Development Of New Late Transition Metal Catalysts For The Oligomerisation Of Ethene
Download Development Of New Late Transition Metal Catalysts For The Oligomerisation Of Ethene full books in PDF, epub, and Kindle. Read online free Development Of New Late Transition Metal Catalysts For The Oligomerisation Of Ethene ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
| Author | : Ray Hoff |
| Publisher | : John Wiley & Sons |
| Total Pages | : 895 |
| Release | : 2018-04-20 |
| Genre | : Technology & Engineering |
| ISBN | : 1119242215 |
Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
| Author | : Bernhard Rieger |
| Publisher | : John Wiley & Sons |
| Total Pages | : 345 |
| Release | : 2006-03-06 |
| Genre | : Technology & Engineering |
| ISBN | : 3527605266 |
At the start of the 1950s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in 1963. In the 80s and 90s, the development of molecular defined metallocenes led to a renaissance for non-polar polyolefin materials. Designer catalysts allowed a greater precision in defining properties of the material. The past 10 years have seen the discovery of new catalysts based on late transition metals, which allow the combination of polar monomers with non-polar olefins and thus lead to innovative materials. Here, the world's leading authors from industry and academia describe the latest developments in this fascinating field for the first time in such comprehensive detail. In so doing, they introduce readers systematically to the basic principles and show how these new catalysts can effectively be used for polymerization reactions. This makes the book an ideal and indispensable reference for specialists, advanced students, and scientists of various disciplines dealing with research into catalysts and materials science.
| Author | : Giuliano Giambastiani |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 296 |
| Release | : 2011-04-29 |
| Genre | : Science |
| ISBN | : 9048138159 |
This book highlights key advances that have occurred in the field of olefin conversion in recent years. The role of homogenous transition metal catalysts which contain an imine functionality is emphasized; their potential applications in the processing and upgrade of olefins to a wide variety of commodity products of very high industrial value is also explored. On the threshold of the fiftieth anniversary of the Noble Prize to Ziegler and Natta, this book gives a critical summary of the state of the art developments in the fascinating and rapidly developing field of the olefin polymerization, oligomerization, and co-polymerization catalysis.
| Author | : Gernot Frenking |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 284 |
| Release | : 2005-06-23 |
| Genre | : Science |
| ISBN | : 9783540235101 |
Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.
| Author | : Kohtaro Osakada |
| Publisher | : Springer |
| Total Pages | : 307 |
| Release | : 2014-07-15 |
| Genre | : Technology & Engineering |
| ISBN | : 366243539X |
This compilation provides advanced graduate students and researchers with a structured overview of olefin polymerization. Divided into eight chapters written by international experts, this book covers polymerization using various organotransition-metal catalysts, including early and late transition metal complexes, new trends in olefin oligomerization and related reactions. All authors address the historic and scientific backgrounds of the field as well as current research progress and potential for further research. The complete book is designed to present eight independent lectures and, because all authors are well versed in organometallic chemistry, each is based on a profound understanding of the reactions and structures of organotransition metal complexes. This book is an ideal accompaniment for researchers taking courses in olefin polymerization and also serves as a valuable resource for teachers and lecturers of chemistry when planning and researching material for advanced lecture courses.
| Author | : |
| Publisher | : Newnes |
| Total Pages | : 7694 |
| Release | : 2013-07-23 |
| Genre | : Science |
| ISBN | : 0080965296 |
Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973
| Author | : Giuliano GIAMBASTIANI |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 272 |
| Release | : 2011-05-19 |
| Genre | : Science |
| ISBN | : 9400706960 |
Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II: State-of-the-art and Perspectives provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands. All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.
| Author | : Zhibin Guan |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 262 |
| Release | : 2009-03-31 |
| Genre | : Science |
| ISBN | : 3540877509 |
Polyolefin is a major industry that is important for our economy and impacts every aspect of our lives. The discovery of new transition metal-based catalysts is one of the driving forces for the further advancement of this field. Whereas the classical heterogeneous Ziegler-Natta catalysts and homogeneous early transition metal metallocene catalysts remain the workhorses of the polyolefin industry, in roughly the last decade, tremendous progress has been made in developing non-metallocene-based olefin polymerization catalysts. Particularly, the discovery of late transition metal-based olefin polymerization catalysts heralds a new era for this field. These late transition metal complexes not only exhibit high activities rivaling their early metal counterparts, but more importantly they offer unique properties for polymer architectural control and copolymerization with polar olefins. In this book, the most recent major breakthroughs in the development of new olefin polymerization catalysts, including early metal metallocene and non-metallocene complexes and late transition metal complexes, are discussed by leading experts. The authors highlight the most important discoveries in catalysts and their applications in designing new polyolefin-based functional materials.
| Author | : R. Blom |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 448 |
| Release | : 2012-12-06 |
| Genre | : Technology & Engineering |
| ISBN | : 3642594654 |
"Catalysis is more art than science", probably all of you have heard and even used this expression. Whether it is true or not, it alludes to the experience that new catalysts are hard to find, and near impossible to predict. Hard work and a lifetime of experience is invaluable. However, a keen mind might give insight into where to search, but not necessarily about where to find the answers. Historically, "quantum leaps" have often arisen from serendipity - we all know the story about the nickel-contaminated reactor that triggered further research towards the first coordination catalyst for ethene polymerization. Taking advan tage of this event, Karl Ziegler became the first chemist to earn both a Nobel prize and a fortune for the same invention. A broken NMR tube helped Walter Kaminsky discover the effect of high concentrations of methylaluminoxanes as co catalysts for metallocenes. When air reacted with the concentrated trim ethyl aluminum solution, sufficient amounts of methylaluminoxanes were formed, and the lazy catalyst dormant in the NMR tube suddenly became sensationally active. Ziegler and Kaminsky were lucky and had the genius needed to take advantage of their luck.
| Author | : Claire Lesieur |
| Publisher | : BoD – Books on Demand |
| Total Pages | : 454 |
| Release | : 2014-06-18 |
| Genre | : Science |
| ISBN | : 9535116177 |
Many thanks to the authors for high quality chapters and to the referees for helping improve the manuscripts. The book is interdisciplinary, it covers fields from organic chemistry to mathematics, and raises different aspects of oligomerization. It is a great source of information as every chapter introduces general knowledge and deep details. Mixing communities is to instigate novel ideas and hopefully help looking at oligomerization with new eyes.
