Heterocycles Via Cross Dehydrogenative Coupling

Heterocycles Via Cross Dehydrogenative Coupling
Author: Ananya Srivastava
Publisher:
Total Pages: 498
Release: 2019
Genre: Heterocyclic chemistry
ISBN: 9789811391453

This book discusses the developments in the synthesis and functionalization of different heterocycles based on the formation of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds using cross-dehydrogenative coupling (CDC). Consisting of 13 chapters, the book systematically describes the advances in the synthesis and functionalization of nitrogen, oxygen, and sulfur-containing heterocycles. It also discusses the various mechanistic pathways to help readers gain an in-depth understanding of the CDC reactions of heterocycles. Lastly, in order to promote green chemistry, it addresses a range of metal-free CDC reactions of heterocycles - an area that has attracted significant attention in both academic and industrial research.

From C-H to C-C Bonds

From C-H to C-C Bonds
Author: Chao-Jun Li
Publisher: Royal Society of Chemistry
Total Pages: 330
Release: 2014-09-30
Genre: Science
ISBN: 1849737975

This book examines the first ten years of this rapidly-expanding field, providing the reader with the knowledge to develop new syntheses in keeping with the principles of Green Chemistry.

Organic Reaction Mechanisms 2014

Organic Reaction Mechanisms 2014
Author: A. C. Knipe
Publisher: John Wiley & Sons
Total Pages: 1024
Release: 2017-11-27
Genre: Science
ISBN: 1118941802

Organic Reaction Mechanisms 2014, the 50th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2014. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. This volume includes a 5-year cumulative index.

Aromatic C(sp2)−H Dehydrogenative Coupling Reactions

Aromatic C(sp2)−H Dehydrogenative Coupling Reactions
Author: Bagher Eftekhari-Sis
Publisher: CRC Press
Total Pages: 295
Release: 2019-10-31
Genre: Science
ISBN: 1000733912

This comprehensive text covers the research and development trends in the growing field of aromatic C–H dehydrogenative coupling reactions, leading to different types of heterocycles. The author provides answers to how these coupling reactions occur, what kinds of heterocycles are synthesized, and what their advantages are. The palladium-, rhodium-, iridium-, copper-, cobalt-, ruthenium-, and ferric-catalyzed aromatic C(sp2)–H dehydrogenative cross-coupling reactions are described in detail. A useful reference source for researchers and graduates in the field of heterocyclic chemistry and transition-metal-catalyzed dehydrogenative coupling reactions. Features: Comprehensive volume on the synthesis of benzo-heterocycles via aromatic C(sp2)–H bond activation. Heterocycles are of paramount importance to medicinal chemistry and drug discovery. Provides a comprehensive literature survey on the construction of heterocycles. Reaction procedures and mechanistic explanations are included, which will appeal to those in fine chemicals and pharmaceutical companies.

Oxidative Cross-Coupling Reactions

Oxidative Cross-Coupling Reactions
Author: Aiwen Lei
Publisher: John Wiley & Sons
Total Pages: 240
Release: 2016-08-12
Genre: Technology & Engineering
ISBN: 3527681019

The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.

Organic Electrochemistry

Organic Electrochemistry
Author: Ole Hammerich
Publisher: CRC Press
Total Pages: 1706
Release: 2015-09-22
Genre: Science
ISBN: 142008402X

Praise for the Fourth Edition"Outstanding praise for previous editions.the single best general reference for the organic chemist."-Journal of the Electrochemical Society"The cast of editors and authors is excellent, the text is, in general, easily readable and understandable, well documented, and well indexed those who purchase the book will be sa

The Nitro Group in Organic Synthesis

The Nitro Group in Organic Synthesis
Author: Noboru Ono
Publisher: John Wiley & Sons
Total Pages: 392
Release: 2003-05-08
Genre: Science
ISBN: 0471458465

The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include: * Henry reaction * Asymmetric Michael addition * Alkylation, acylation, halogenation, and related reactions of RNO2 * Substitution and elimination of NO2 and RNO2 The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.

Fluorine Chemistry at the Millennium

Fluorine Chemistry at the Millennium
Author: R.E. Banks
Publisher: Elsevier
Total Pages: 661
Release: 2000-12-04
Genre: Science
ISBN: 0080531792

This volume brings together contributions by leading researchers covering a wide scope so characteristic of fluorine chemistry. It is a monograph of historical character comprising personalized accounts of progress and events in areas of particular interest.There is also much to interest and instruct chemists from other disciplines as a good proportion of the chapters contain a considerable amount of 'hard' referenced information relating to modern organic, organoelemental and inorganic chemistry. Historians of chemistry and technology will no doubt be tempted to dip into this book, and surely whoever addresses the task of commemorating Moissan's achievement at the 150-years stage will bless us all in some measure for its existence.

Inventing Reactions

Inventing Reactions
Author: Lukas J. Gooßen
Publisher: Springer
Total Pages: 345
Release: 2012-10-30
Genre: Science
ISBN: 3642342868

Barry Trost: Transition metal catalyzed allylic alkylation.- Jeffrey W. Bode: Reinventing Amide Bond Formation.- Naoto Chatani and Mamoru Tobisu: Catalytic Transformations Involving the Cleavage of C-OMe Bonds.- Gregory L. Beutner and Scott E. Denmark: The Interplay of Invention, Observation and Discovery in the Development of Lewis Base Activation of Lewis Acids for Catalytic Enantioselective Synthesis.- David R. Stuart and Keith Fagnou: The Discovery and Development of a Palladium(II)-Catalyzed Oxidative Cross-Coupling of Two Unactivated Arenes.- Lukas Gooßen and Käthe Gooßen: Decarboxylative Cross-Coupling Reactions.- A. Stephen K. Hashmi: Gold-Catalyzed Organic Reactions.- Ben List: Developing Catalytic Asymmetric Acetalizations.- Steven M. Bischof, Brian G. Hashiguchi, Michael M. Konnick, and Roy A. Periana: The De NovoDesign of CH Bond Hydroxylation Catalysts.- Benoit Cardinal-David, Karl A. Scheidt: Carbene Catalysis: Beyond the Benzoin and Stetter Reactions.- Kenso Soai and Tsuneomi Kawasaki: Asymmetric autocatalysis of pyrimidyl alkanol.- Douglas C. Behenna and Brian M. Stoltz: Natural Products as Inspiration for Reaction Development: Catalytic Enantioselective Decarboxylative Reactions of Prochiral Enolate Equivalents. Hisashi Yamamoto: Acid Catalysis in Organic Synthesis.

Sustainable Organic Synthesis

Sustainable Organic Synthesis
Author: Dr Stefano Protti
Publisher: Royal Society of Chemistry
Total Pages: 602
Release: 2021-10-29
Genre: Science
ISBN: 1839162031

Recent years have seen huge growth in the area of sustainable chemistry. In order to meet the chemical needs of the global population whilst minimising impacts on health and the environment it is essential to keep reconsidering and improving synthetic processes. Sustainable Organic Synthesis is a comprehensive collection of contributions, provided by specialists in Green Chemistry, covering topics ranging from catalytic approaches to benign and alternative reaction media, and innovative and more efficient technologies.