Structural Chemistry of Inorganic Actinide Compounds

Structural Chemistry of Inorganic Actinide Compounds
Author: Sergey Krivovichev
Publisher: Elsevier
Total Pages: 505
Release: 2006-12-08
Genre: Science
ISBN: 0080467911

Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'

Chemical Thermodynamics of Neptunium and Plutonium

Chemical Thermodynamics of Neptunium and Plutonium
Author: Robert J. Lemire
Publisher: Elsevier
Total Pages: 876
Release: 2001-08-26
Genre: Medical
ISBN: 9780444503794

Unlike earlier books in this series, this review describes the selection of chemical thermodynamic data for species of two elements, neptunium and plutonium. Although this came about more by circumstance than design, it has allowed for a more consistent approach to chemical interpretation than might have occurred in two separate treatments. It has also drawn attention to cases where the available data do not show expected parallels, and where further work may be useful to confirm or refute apparent differences in the behaviour of neptunium and plutonium.

The Crystal Structure of Plutonium Sesquicarbide

The Crystal Structure of Plutonium Sesquicarbide
Author: W. H. Zachariasen
Publisher:
Total Pages: 22
Release: 1951
Genre: Crystals
ISBN:

It is the purpose of the present paper to describe crystal structure determination of Pu2C3 in some detail. In the preliminary account of the investigation the identification of Pu2C3 was given as tentative in character. The uncertainty of the identification was later removed, and the identity is, of course, further confirmed by the recent identification of a corresponding uranium compound.