapidly master the basic knowledge, to grasp important issues and critically discuss them. Ultimately, it aims to inspire him or her to find novel ways to approach still open questions. As such, this book is addressed to new researchers in the field as well as experts.