Feasibility of CO2 desorption and electrolytic regeneration of potassium carbonate solution in an anion exchange membrane cell

Feasibility of CO2 desorption and electrolytic regeneration of potassium carbonate solution in an anion exchange membrane cell
Author: Daxue Fu
Publisher: OAE Publishing Inc.
Total Pages: 10
Release: 2023-10-23
Genre: Science
ISBN:

In this work, an electrolytic process was introduced for coupled regeneration of potassium carbonate (K2CO3) solution and water electrolysis by using an anion exchange membrane cell. The process made the CO2 separation from O2 much easier with respect to the existing cationic exchange membrane process. The solution of K2CO3 was used in the cathode chamber to simulate the solution after absorbing CO2. The solution of sulfuric acid (0.1 mol/L H2SO4) was charged in the anode chamber. The feasibility of the process was discussed. The effects of various operation parameters, including temperature, current density, and electrolysis time, were studied. The results indicate that both the yield rate of CO2 and the current efficiency increase initially and decrease afterward with temperature. The yield rate of CO2 increases while the current efficiency decreases with the current density. A low current density can reduce the energy consumption for producing the same amount of CO2. The processes using anion exchange membrane electrolysis can regenerate the absorbent solution to achieve 89% current efficiency, and the simultaneous production of three pure gases, CO2, H2, and O2, makes this method promising.

Mercury Cathode Cell Reduction of Carbonate Solutions

Mercury Cathode Cell Reduction of Carbonate Solutions
Author: J. C. Huggins
Publisher:
Total Pages: 80
Release: 1955
Genre: Electrolysis
ISBN:

This is the final report on the laboratory investigation of electrolysis of carbonate leach solutions using the mercury cathode cell. Data are presented on the electrolysis of Anaconda pregnant solution, and a pregnant solution containing uranium only which was derived from laboratory leaching tests on Cal Uranium ore. High recoveries from both solutions were made with low power consumptions. A correlation of the rate data as a function of cathode current density and temperature which should be adequate for design of a pilot-plant facility is presented. An economic evaluation of the electrolysis using the mercury cathode cell is included. The estimates show quite a high initial investment but the operating costs appear to be favorable compared to other methods of recovery.

Physical Chemistry of Electrolyte Solutions

Physical Chemistry of Electrolyte Solutions
Author: Josef Barthel
Publisher: Springer Science & Business Media
Total Pages: 434
Release: 1998-04
Genre: Science
ISBN: 9783798510760

The aim and purpose of this book is a survey of our actual basic knowledge of electrolyte solutions. It is meant for chemical engineers looking for an introduction to this field of increasing interest for various technologies, and for scientists wishing to have access to the broad field of modern electrolyte chemistry.

Lithium-ion Batteries: Solid-electrolyte Interphase

Lithium-ion Batteries: Solid-electrolyte Interphase
Author: Perla B Balbuena
Publisher: World Scientific
Total Pages: 424
Release: 2004-05-07
Genre: Science
ISBN: 1783260963

This invaluable book focuses on the mechanisms of formation of a solid-electrolyte interphase (SEI) on the electrode surfaces of lithium-ion batteries. The SEI film is due to electrochemical reduction of species present in the electrolyte. It is widely recognized that the presence of the film plays an essential role in the battery performance, and its very nature can determine an extended (or shorter) life for the battery. In spite of the numerous related research efforts, details on the stability of the SEI composition and its influence on the battery capacity are still controversial. This book carefully analyzes and discusses the most recent findings and advances on this topic./a

Activity Coefficients in Electrolyte Solutions

Activity Coefficients in Electrolyte Solutions
Author: Kenneth S. Pitzer
Publisher: CRC Press
Total Pages: 552
Release: 2018-05-04
Genre: Science
ISBN: 1351077929

This book was first published in 1991. It considers the concepts and theories relating to mostly aqueous systems of activity coefficients.

New Promising Electrochemical Systems for Rechargeable Batteries

New Promising Electrochemical Systems for Rechargeable Batteries
Author: V. Barsukov
Publisher: Springer Science & Business Media
Total Pages: 518
Release: 2013-11-09
Genre: Science
ISBN: 9400916434

The storage of electroenergy is an essential feature of modem energy technologies. Unfortunately, no economical and technically feasible method for the solution of this severe problem is presently available. But electrochemistry is a favourite candidate from an engineering point of view. It promises the highest energy densities of all possible alternatives. If this is true, there will be a proportionality between the amount of electricity to be stored and the possible voltage, together with the mass of materials which make this storage possible. Insofar it is a matter of material science to develop adequate systems. Electricity is by far the most important secondary energy source. The present production rate, mainly in the thermal electric power stations, is in the order of 1.3 TW. Rechargeable batteries (RB) are of widespread use in practice for electroenergy storage and supply. The total capacity of primary and rechargeable batteries being exploited is the same as that of the world electric power stations. However, the important goal in the light of modem energy technology, namely the economical storage of large amounts of electricity for electric vehicles, electric route transport, load levelling, solar energy utilization, civil video & audio devices, earth and spatial communications, etc. will not be met by the presently available systems. Unless some of the new emerging electrochemical systems are established up to date, RB's based on aqueous acidic or alkali accumulators are mainly produced today.