Electrolytic Dissolution of Nuclear Fuels
Author | : J. R. Aylward |
Publisher | : |
Total Pages | : 30 |
Release | : 1962 |
Genre | : Reactor fuel reprocessing |
ISBN | : |
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Author | : J. R. Aylward |
Publisher | : |
Total Pages | : 30 |
Release | : 1962 |
Genre | : Reactor fuel reprocessing |
ISBN | : |
Author | : J. R. Aylward |
Publisher | : |
Total Pages | : 32 |
Release | : 1961 |
Genre | : Reactor fuel reprocessing |
ISBN | : |
Author | : |
Publisher | : |
Total Pages | : |
Release | : 1962 |
Genre | : |
ISBN | : |
The potential-current density relationships for 304 stainless steel dissolution in a nitrate system were studied as a function of solution composition and temperature in order to optimize the conditions for electrolytic dissolution of ihis material. In the nitrate system, the anodic dissolution of steel takes place in the transpassive region. Under some conditions, deviations from Tafel behavior are observed which depend greatly on the nitrate and hydrogen ion concentration, and on temperature. A discussion of passivity, transpassivity, secondary passivation, the limiting current density, and the effect of alloy composition on the dissolution behavior is given. It was found that at temperatures above 60 deg C efficient dissolver operation should be possible over a wide range of solution compositions and at current densities up to 2 amp/cm/sup 2/. (auth).
Author | : M. R. Bomar |
Publisher | : |
Total Pages | : 28 |
Release | : 1961 |
Genre | : Electrolytic oxidation |
ISBN | : |
Author | : |
Publisher | : |
Total Pages | : |
Release | : 1961 |
Genre | : |
ISBN | : |
A dissolver design was demonstrated on a laboratory scale for the electrolytic dissolution of nuclear fuels. Simplified electrodes are used which need not touch the fuel pieces, thus avoiding the usual problems of achieving adequate electrical contact between the fuel and the anode basket. Because a series of electrolytic cells are formed along the length of the dissolver, current efficiency is enormously increased; this technique allows for the use of higher voltage and much lower current than is presently considered essential in plant-scale electrolytic dissolution. (auth).
Author | : Vincent P. Caracciolo |
Publisher | : |
Total Pages | : 36 |
Release | : 1964 |
Genre | : Electrolytic oxidation |
ISBN | : |