Combinatorial Discovery And Optimization Of The Composition Doping And Morphology Of New Oxide Semiconductors For Efficient Photoelectrochemical Water Splitting
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| Author | : Zhebo Chen |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 130 |
| Release | : 2013-08-28 |
| Genre | : Science |
| ISBN | : 1461482984 |
This book outlines many of the techniques involved in materials development and characterization for photoelectrochemical (PEC) – for example, proper metrics for describing material performance, how to assemble testing cells and prepare materials for assessment of their properties, and how to perform the experimental measurements needed to achieve reliable results towards better scientific understanding. For each technique, proper procedure, benefits, limitations, and data interpretation are discussed. Consolidating this information in a short, accessible, and easy to read reference guide will allow researchers to more rapidly immerse themselves into PEC research and also better compare their results against those of other researchers to better advance materials development. This book serves as a “how-to” guide for researchers engaged in or interested in engaging in the field of photoelectrochemical (PEC) water splitting. PEC water splitting is a rapidly growing field of research in which the goal is to develop materials which can absorb the energy from sunlight to drive electrochemical hydrogen production from the splitting of water. The substantial complexity in the scientific understanding and experimental protocols needed to sufficiently pursue accurate and reliable materials development means that a large need exists to consolidate and standardize the most common methods utilized by researchers in this field.
| Author | : Fabian I. Ezema |
| Publisher | : Springer Nature |
| Total Pages | : 926 |
| Release | : 2021-06-26 |
| Genre | : Technology & Engineering |
| ISBN | : 3030684628 |
This book guides beginners in the areas of thin film preparation, characterization, and device making, while providing insight into these areas for experts. As chemically deposited metal oxides are currently gaining attention in development of devices such as solar cells, supercapacitors, batteries, sensors, etc., the book illustrates how the chemical deposition route is emerging as a relatively inexpensive, simple, and convenient solution for large area deposition. The advancement in the nanostructured materials for the development of devices is fully discussed.
| Author | : Roel van de Krol |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 322 |
| Release | : 2011-11-09 |
| Genre | : Technology & Engineering |
| ISBN | : 146141380X |
Photoelectrochemical Hydrogen Production describes the principles and materials challenges for the conversion of sunlight into hydrogen through water splitting at a semiconducting electrode. Readers will find an analysis of the solid state properties and materials requirements for semiconducting photo-electrodes, a detailed description of the semiconductor/electrolyte interface, in addition to the photo-electrochemical (PEC) cell. Experimental techniques to investigate both materials and PEC device performance are outlined, followed by an overview of the current state-of-the-art in PEC materials and devices, and combinatorial approaches towards the development of new materials. Finally, the economic and business perspectives of PEC devices are discussed, and promising future directions indicated. Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art materials/devices and future directions.
| Author | : Sixto Giménez |
| Publisher | : Springer |
| Total Pages | : 574 |
| Release | : 2016-04-29 |
| Genre | : Technology & Engineering |
| ISBN | : 3319296418 |
This book explores the conversion for solar energy into renewable liquid fuels through electrochemical reactions. The first section of the book is devoted to the theoretical fundamentals of solar fuels production, focusing on the surface properties of semiconductor materials in contact with aqueous solutions and the reaction mechanisms. The second section describes a collection of current, relevant characterization techniques, which provide essential information of the band structure of the semiconductors and carrier dynamics at the interface semiconductor. The third, and last section comprises the most recent developments in materials and engineered structures to optimize the performance of solar-to-fuel conversion devices.
| Author | : Aracely Hernández-Ramírez |
| Publisher | : Springer |
| Total Pages | : 298 |
| Release | : 2014-11-17 |
| Genre | : Science |
| ISBN | : 3319109995 |
This critical volume examines the different methods used for the synthesis of a great number of photocatalysts, including TiO2, ZnO and other modified semiconductors, as well as characterization techniques used for determining the optical, structural and morphological properties of the semiconducting materials. Additionally, the authors discuss photoelectrochemical methods for determining the light activity of the photocatalytic semiconductors by means of measurement of properties such as band gap energy, flat band potential and kinetics of hole and electron transfer. Photocatalytic Semiconductors: Synthesis, Characterization and Environmental Applications provide an overview of the semiconductor materials from first- to third-generation photocatalysts and their applications in wastewater treatment and water disinfection. The book further presents economic and toxicological aspects in the production and application of photocatalytic materials.
| Author | : Leonardo Palmisano |
| Publisher | : Elsevier |
| Total Pages | : 488 |
| Release | : 2022-10-21 |
| Genre | : Technology & Engineering |
| ISBN | : 0128242426 |
Photoelectrocatalysis: Fundamentals and Applications presents an in-depth review of the topic for students and researchersworking on photoelectrocatalysis-related subjects from pure chemistry to materials and environmental chemistry inorder to propose applications and new perspectives. The main advantage of a photoelectrocatalytic process is the mildexperimental conditions under which the reactions are carried out, which are often possible at atmospheric pressure androom temperature using cheap and nontoxic solvents (e.g., water), oxidants (e.g., O2 from the air), catalytic materials (e.g.,TiO2 on Ti layer), and the potential exploitation of solar light. This book presents the fundamentals and the applications of photoelectrocatalysis, such as hydrogen production fromwater splitting, the remediation of harmful compounds, and CO2 reduction. Photoelectrocatalytic reactors and lightsources, in addition to kinetic aspects, are presented along with an exploration of the relationship between photocatalysisand electrocatalysis. In addition, photocorrosion issues and the application of selective photoelectrocatalytic organictransformations, which is now a growing field of research, are also reported. Finally, the advantages/disadvantages andfuture perspectives of photoelectrocatalysis are highlighted through the possibility of working at a pilot/industrial scale inenvironmentally friendly conditions. - Presents the fundamentals of photoelectrocatalysis - Outlines photoelectrocatalytic green chemistry - Reviews photoelectrocatalytic remediation of harmful compounds, hydrogen production, and CO2 reduction - Includes photocorrosion, photoelectrocatalytic reactors, and modeling along with kinetic aspects
| Author | : Pradip Kar |
| Publisher | : John Wiley & Sons |
| Total Pages | : 176 |
| Release | : 2013-08-26 |
| Genre | : Technology & Engineering |
| ISBN | : 1118573803 |
An A-to-Z of doping including its definition, its importance, methods of measurement, advantages and disadvantages, properties and characteristics—and role in conjugated polymers The versatility of polymer materials is expanding because of the introduction of electro-active behavior into the characteristics of some of them. The most exciting development in this area is related to the discovery of intrinsically conductive polymers or conjugated polymers, which include such examples as polyacetylene, polyaniline, polypyrrole, and polythiophene as well as their derivatives. "Synmet" or "synthetic metal" conjugated polymers, with their metallic characteristics, including conductivity, are of special interest to researchers. An area of limitless potential and application, conjugated polymers have sparked enormous interest, beginning in 2000 when the Nobel Prize for the discovery and development of electrically conducting conjugated polymers was awarded to three scientists: Alan J. Heeger, Alan G. MacDiarmid, and Hideki Shirakawa. Conjugated polymers have a combination of properties—both metallic (conductivity) and polymeric; doping gives the conjugated polymer's semiconducting a wide range of conductivity, from insulating to low conducting. The doping process is a tested effective method for producing conducting polymers as semiconducting material, providing a substitute for inorganic semiconductors. Doping in Conjugated Polymers is the first book dedicated to the subject and offers a comprehensive A-to-Z overview. It details doping interaction, dopant types, doping techniques, and the influence of the dopant on applications. It explains how the performance of doped conjugated polymers is greatly influenced by the nature of the dopants and their level of distribution within the polymer, and shows how the electrochemical, mechanical, and optical properties of the doped conjugated polymers can be tailored by controlling the size and mobility of the dopants counter ions. The book also examines doping at the nanoscale, in particular, with carbon nanotubes. Readership The book will interest a broad range of researchers including chemists, electrochemists, biochemists, experimental and theoretical physicists, electronic and electrical engineers, polymer and materials scientists. It can also be used in both graduate and upper-level undergraduate courses on conjugated polymers and polymer technology.
| Author | : Francesco Calise |
| Publisher | : Academic Press |
| Total Pages | : 453 |
| Release | : 2021-09-22 |
| Genre | : Technology & Engineering |
| ISBN | : 0128206268 |
The support for polygeneration lies in the possibility of integrating different technologies into a single energy system, to maximize the utilization of both fossil and renewable fuels. A system that delivers multiple forms of energy to users, maximizing the overall efficiency makes polygeneration an emerging and viable option for energy consuming industries. Polygeneration Systems: Design, Processes and Technologies provides simple and advanced calculation techniques to evaluate energy, environmental and economic performance of polygeneration systems under analysis. With specific design guidelines for each type of polygeneration system and experimental performance data, referred both to single components and overall systems, this title covers all aspects of polygeneration from design to operation, optimization and practical implementation. Giving different aspects of both fossil and non-fossil fuel based polygeneration and the wider area of polygeneration processes, this book helps readers learn general principles to specific system design and development through analysis of case studies, examples, simulation characteristics and thermodynamic and economic data. - Detailed economic data for technology to assist developing feasibility studies regarding the possible application of polygeneration technologies - Offers a comprehensive list of all current numerical and experimental results of polygeneration available - Includes simulation models, cost figures, demonstration projects and test standards for designers and researchers to validate their own models and/or to test the reliability of their results
| Author | : Aiguo Wu |
| Publisher | : John Wiley & Sons |
| Total Pages | : 252 |
| Release | : 2020-06-02 |
| Genre | : Science |
| ISBN | : 3527347240 |
A unique book that summarizes the properties, toxicology, and biomedical applications of TiO2-based nanoparticles Nanotechnology is becoming increasingly important for products used in our daily lives. Nanometer-sized titanium dioxide (TiO2) are widely used in industry for different purposes, such as painting, sunscreen, printing, cosmetics, biomedicine, and so on. This book summarizes the advances of TiO2 based nanobiotechnology and nanomedicine, covering materials properties, toxicological research, and biomedical application, such as antibacter, biosensing, and cancer theranostics. It uniquely integrates the TiO2 applications from physical properties, toxicology to various biomedical applications, and includes black TiO2 based cancer theranostics. Beginning with a comprehensive introduction to the properties and applications of nanoparticles, TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine offers chapters on: Toxicity of TiO2 Nanoparticles; Antibacterial Applications of TiO2 Nanoparticles; Surface Enhanced Raman Spectrum of TiO2 Nanoparticle for Biosensing (TiO2 Nanoparticle Served as SERS Sensing Substrate); TiO2 as Inorganic Photosensitizer for Photodynamic Therapy; Cancer Theranostics of Black TiO2 Nanoparticles; and Neurodegenerative Disease Diagnostics and Therapy of TiO2-Based Nanoparticles. This title: Blends the physical properties, toxicology of TiO2 nanoparticles to the many biomedical applications Includes black TiO2 based cancer theranostics in its coverage Appeals to a broad audience of researchers in academia and industry working on nanomaterials-based biosensing, drug delivery, nanomedicine TiO2 Nanoparticles: Applications in Nanobiotechnology, Theranostics and Nanomedicine is an ideal book for medicinal chemists, analytical chemists, biochemists, materials scientists, toxicologists, and those in the pharmaceutical industry.
| Author | : Tatsumi Ishihara |
| Publisher | : Springer Science & Business Media |
| Total Pages | : 310 |
| Release | : 2009-06-12 |
| Genre | : Technology & Engineering |
| ISBN | : 0387777083 |
Fuel cell technology is quite promising for conversion of chemical energy of hydrocarbon fuels into electricity without forming air pollutants. There are several types of fuel cells: polymer electrolyte fuel cell (PEFC), phosphoric acid fuel cell (PAFC), molten carbonate fuel cell (MCFC), solid oxide fuel cell (SOFC), and alkaline fuel cell (AFC). Among these, SOFCs are the most efficient and have various advantages such as flexibility in fuel, high reliability, simple balance of plant (BOP), and a long history. Therefore, SOFC technology is attracting much attention as a power plant and is now close to marketing as a combined heat and power generation system. From the beginning of SOFC development, many perovskite oxides have been used for SOFC components; for example, LaMnO -based oxide for the cathode and 3 LaCrO for the interconnect are the most well known materials for SOFCs. The 3 current SOFCs operate at temperatures higher than 1073 K. However, lowering the operating temperature of SOFCs is an important goal for further SOFC development. Reliability, durability, and stability of the SOFCs could be greatly improved by decreasing their operating temperature. In addition, a lower operating temperature is also beneficial for shortening the startup time and decreasing energy loss from heat radiation. For this purpose, faster oxide ion conductors are required to replace the conventional Y O -stabilized ZrO 2 3 2 electrolyte. A new class of electrolytes such as LaGaO is considered to be 3 highly useful for intermediate-temperature SOFCs.
