Cyclobutadiene And Related Compounds
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| Author | : M.P. Cava |
| Publisher | : Elsevier |
| Total Pages | : 519 |
| Release | : 2012-12-02 |
| Genre | : Science |
| ISBN | : 0323163122 |
Cyclobutadiene and Related Compounds describes the four-membered carbocyclic compounds that have only trigonally hybridized carbon atoms in the ring. The book discusses the chemistry of cyclobutadiene and the substituted cyclobutadienes, including the preparation of cyclobutadiene-metal complexes that can be done in four ways. These are (1) by reaction of acetylenes with transition metal compounds, (2) from cyclobutenyl metal complexes, (3) by transformation of other cyclobutadiene-metal complexes, and (4) by trapping cyclobutadienes with transitional metal compounds. The text also describes cyclobutadiene dianion, the chemistry of the cyclobutadienequinones, the condensed methylenecyclobutene aromatic systems, and the higher aromatic analogs of benzocyclobutadiene. The book cites proofs of the structure of biphenylene using chemical and physical methods. The text also presents theoretical aspects of the cyclobutadiene problem including studies regarding the ?-electronic state of cyclobutadiene; the comparisons of some of these studies; the framework energies and Janh-Teller considerations; and the substituted cyclobutadienes, cyclobutadiene divalent ions, and metal complexes. This book is suitable for scientists and researchers working in the field of organic chemistry, analytical chemistry, and molecular physics.
| Author | : Steven M. Bachrach |
| Publisher | : John Wiley & Sons |
| Total Pages | : 653 |
| Release | : 2014-04-07 |
| Genre | : Science |
| ISBN | : 1118291921 |
The Second Edition demonstrates how computational chemistry continues to shed new light on organic chemistry The Second Edition of author Steven Bachrach’s highly acclaimed Computational Organic Chemistry reflects the tremendous advances in computational methods since the publication of the First Edition, explaining how these advances have shaped our current understanding of organic chemistry. Readers familiar with the First Edition will discover new and revised material in all chapters, including new case studies and examples. There’s also a new chapter dedicated to computational enzymology that demonstrates how principles of quantum mechanics applied to organic reactions can be extended to biological systems. Computational Organic Chemistry covers a broad range of problems and challenges in organic chemistry where computational chemistry has played a significant role in developing new theories or where it has provided additional evidence to support experimentally derived insights. Readers do not have to be experts in quantum mechanics. The first chapter of the book introduces all of the major theoretical concepts and definitions of quantum mechanics followed by a chapter dedicated to computed spectral properties and structure identification. Next, the book covers: Fundamentals of organic chemistry Pericyclic reactions Diradicals and carbenes Organic reactions of anions Solution-phase organic chemistry Organic reaction dynamics The final chapter offers new computational approaches to understand enzymes. The book features interviews with preeminent computational chemists, underscoring the role of collaboration in developing new science. Three of these interviews are new to this edition. Readers interested in exploring individual topics in greater depth should turn to the book’s ancillary website www.comporgchem.com, which offers updates and supporting information. Plus, every cited article that is available in electronic form is listed with a link to the article.
| Author | : Herbert W Roesky |
| Publisher | : Academic Press |
| Total Pages | : 540 |
| Release | : 2016-05-12 |
| Genre | : Science |
| ISBN | : 0128035684 |
Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry. - Includes contributions and edits from leading experts in the field - Includes detailed chemical schemes and useful references for each preparative method - Organized by the coordination numbers of the central silicon atom for each compound for easy navigation - Serves as a go-to primer for researchers in novel compositions of silicon matter
| Author | : George A Olah |
| Publisher | : World Scientific |
| Total Pages | : 1503 |
| Release | : 2003-01-29 |
| Genre | : Science |
| ISBN | : 9814498548 |
In the course of his distinguished career spanning about half a century, George A Olah, winner of the 1994 Nobel Prize for Chemistry, has been exceedingly prolific and has published more than 1000 scientific papers and 15 books and holds more than 100 patents. This invaluable volume contains about 250 papers selected for their breadth and current importance.
| Author | : Stephen G. Brush |
| Publisher | : Oxford University Press |
| Total Pages | : 553 |
| Release | : 2015-04-13 |
| Genre | : Science |
| ISBN | : 0190266945 |
Historically, the scientific method has been said to require proposing a theory, making a prediction of something not already known, testing the prediction, and giving up the theory (or substantially changing it) if it fails the test. A theory that leads to several successful predictions is more likely to be accepted than one that only explains what is already known but not understood. This process is widely treated as the conventional method of achieving scientific progress, and was used throughout the twentieth century as the standard route to discovery and experimentation. But does science really work this way? In Making 20th Century Science, Stephen G. Brush discusses this question, as it relates to the development of science throughout the last century. Answering this question requires both a philosophically and historically scientific approach, and Brush blends the two in order to take a close look at how scientific methodology has developed. Several cases from the history of modern physical and biological science are examined, including Mendeleev's Periodic Law, Kekule's structure for benzene, the light-quantum hypothesis, quantum mechanics, chromosome theory, and natural selection. In general it is found that theories are accepted for a combination of successful predictions and better explanations of old facts. Making 20th Century Science is a large-scale historical look at the implementation of the scientific method, and how scientific theories come to be accepted.
| Author | : Norman Kharasch |
| Publisher | : Elsevier |
| Total Pages | : 357 |
| Release | : 2013-10-22 |
| Genre | : Reference |
| ISBN | : 1483149374 |
Index to Reviews, Symposia Volumes and Monographs in Organic Chemistry for the Period 1940-1960 presents a resume of published monographs, reviews, and symposia lectures in organic chemistry. The editors adopted the plan of listings by symposia volume or journal, backed up by the total subject and author indexes. In this way the user can readily locate a particular article through the author index or the subject index; or should he recall that an article appeared in a particular source, the chronological listing in that source can be scanned quickly. The Index gives a convenient overview of the accomplishments of organic chemists during this very prolific period of the growth of the field. Frequently, several articles on the same or similar subject appear, hence the historical perspective can be sensed by rapid evaluation of the reviews selected. This Index will be useful to research workers, teachers and students. It will also assist editors and authors to select specific areas which require critical review.
| Author | : Francis A. Carey |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 1213 |
| Release | : 2007-06-13 |
| Genre | : Science |
| ISBN | : 0387448977 |
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.
| Author | : Vladimir Ya. Lee |
| Publisher | : John Wiley & Sons |
| Total Pages | : 1531 |
| Release | : 2023-03-16 |
| Genre | : Science |
| ISBN | : 1119613523 |
Organogermanium Compounds Understand the chemistry of organogermanium compounds with this thorough and cutting-edge reference Discovered comparatively late in the history of chemistry, germanium has become one of the most technology-critical elements in modern industry. Germanium and its inorganic and organic derivatives found widespread applications in fiber- and infrared-optics, electronics, polymerization catalysis, solar electric technology, nanotechnology, chemotherapy, and more. Organogermanium compounds containing carbon to germanium chemical bonds, have applications in microelectronics, medicinal and health industries, and beyond. Organogermanium Compounds: Theory, Experiment, and Applications, 2 Volume Set provides a comprehensive review of this class of compounds in two thorough volumes. It covers all modern aspects of these critically important compounds, including theoretical, synthetic, physico-chemical, and applied research. Reflecting the latest breakthroughs in this rapidly growing field, this book promises to serve as the high-level reference for those readers who are interested in organogermanium chemistry. Organogermanium Compounds readers will also find: 19 chapters produced by leading global experts Descriptions of pivotal historical achievements in organogermanium research Coverage of the latest computational, synthetic, and applied breakthroughs Organogermanium Compounds is a critical reference for researchers and professionals in a wide range of academic and industrial fields working with these fascinating compounds. This will also be helpful for university and college students, at both graduate and undergraduate levels.
| Author | : Frank H. Herbstein |
| Publisher | : Oxford University Press, USA |
| Total Pages | : 722 |
| Release | : 2005 |
| Genre | : Science |
| ISBN | : 9780198568933 |
This book provides an account of the structure and properties of crystalline binary adducts. Such crystals are perhaps better known as molecular compounds and complexes and are estimated to make up one quarter of the world's crystals. More than 600 figures, 200 tables and 3500 references are included in the book.
| Author | : Donald J Cram |
| Publisher | : Royal Society of Chemistry |
| Total Pages | : 240 |
| Release | : 2007-10-31 |
| Genre | : Science |
| ISBN | : 1847550622 |
Container Molecules and Their Guests deals with the fundamental principles and objectives that govern this rapidly developing subject and illustrates the emergence of a new field of biomimetic chemistry. The book demonstrates how a number of techniques, such as molecular modelling, synthesis, crystal structure, NMR solution structure and mass spectral structure determinations can be combined to develop a new branch of organic chemistry. It discusses the chemistry of completely new families of complexes - the carceplexes, hemicarceplexes and velcraplexes - and reviews for the first time the uses of the interiors of hemicarceplexes as a new phase for carrying out chemical reactions and for protecting unstable species. Furthermore, it illustrates how complexation and decomplexation rates are measured to provide free energies of binding, discusses new phenomena such as constrictive binding, and shows how solvophobic forces drive complexation in a variety of organic solvents. It also covers catalysis through complexation and chiral recognition in catalysis, both secondary themes of this volume. Container Molecules and Their Guests will provide stimulating reading for researchers, post-graduate students and teachers involved in bio-organic chemistry, organic chemistry, materials science, and medicinal and pharmaceutical chemistry.
