Deuterium Solid State Nmr And Reaction Kinetics Studies Of Solid Acid Catalysts
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Reactions in the Solid State
Author | : Michael E. Brown |
Publisher | : Elsevier |
Total Pages | : 355 |
Release | : 1980-01-01 |
Genre | : Science |
ISBN | : 0080868169 |
The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Kinetics of Heterogeneous Solid State Processes
Author | : Pritam Deb |
Publisher | : Springer Science & Business Media |
Total Pages | : 51 |
Release | : 2013-12-03 |
Genre | : Technology & Engineering |
ISBN | : 813221756X |
Kinetic studies have traditionally being extremely useful in characterizing several physical and chemical phenomena in organic, inorganic and metallic systems. It provides valuable qualitative, quantitative and kinetic information on phase transformations, solid state precipitation, crystallization, oxidation and decomposition. Unfortunately, no single reference comprehensively presents nonisothermal kinetic analysis method for the study of complex processes, determining the actual mechanism and kinetic parameters. This book provides a new method for nonisothermal kinetics and its application in heterogeneous solid state processes. In the backdrop of limitations in existing methods, the book presents a brief review of the widely used isothermal and nonisothermal kinetic analysis methods.
Solid-state NMR Studies of Acidic Catalysts
Author | : Luming Peng |
Publisher | : |
Total Pages | : 189 |
Release | : 2006 |
Genre | : Nuclear magnetic resonance spectroscopy |
ISBN | : 9781109853070 |
The research presented in this dissertation involves the use of probe molecules and solid-state NMR techniques to investigate the local structure of acid catalysts.
A Review of the Reaction Kinetics of Deuterium Compounds
Author | : Lawrence M. Brown |
Publisher | : |
Total Pages | : 124 |
Release | : 1954 |
Genre | : Chemical kinetics |
ISBN | : |
Reactions in the Solid State
Author | : Michael E. Brown |
Publisher | : Elsevier Science |
Total Pages | : 339 |
Release | : 1980-01-15 |
Genre | : Science |
ISBN | : 9780444418074 |
The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.
Solid State Chemistry in Catalysis
Author | : Robert K. Grasselli |
Publisher | : |
Total Pages | : 386 |
Release | : 1985 |
Genre | : Science |
ISBN | : |
Good,No Highlights,No Markup,all pages are intact, Slight Shelfwear,may have the corners slightly dented, may have slight color changes/slightly damaged spine.
Reaction Diffusion and Solid State Chemical Kinetics
Author | : V.I. Dybkov |
Publisher | : Trans Tech Publications Ltd |
Total Pages | : 334 |
Release | : 2010-03-18 |
Genre | : Technology & Engineering |
ISBN | : 3038134457 |
Volume is indexed by Thomson Reuters BCI (WoS). This monograph deals with a physico-chemical approach to the problem of the solid-state growth of chemical compound layers and reaction-diffusion in binary heterogeneous systems formed by two solids; as well as a solid with a liquid or a gas. It is explained why the number of compound layers growing at the interface between the original phases is usually much lower than the number of chemical compounds in the phase diagram of a given binary system. For example, of the eight intermetallic compounds which exist in the aluminium-zirconium binary system, only ZrAl3 was found to grow as a separate layer at the AlZr interface under isothermal conditions. The physico-chemical approach predicts that, in most cases, the number of compound layers should not exceed two; with the main factor, resulting in the appearance of additional layers, being crack formation due to thermal expansion and volume effects.