Characteristics of Stored High-level ICPP Waste Calcine

Characteristics of Stored High-level ICPP Waste Calcine
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Total Pages:
Release: 1979
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Calcined high-level radioactive defense waste stored at the Idaho Chemical Processing Plant for up to twelve years was sampled for retrievability. The calcine was determined to be retrievable as expected. A program to determine physical and chemical characteristics for future retrieval and alternative waste treatment processes has been completed.

Effect of Aluminum and Silicon Reactants and HIP Soak Time on Characteristics of Glass-ceramic Waste Forms

Effect of Aluminum and Silicon Reactants and HIP Soak Time on Characteristics of Glass-ceramic Waste Forms
Author:
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Total Pages: 40
Release: 1993
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The high level liquid waste (HLLW) from nuclear fuel reprocessing is being calcined into solid granules and being stored onsite at the Idaho Chemical Processing Plant (ICPP) since 1963. Final disposal of the calcined waste in a geologic repository requires further consolidation of the calcine in to a solid waste form. One of the solid waste forms being considered for immobilization of the ICPP calcines is the glass-ceramic. The glass-ceramic waste form is a promising option because it can potentially reduce the calcined high level waste (HLW) volume significantly compared to glass waste forms while maintaining similar leach rates. Based on technical evaluations, and laboratory and pilot plant mockup tests, the Environmental Protection Agency (EPA) believes that the glass-ceramic process is more efficient than the glass process for ICPP calcine waste forms. The EPA has determined that the glass-ceramic waste form technology is an acceptable technology to meet the Best Demonstrated Acceptable Technology (BDAT) for ICPP HLW calcine. In this progress report, the impact of aluminum and silicon reactants and HIP soak time on leach rates, microstructure and phase composition of glass-ceramic waste forms are discussed.

Effect of Aluminum and Silicon Reactants and Process Parameters on Glass-ceramic Waste Form Characteristics for Immobilization of High-level Fluorinel-sodium Calcined Waste

Effect of Aluminum and Silicon Reactants and Process Parameters on Glass-ceramic Waste Form Characteristics for Immobilization of High-level Fluorinel-sodium Calcined Waste
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Total Pages: 45
Release: 1993
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In this report, the effects of aluminum and silicon reactants, process soak time and the initial calcine particle size on glass-ceramic waste form characteristics for immobilization of the high-level fluorinel-sodium calcined waste stored at the Idaho Chemical Processing Plant (ICPP) are investigated. The waste form characteristics include density, total and normalized elemental leach rates, and microstructure. Glass-ceramic waste forms were prepared by hot isostatically pressing (HIPing) a pre-compacted mixture of pilot plant fluorinel-sodium calcine, Al, and Si metal powders at 1050°C, 20,000 psi for 4 hours. One of the formulations with 2 wt % Al was HIPed for 4, 8, 16 and 24 hours at the same temperature and pressure. The calcine particle size range include as calcined particle size smaller than 600 [mu]m (finer than -30 mesh, or 215 [mu]m Mass Median Diameter, MMD) and 180 [mu]m (finer than 80 mesh, or 49 [mu]m MMD).

ERDA.

ERDA.
Author:
Publisher:
Total Pages: 186
Release: 1977
Genre:
ISBN: