Electrolyte Solutions
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| Author | : Margaret Robson Wright |
| Publisher | : John Wiley & Sons |
| Total Pages | : 603 |
| Release | : 2007-06-05 |
| Genre | : Science |
| ISBN | : 0470842938 |
An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.
| Author | : Lloyd L Lee |
| Publisher | : World Scientific |
| Total Pages | : 295 |
| Release | : 2021-01-07 |
| Genre | : Technology & Engineering |
| ISBN | : 9811233012 |
Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.
| Author | : Ivan D. Zaytsev |
| Publisher | : CRC Press |
| Total Pages | : 1782 |
| Release | : 1992-08-24 |
| Genre | : Science |
| ISBN | : 9780849393143 |
Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources, and other such activities. This edition, the first available in English, has been substantially revised and augmented. Many new tables have been added because of a significantly larger list of electrolytes and their properties (electrical conductivity, boiling and freezing points, pressure of saturated vapors, activity and diffusion coefficients). The book is divided into two sections. The first section provides tables that list the properties of binary aqueous solutions of electrolytes, while the second section deals with the methods for calculating their properties in multicomponent systems. All values are given in PSI units or fractional and multiple units. Metrological characteristics of the experimental methods used for the determination of physico-chemical parameters are indicated as a relative error and those of the computational methods as a relative error or a root-mean square deviation.
| Author | : R. Mills |
| Publisher | : Elsevier |
| Total Pages | : 355 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 1483290670 |
This compilation - the first of its kind - fills a real gap in the field of electrolyte data. Virtually all self-diffusion data in electrolyte solutions as reported in the literature have been examined and the book contains over 400 tables covering diffusion in binary and ternary aqueous solutions, in mixed solvents, and of non-electrolytes in various solvents. An important feature of the compilation is that all data have been critically examined and their accuracy assessed. Other features are an introductory chapter in which the methods of measurement are reviewed; appendices containing tables of the limiting self-diffusion coefficients of ions; and a list of references to data which have been omitted but where information about the diffusing system is given. This is the only complete compilation of self-diffusion data in electrolyte solutions. It will appeal to electrochemists in general, particularly now that recent developments in the theory of transport processes require these data. It will also have a special appeal to electroanalytical chemists in that the ionic self-diffusion coefficient is an important quantity for the interpretation of electrode reactions. In addition, the book will interest geochemists and environmental chemists because the migration of radioactive ions from nuclear waste in certain aqueous media will be governed by the tracer-diffusion coefficient.
| Author | : Josef Barthel |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 434 |
| Release | : 1998-04 |
| Genre | : Science |
| ISBN | : 9783798510760 |
The aim and purpose of this book is a survey of our actual basic knowledge of electrolyte solutions. It is meant for chemical engineers looking for an introduction to this field of increasing interest for various technologies, and for scientists wishing to have access to the broad field of modern electrolyte chemistry.
| Author | : Kenneth S. Pitzer |
| Publisher | : CRC Press |
| Total Pages | : 552 |
| Release | : 2018-05-04 |
| Genre | : Science |
| ISBN | : 1351077929 |
This book was first published in 1991. It considers the concepts and theories relating to mostly aqueous systems of activity coefficients.
| Author | : H. C. Van Ness |
| Publisher | : Elsevier |
| Total Pages | : 176 |
| Release | : 2013-10-22 |
| Genre | : Science |
| ISBN | : 148322547X |
Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.
| Author | : Norihiro Matubayasi |
| Publisher | : CRC Press |
| Total Pages | : 226 |
| Release | : 2013-09-09 |
| Genre | : Science |
| ISBN | : 1439880875 |
Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a detailed and systematic analysis of the properties of ions at the air/water interface. Unifying older and newer theories and measurements, this book emphasizes the contributions of simple ions to surface tension behavior, and the practical consequences. It begins with a general discussion on Gibbs surface thermodynamics, offering a guide to his theoretical insight and formulation of the boundary between fluids. The text then discusses the thermodynamic formulae that are useful for practical experimental work in the analysis of fluid/fluid interfaces. Chapters cover surface tension of pure water at air/water and air/oil interfaces, surface tension of solutions and the thermodynamic quantities associated with the adsorption and desorption of solutes, and surface tension of simple salt solutions. They also address adsorption of ions at the air/water interface, surface tension of solutions and the effect of temperature, adsorption from mixed electrolyte solutions, and thermodynamic properties of zwitterionic amino acids in the surface region. Focusing on the thermodynamic properties of ions at air/fluid interfaces, this book gives scientists a quantitative, rigorous, and objectively experimental methodology they can employ in their research.
| Author | : Hans Helmut Gunter Jellinek |
| Publisher | : |
| Total Pages | : 16 |
| Release | : 1974 |
| Genre | : Adhesion |
| ISBN | : |
Experiments by Smith-Johannsen on the adhesion of ice frozen from a number of 0.001 M electrolyte solutions to a wax-treated aluminum surface at -10C are discussed. It is concluded that the adhesive strength measured by the force per square centimeter needed to shear the ice off the substrate surface is mainly due to a liquid interfacial solution layer between the ice and the substrate surface. The thickness of such a layer is largely determined by the same considerations as the thickness of grain boundary layers in ice obtained from dilute electrolyte solutions. (Author).
| Author | : Pierre Turq |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 222 |
| Release | : 2012-12-06 |
| Genre | : Science |
| ISBN | : 3642487556 |
The presence of freely moving charges gives peculiar properties to electrolyte solutions, such as electric conductance, charge transfer, and junction potentials in electrochemical systems. These charges play a dominant role in transport processes, by contrast with classical equilibrium thermodynamics which considers the electrically neutral electrolyte compounds. The present status of transport theory does not permit a first prin ciples analys1s of all transport phenomena with a detailed model of the relevant interactions. Host of the models are still unsufficient for real systems of reasonable complexity. The Liouville equation may be adapted with some Brownian approximations to problems of interact ing solute particles in a continuum (solvent>; however, keeping the Liouville level beyond the limiting laws is an unsolvable task. Some progress was made at the Pokker-Planck level; however, despite a promising start, this theory in its actual form is still unsatis factory for complex systems involving many ions and chemical reac tions. A better approach is provided by the so-called Smoluchowski level in which average velocities are used, but there the hydrodyna mic interactions produce some difficulties. The chemist or chemical engineer, or anyone working with complex electrolyte solutions in applied research wants a general representa tion of the transport phenomena which does not reduce the natural complexity of the multicomponent systems. Reduction of the natural complexity generally is connected with substantial changes of the systems.
