Cleaner Combustion

Cleaner Combustion
Author: Frédérique Battin-Leclerc
Publisher: Springer Science & Business Media
Total Pages: 657
Release: 2013-09-06
Genre: Technology & Engineering
ISBN: 1447153073

This overview compiles the on-going research in Europe to enlarge and deepen the understanding of the reaction mechanisms and pathways associated with the combustion of an increased range of fuels. Focus is given to the formation of a large number of hazardous minor pollutants and the inability of current combustion models to predict the formation of minor products such as alkenes, dienes, aromatics, aldehydes and soot nano-particles which have a deleterious impact on both the environment and on human health. Cleaner Combustion describes, at a fundamental level, the reactive chemistry of minor pollutants within extensively validated detailed mechanisms for traditional fuels, but also innovative surrogates, describing the complex chemistry of new environmentally important bio-fuels. Divided into five sections, a broad yet detailed coverage of related research is provided. Beginning with the development of detailed kinetic mechanisms, chapters go on to explore techniques to obtain reliable experimental data, soot and polycyclic aromatic hydrocarbons, mechanism reduction and uncertainty analysis, and elementary reactions. This comprehensive coverage of current research provides a solid foundation for researchers, managers, policy makers and industry operators working in or developing this innovative and globally relevant field.

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion
Author:
Publisher: Elsevier
Total Pages: 1036
Release: 2019-06-06
Genre: Technology & Engineering
ISBN: 0444640886

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications. - Details thermochemical properties and "ab initio" calculations of elementary reaction rates - Details kinetic mechanisms of pyrolysis and combustion processes - Explains experimental data for improving reaction models and for kinetic mechanisms assessment - Describes surrogate fuels and molecular reconstruction of hydrocarbon liquid mixtures - Describes pollutant formation in combustion systems - Solves and validates the kinetic mechanisms using numerical and statistical methods - Outlines optimal design of industrial burners and optimization and dynamic control of pyrolysis furnaces - Outlines large eddy simulation of turbulent reacting flows

Production of Biofuels and Numerical Modeling of Chemical Combustion Systems

Production of Biofuels and Numerical Modeling of Chemical Combustion Systems
Author: Miguel Torres García
Publisher: MDPI
Total Pages: 298
Release: 2021-08-18
Genre: Technology & Engineering
ISBN: 3036513329

Biofuels have recently attracted a lot of attention, mainly as alternative fuels for applications in energy generation and transportation. The utilization of biofuels in such controlled combustion processes has the great advantage of not depleting the limited resources of fossil fuels while leading to emissions of greenhouse gases and smoke particles similar to those of fossil fuels. On the other hand, a vast amount of biofuels are subjected to combustion in small-scale processes, such as for heating and cooking in residential dwellings, as well as in agricultural operations, such as crop residue removal and land clearing. In addition, large amounts of biomass are consumed annually during forest and savanna fires in many parts of the world. These types of burning processes are typically uncontrolled and unregulated. Consequently, the emissions from these processes may be larger compared to industrial-type operations. Aside from direct effects on human health, especially due to a sizeable fraction of the smoke emissions remaining inside residential homes, the smoke particles and gases released from uncontrolled biofuel combustion impose significant effects on the regional and global climate. Estimates have shown the majority of carbonaceous airborne particulate matter to be derived from the combustion of biofuels and biomass. “Production of Biofuels and Numerical Modelling of Chemical Combustion Systems” comprehensively overviews and includes in-depth technical research papers addressing recent progress in biofuel production and combustion processes. To be specific, this book contains sixteen high-quality studies (fifteen research papers and one review paper) addressing techniques and methods for bioenergy and biofuel production as well as challenges in the broad area of process modelling and control in combustion processes.

Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels

Investigations into the Combustion Kinetics of Several Novel Oxygenated Fuels
Author: Wenyu Sun
Publisher: Springer Nature
Total Pages: 178
Release: 2023-09-22
Genre: Technology & Engineering
ISBN: 9819945100

In this thesis, attention was paid to several novel oxygenated fuels—carbonates, polyethers and ketones. Combustion kinetic investigations were performed for typical representative compounds, including dimethyl carbonate, diethyl carbonate, cyclopentanone, 3-pentanone, 1,2-dimethoxyethane and dimethoxymethane. For experiments, suitable diagnostic techniques were used to measure the detailed speciation information of the target fuels under different conditions. For kinetic modeling, rate coefficients for crucial elementary reactions were obtained through high-level theoretical calculations. Based on that, validated kinetic models with good predictive performances were developed. On the basis of experimental measurements and model interpretations, this work highlighted two important combustion characteristics regarding the practical use: the pollutant formation and the ignition performance. Besides, the correlation between oxygen-containing functional groups and the aforementioned combustion characteristics was revealed. To reveal the potential interactions between the reaction networks of oxygenated additives and the hydrocarbon base fuels during combustion. Chemical structures of laminar premixed flames fueled by binary fuels were measured, and by changing the initial fuel compositions, the addition effects of the oxygenates on the fuel consumption and pollutant formation behaviors were explored. It was found that complicated chemical interactions do not exist in the reaction networks under the investigated conditions.

Advances in Physical Organic Chemistry

Advances in Physical Organic Chemistry
Author:
Publisher: Academic Press
Total Pages: 316
Release: 2015-11-20
Genre: Science
ISBN: 0128024291

Advances in Physical Organic Chemistry series of volumes is the definitive resource for authoritative reviews of work in physical organic chemistry. It aims to provide a valuable source of information not only for physical organic chemists applying their expertise to both novel and traditional problems but also for non-specialists across diverse areas who identify a physical organic component in their approach to research. Its hallmark is quantitative, molecular level understanding of phenomena across a diverse range of disciplines. - Reviews the application of quantitative and mathematical methods to help readers understand chemical problems - Provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry - Covers organic, organometallic, bioorganic, enzymes, and materials topics - The only regularly published resource for reviews in physical organic chemistry - Chapters are written by authoritative experts - Wide coverage of topics requiring a quantitative, molecular-level understanding of phenomena across a diverse range of disciplines

Application of Liquid Biofuels to Internal Combustion Engines

Application of Liquid Biofuels to Internal Combustion Engines
Author: Soo-Young No
Publisher: Springer Nature
Total Pages: 480
Release: 2020-02-17
Genre: Technology & Engineering
ISBN: 981136737X

This book provides a comprehensive overview of the application of liquid biofuels to internal combustion (IC) engines. Biofuels are one of the most promising renewable and sustainable energy sources. Particularly, liquid biofuels obtained from biomass could become a valid alternative to the use of fossil fuels in the light of increasingly stringent environmental constraints. In this book, the discussion is limited to liquid biofuels obtained from triglycerides and lignocellulose among the many different kinds of biomass. Several liquid biofuels from triglycerides, straight vegetable oil, biodiesel produced from inedible vegetable oil, hydrotreated vegetable oil, and pyrolytic oil have been selected for discussion, as well as biofuels from lignocellulose bio-oil, alcohols such as methanol, ethanol and butanol, and biomass-to-liquids diesel. This book includes three chapters on the application of methanol, ethanol and butanol to advanced compression ignition (CI) engines such as LTC, HCCI, RCCI and DF modes. Further, the application of other higher alcohols and other drop-in fuels such as DMF, MF, MTHF, and GVL are also discussed. The book will be a valuable resource for graduate students, researchers and engine designers who are interested in the application of alcohols and other biofuels in advanced CI engines, and also useful for alternative energy planners selecting biofuels for CI engines in the future.

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion
Author:
Publisher: Elsevier
Total Pages: 1034
Release: 2019-06-07
Genre: Technology & Engineering
ISBN: 0128195797

Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications.

Biofuels

Biofuels
Author: Krzysztof Biernat
Publisher: BoD – Books on Demand
Total Pages: 302
Release: 2018-07-11
Genre: Science
ISBN: 1789233461

This book offers the current state of knowledge in the field of biofuels, presented by selected research centers from around the world. Biogas from waste production process and areas of application of biomethane were characterized. Also, possibilities of applications of wastes from fruit bunch of oil palm tree and high biomass/bagasse from sorghum and Bermuda grass for second-generation bioethanol were presented. Processes and mechanisms of biodiesel production, including the review of catalytic transesterification process, and careful analysis of kinetics, including bioreactor system for algae breeding, were widely analyzed. Problem of emissivity of NOx from engines fueled by B20 fuel was characterized. The closing chapters deal with the assessment of the potential of biofuels in Turkey, the components of refinery systems for production of biodegradable plastics from biomass. Also, a chapter concerning the environmental conditions of synthesis gas production as a universal raw material for the production of alternative fuels was also added.

Analysis of Kinetic Reaction Mechanisms

Analysis of Kinetic Reaction Mechanisms
Author: Tamás Turányi
Publisher: Springer
Total Pages: 369
Release: 2014-12-29
Genre: Science
ISBN: 366244562X

Chemical processes in many fields of science and technology, including combustion, atmospheric chemistry, environmental modelling, process engineering, and systems biology, can be described by detailed reaction mechanisms consisting of numerous reaction steps. This book describes methods for the analysis of reaction mechanisms that are applicable in all these fields. Topics addressed include: how sensitivity and uncertainty analyses allow the calculation of the overall uncertainty of simulation results and the identification of the most important input parameters, the ways in which mechanisms can be reduced without losing important kinetic and dynamic detail, and the application of reduced models for more accurate engineering optimizations. This monograph is invaluable for researchers and engineers dealing with detailed reaction mechanisms, but is also useful for graduate students of related courses in chemistry, mechanical engineering, energy and environmental science and biology.

Production of Biofuels and Chemicals with Pyrolysis

Production of Biofuels and Chemicals with Pyrolysis
Author: Zhen Fang
Publisher: Springer Nature
Total Pages: 456
Release: 2020-10-27
Genre: Medical
ISBN: 9811527326

This book presents a collection of studies on state-of-art techniques for converting biomass to chemical products by means of pyrolysis, which are widely applicable to the valorization of biomass. In addition to discussing the fundamentals and mechanisms for producing bio-oils, chemicals, gases and biochar using pyrolysis, it outlines key reaction parameters and reactor configurations for various types of biomass. Written by leading experts and providing a broad range of perspectives on cutting-edge applications, the book is a comprehensive reference guide for academic researchers and industrial engineers in the fields of natural renewable materials, biorefinery of lignocellulose, biofuels, and environmental engineering, and a valuable resource for university students in the fields of chemical engineering, material science and environmental engineering.