d-d Excitations in Transition-Metal Oxides

d-d Excitations in Transition-Metal Oxides
Author: Bärbel Fromme
Publisher: Springer
Total Pages: 156
Release: 2007-08-03
Genre: Technology & Engineering
ISBN: 3540453423

In this monograph, investigations of the electronic structures of the transition-metal oxides MnO, CoO, and NiO with spin-polarized electron energy-loss spectroscopy are presented and compared with other experimental and theoretical results. After a review of the present knowledge of the electronic structure of the monoxides, the spectroscopic method applied and its special advantages are described. The knowledge and use of the different spin, angle, and primary-energy dependences of the various relevant inelastic electron-scattering mechanisms provide new insights into the excitation processes of the optically forbidden transitions between the crystal-field-split 3d states of the bulk and of the surface.

Magnetism and Synchrotron Radiation

Magnetism and Synchrotron Radiation
Author: Eric Beaurepaire
Publisher: Springer Science & Business Media
Total Pages: 435
Release: 2010-03-12
Genre: Science
ISBN: 3642044980

Advances in the synthesis of new materials with often complex, nano-scaled structures require increasingly sophisticated experimental techniques that can probe the electronic states, the atomic magnetic moments and the magnetic microstructures responsible for the properties of these materials. At the same time, progress in synchrotron radiation techniques has ensured that these light sources remain a key tool of investigation, e.g. synchrotron radiation sources of the third generation are able to support magnetic imaging on a sub-micrometer scale. With the Fifth Mittelwihr School on Magnetism and Synchrotron Radiation the tradition of teaching the state-of-the-art on modern research developments continues and is expressed through the present set of extensive lectures provided in this volume. While primarily aimed at postgraduate students and newcomers to the field, this volume will also benefit researchers and lecturers actively working in the field.

Resonant X-Ray Scattering in Correlated Systems

Resonant X-Ray Scattering in Correlated Systems
Author: Youichi Murakami
Publisher: Springer
Total Pages: 246
Release: 2016-12-27
Genre: Science
ISBN: 3662532271

The research and its outcomes presented here is devoted to the use of x-ray scattering to study correlated electron systems and magnetism. Different x-ray based methods are provided to analyze three dimensional electron systems and the structure of transition-metal oxides. Finally the observation of multipole orderings with x-ray diffraction is shown.

New Trends in Quantum Systems in Chemistry and Physics

New Trends in Quantum Systems in Chemistry and Physics
Author: J. Maruani
Publisher: Springer Science & Business Media
Total Pages: 310
Release: 2006-04-10
Genre: Science
ISBN: 0306469502

These two volumes collect thirty-eight selected papers from the scientific contributions presented at the Fourth European Workshop on Quantum Systems in Chemistry and Physics (QSCP-IV), held in Marly-le-Roi (France) in April 22-27, 1999. A total of one hundred and fifteen scientists attended the workshop, 99 from Europe and 16 from the rest of the world. They discussed the state of the art, new trends, and future evolution of the methods and applications. The workshop was held in the old town of Marly-le-Roi, which lies to the West of Paris between the historic centres of Saint-Germain-en-Laye and Versailles. Participants were housed at the National Youth Institute, where over sixty lectures were given by l- ding members of the scientific community; in addition, over sixty posters were presented in two very animated sessions. We are grateful to the oral speakers and to the poster p- senters for making the workshop such an stimulating experience. The social programme was also memorable – and not just for the closing banquet, which was held at the French Senate House. We are sure that participants will long remember their visit to the 'Musée des Antiquités Nationales': created by Napoleon III at the birthplace of Louis XIV, this museum boasts one of the world finest collections of archeological artifacts. The Marly-le-Roi workshop followed the format established at the three previous meetings, organized by Prof.

Metal Organic Frameworks as Heterogeneous Catalysts

Metal Organic Frameworks as Heterogeneous Catalysts
Author: Francesc X. Llabrés i Xamena
Publisher: Royal Society of Chemistry
Total Pages: 446
Release: 2013-07-01
Genre: Science
ISBN: 1849735727

This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.

An Introduction to Synchrotron Radiation

An Introduction to Synchrotron Radiation
Author: Philip Willmott, PhD
Publisher: John Wiley & Sons
Total Pages: 501
Release: 2019-03-07
Genre: Science
ISBN: 1119280389

The updated guide to the fundamental concepts, techniques and applications of synchrotron radiation and its applications in this rapidly developing field Synchrotron light is recognized as an invaluable research tool by a broad spectrum of scientists, ranging from physicists to biologists and archaeologists. The comprehensively revised second edition of An Introduction to Synchrotron Radiation offers a guide to the basic concepts of the generation and manipulation of synchrotron light, its interaction with matter and the application of synchrotron light in x-ray scattering, spectroscopy, and imaging. The author, a noted expert in the field, reviews the fundamentals of important experimental methods, and explores the most recent technological advances in both the latest generation of x-ray sources and x-ray instrumentation. Designed to be an accessible resource, the book contains full-colour illustrations of the underlying physics and experimental applications, as well as the most commonly-used synchrotron techniques. In particular, the updated second edition now includes: In-depth descriptions of the latest x-ray-source technologies, notably diffraction-limited storage rings and x-ray free-electron lasers The latest advances in instrumentation, x-ray optics, and experimental methods in synchrotron radiation The most recent developments in macromolecular crystallography, time-resolved studies, and imaging techniques A comprehensive set of problems for each chapter, plus their ideal solutions in the appendices. Written for undergraduate and postgraduate students from all areas of the natural and physical sciences, An Introduction to Synchrotron Radiation, Second Edition is an invaluable up-to-date reference source in this highly multidisciplinary field. PowerPoint slides of all the figures within the text are available for download, for instructors and users of this book, at http://booksupport.wiley.com

Principles and Applications of Density Functional Theory in Inorganic Chemistry II

Principles and Applications of Density Functional Theory in Inorganic Chemistry II
Author: Nikolas Kaltsoyannis
Publisher: Springer Science & Business Media
Total Pages: 264
Release: 2004
Genre: Chemistry
ISBN: 9783540218616

E. Clot, O. Eisenstein: Agostic Interactions from a Computational Perspective: One Name, many Interpretations.- Robert J. Deet: Recent Developments in Computational Bioinorganic Chemistry.- E. Ruiz: Theoretical Study of the Exchange Coupling in Large Polynuclear Transition Metal Complexes Using DFT Methods.- D. Sánches-Portal, P. Ordejón, E. Canadell: Computing the Properties of Materials from First Principles with SIESTA.- F. Corà, M. Alfredsson, G. Mallia, D.S. Middlemiss, W.C. Mackrodt, R. Dovesi, R. Orlando: The Performance of Hybrid Density Functionals in Solid State Chemistry

Nanostructure Control of Materials

Nanostructure Control of Materials
Author: R H J Hannink
Publisher: Woodhead Publishing
Total Pages: 373
Release: 2006-02-28
Genre: Technology & Engineering
ISBN: 1845691180

The ability to measure and manipulate matter on the nanometer level is making possible a new generation of materials with enhanced mechanical, optical, transport and magnetic properties. This important book summarises key developments in nanotechnology and their impact on the processing of metals, polymers, composites and ceramics.After a brief introduction, a number of chapters discuss the practical issues involved in the commercial production and use of nanomaterials. Other chapters review ways of nanoengineering steel, aluminium and titanium alloys. Elsewhere the book discusses the use of nanoengineered metal hydrides to store hydrogen as an energy source, and the development of nanopolymers for batteries and other energy storage devices. Other chapters discuss the use of nanotechnology to enhance the toughness of ceramics, the production of synthetic versions of natural materials such as bone, and the development of nanocomposites.Nanostructure control of materials is an ideal introduction to the ways nanotechnology is being used to create new materials for industry. It will be welcomed by R&D managers in such sectors as automotive engineering as well as academics working in this exciting area. - Reviews key developments in nanotechnology and their impact on various materials - Edited by leading experts in the field

Capillary Surfaces

Capillary Surfaces
Author: Dieter W. Langbein
Publisher: Springer Science & Business Media
Total Pages: 388
Release: 2002-01-29
Genre: Technology & Engineering
ISBN: 3540418156

Featuring a foreword by the astronaut Ulf Merbold, this book is devoted to interfaces between two fluids, that is, between a liquid and a gas or between two liquids. It is the first review on the subject, providing an up-to-date overview.

Physics of Transition Metal Oxides

Physics of Transition Metal Oxides
Author: Sadamichi Maekawa
Publisher: Springer Science & Business Media
Total Pages: 356
Release: 2004-06-22
Genre: Technology & Engineering
ISBN: 9783540212935

The fact that magnetite (Fe304) was already known in the Greek era as a peculiar mineral is indicative of the long history of transition metal oxides as useful materials. The discovery of high-temperature superconductivity in 1986 has renewed interest in transition metal oxides. High-temperature su perconductors are all cuprates. Why is it? To answer to this question, we must understand the electronic states in the cuprates. Transition metal oxides are also familiar as magnets. They might be found stuck on the door of your kitchen refrigerator. Magnetic materials are valuable not only as magnets but as electronics materials. Manganites have received special attention recently because of their extremely large magnetoresistance, an effect so large that it is called colossal magnetoresistance (CMR). What is the difference between high-temperature superconducting cuprates and CMR manganites? Elements with incomplete d shells in the periodic table are called tran sition elements. Among them, the following eight elements with the atomic numbers from 22 to 29, i. e. , Ti, V, Cr, Mn, Fe, Co, Ni and Cu are the most im portant. These elements make compounds with oxygen and present a variety of properties. High-temperature superconductivity and CMR are examples. Most of the textbooks on magnetism discuss the magnetic properties of transition metal oxides. However, when one studies magnetism using tradi tional textbooks, one finds that the transport properties are not introduced in the initial stages.