Catalytic Transformations Of Sustainable And Versatile Furanic Chemicals
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| Author | : S. Saravanamurugan |
| Publisher | : CRC Press |
| Total Pages | : 290 |
| Release | : 2024-12-03 |
| Genre | : Science |
| ISBN | : 1040216633 |
Diminishing confined fossil resources has spurred the scientific community to strive for alternative, sustainable resources, such as terrestrial biomass, which can potentially substitute fossil-based derivatives. Lignocellulosic biomass is deemed an indispensable carbon source for meeting industrial and social demands regarding energy/fuels and chemicals. Over the past decade, significant advances have been shown in developing a broad spectrum of high-value chemicals and functional materials derived from biomass-based substrates. In connection with this, furanic chemicals, such as 5-hydroxymethylfurfural (HMF) and furfural, have recently received considerable attention due to their potential applications. Catalytic Transformations of Sustainable and Versatile Furanic Chemicals aims to explicitly display the latest technical developments on designing functional catalysts, optimizing process and reaction parameters, and improving the stability of the employed materials on the transformation of HMF and furfural to a wide range of value-added chemicals via oxidation, reduction, hydrodeoxygenation, and reductive amination processes. Features: Highlighting the importance and significance of HMF and furfural. Evaluating the transformations of HMF and furfural with various catalytic processes. Designing robust and efficient catalytic systems. Understanding the stability of catalytic materials. Understanding the characteristic features of the catalytic materials. This book aims to target not only researchers focusing on biomass valorization from academic to industrial sectors but also graduate students interested in pursuing their higher education in biochemicals (especially furanic compounds), covering various aspects in organic synthesis routes, preparation of inorganic materials and physico-chemical properties, for both chemists and chemical engineers.
| Author | : Chaudhery Mustansar Hussain |
| Publisher | : Elsevier |
| Total Pages | : 274 |
| Release | : 2020-05-31 |
| Genre | : Technology & Engineering |
| ISBN | : 012820236X |
Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts' properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts' stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed.
| Author | : Basudeb Saha |
| Publisher | : Newnes |
| Total Pages | : 219 |
| Release | : 2015-06-11 |
| Genre | : Technology & Engineering |
| ISBN | : 0444595791 |
The development of catalysts is the most sophisticated art in chemical sciences. It can be read like a story book when the critical scientific contents are presented in a chronological manner with short and simple sentences. This book will meets these criteria. To address the sustainability issues of existing chemical manufacturing processes or producing new chemicals, researchers are developing alternate catalysts to eliminate toxic chemicals use and by-products formation. Sustainable Catalytic Processes presents critical discussions of the progress of such catalytic development. This book of contemporary research results in sustainable catalysis area will benefit scientists in both industries and academia, and students to learn recent catalysts/process development. - Reports the most recent developments in catalysis with a focus on environmentally friendly commercial processes, such as waste water treatment, alternate energy, etc - Bridges the theory, necessary for the development of environmentally friendly processes, and their implementation through pilot plant and large scale - Contains mainly laboratory scale data and encourages industrial scientists to test these processes on a pilot scale - Includes work examples featuring the development of the new catalysts/processes using bio-renewable feedstock satisfactorily addressing environmental concerns - Includes one chapter demonstrating real industrial examples motivating the industrial and academic researchers to pursue similar research
| Author | : K. K. Pant |
| Publisher | : Springer Nature |
| Total Pages | : 933 |
| Release | : 2021-05-13 |
| Genre | : Technology & Engineering |
| ISBN | : 3030650170 |
This book is part of a two-volume work that offers a unique blend of information on realistic evaluations of catalyst-based synthesis processes using green chemistry principles and the environmental sustainability applications of such processes for biomass conversion, refining, and petrochemical production. The volumes provide a comprehensive resource of state-of-the-art technologies and green chemistry methodologies from researchers, academics, and chemical and manufacturing industrial scientists. The work will be of interest to professors, researchers, and practitioners in clean energy catalysis, green chemistry, chemical engineering and manufacturing, and environmental sustainability. This volume focuses on the potentials, recent advances, and future prospects of catalysis for biomass conversion and value-added chemicals production via green catalytic routes. Readers are presented with a mechanistic framework assessing the development of product selective catalytic processes for biomass and biomass-derived feedstock conversion. The book offers a unique combination of contributions from experts working on both lab-scale and industrial catalytic processes and provides insight into the use of various catalytic materials (e.g., mineral acids, heteropolyacid, metal catalysts, zeolites, metal oxides) for clean energy production and environmental sustainability.
| Author | : Pieter Imhof |
| Publisher | : John Wiley & Sons |
| Total Pages | : 388 |
| Release | : 2013-02-28 |
| Genre | : Science |
| ISBN | : 3527656650 |
Green, clean and renewable are the hottest keywords for catalysis and industry. This handbook and ready reference is the first to combine the fields of advanced experimentation and catalytic process development for biobased materials in industry. It describes the entire workflow from idea, approach, research, and process development, right up to commercialization. A large part of the book is devoted to the use of advanced technologies and methodologies like high throughput experimentation, as well as reactor and process design models, with a wide selection of real-life examples included at each stage. The contributions are from authors at leading companies and institutes, providing firsthand information and knowledge that is hard to find elsewhere. This work is aimed at decision makers, engineers and chemists in industry, chemists and engineers working with/on renewables, chemists in the field of catalysis, and chemical engineers.
| Author | : Gabriel Morales |
| Publisher | : MDPI |
| Total Pages | : 216 |
| Release | : 2020-12-02 |
| Genre | : Technology & Engineering |
| ISBN | : 3039364332 |
Biomass is widely considered as a potential alternative to dwindling fossil fuel reserves. There is a large variety of biomass sources (oleaginous, lignocellulosic, algae, etc.), with many possible conversion routes and products. Currently, biomass is not just viewed as a source of biofuels, but also as an interesting feedstock for the production of bio-based chemicals that could largely replace petrochemicals. In this context, the search for new sustainable and efficient alternatives to fossil sources is gaining increasing relevance within the chemical industry. There, the role of catalysis is often critical for the development of clean and sustainable processes, aiming to produce commodity chemicals or liquid fuels with a high efficiency and atom economy. This book gathers works at the cutting edge of investigation in the application of catalysis, for the sustainable conversion of biomass into biofuels and bio-based chemicals.
| Author | : Michel Brienzo |
| Publisher | : Springer Nature |
| Total Pages | : 508 |
| Release | : 2022-01-03 |
| Genre | : Science |
| ISBN | : 9811636826 |
This edited book provides knowledge about hemicelluloses biorefinery approaching production life cycle, circular economy, and valorization by obtaining value-added bioproducts and bioenergy. A special focus is dedicated to chemical and biochemical compounds produced from the hemicelluloses derivatives platform. Hemicelluloses are polysaccharides located into plant cell wall, with diverse chemical structures and properties. It is the second most spread organic polymer on nature and found in vast lignocellulosic materials from agro and industrial wastes, therefore, hemicelluloses are considered as abundant and renewable raw material/feedstock. Biorefinery concept contributes to hemicelluloses production associated with biomass industrial processes. Hemicelluloses are alternative sources of sugars for renewable fuels and as platform for chemicals production. This book reviews chemical processes for sugar production and degradation, obtaining of intermediate and final products, and challenges for pentose fermentation. Aspects of hemicelluloses chain chemical and enzymatic modifications are presented with focus on physicochemical properties improvement for bioplastic and biomaterial approaches. Hemicelluloses are presented as sources for advanced materials in biomedical and pharmaceutical uses, and as hydrogel for chemical and medicine deliveries. An interdisciplinary approach is needed to cover all the processes involving hemicelluloses, its conversion into final and intermediate value-added compounds, and bioenergy production. Covering this context, this book is of interest to teachers, students, researchers, and scientists dedicated to biomass valorization. This book is a knowledge source of basic aspects to advanced processing and application for graduate students, particularly. Besides, the book serves as additional reading material for undergraduate students (from different courses) with a deep interest in biomass and waste conversion, valorization, and chemical products from hemicelluloses
| Author | : S. Saravanamurugan |
| Publisher | : Elsevier |
| Total Pages | : 510 |
| Release | : 2019-10-23 |
| Genre | : Technology & Engineering |
| ISBN | : 0444643087 |
Biomass, Biofuels, Biochemicals: Recent Advances in Development of Platform Chemicals provides a detailed overview on the experimentally developed methods that facilitate platform chemicals derivation from biomass-based substrates with robust catalyst systems. In addition, the book highlights the green chemistry approach towards platform chemical production. Chapters discuss platform chemicals and global market volumes, the optimization of process schemes and reaction parameters with respect to achieving a high yield of targeted platform chemicals, such as sugars and furonic compounds by modifying the respective catalytic system, the influence of solvents on reaction selectivity and product distribution, and the long-term stability of employed catalysts. Overall, the objectives of the book are to provide the reader with an understanding of the societal importance of platform chemicals, an assessment of the techno-economic viability of biomass valorization processes, catalyst design for a specific reaction, and the design of a catalytic system. - Covers recent developments on platform chemicals - Provides comprehensive technological developments on specific platform chemicals - Covers organic transformations, catalytic synthesis, thermal stability, reaction parameters and solvent effect - Includes case studies on the production of a number of chemicals, such as Levulinic acid, glycerol, phenol derivatives, and more
| Author | : Georgios Papadogianakis |
| Publisher | : Frontiers Media SA |
| Total Pages | : 196 |
| Release | : 2024-08-23 |
| Genre | : Science |
| ISBN | : 2832553745 |
Today, there is growing interest in aqueous-phase catalytic conversions for the valorization of renewable biomass-based feedstocks for biorefineries to produce, in a sustainable way, biofuels, chemicals, power, energy, materials, pharmaceuticals and food. This is because of the highly polar nature of water which makes it an ideal medium to convert polar biomass-based lignocellulose (cellulose, hemicellulose, lignin), with high oxygen content, and their upgraded products such as hydrophilic carbohydrates, platform chemicals and their derivatives. Another reason which makes water the solvent of choice is that water itself is involved either as a reagent or as a byproduct even in large amounts in typical conversions for the valorization of biomass. The obtained intermediates further react in the aqueous medium, often without any separation and purification, to manufacture more valuable products. This results in substantial energy savings, lower emissions and economic benefits. Furthermore, water could act as a catalyst in conversions of biomass-based feedstocks such as in liquefaction reactions under subcritical conditions. Moreover, novel types of catalytic reactivity have been observed in the aqueous solvent, not only with water-soluble transition metal catalytic complexes, but also with conventional heterogeneous catalysts and catalytic nanoparticles in a broad spectrum of different reactions such as, inter alia, aldol condensations and hydrogenation reactions. For example, in the aqueous-phase hydrogenation of the biomass-based key platform chemical levulinic acid into γ-valerolactone and beyond, employing heterogeneous catalysts and nanoparticles the presence of water has a beneficial effect and accelerates the reaction rates, whereas in organic solvents much lower activities were observed. This promotional effect of water in the hydrogenation of levulinic acid was proved by many experimental and theoretical studies using a broad spectrum of different types of catalytic systems.
| Author | : Sudipti Arora |
| Publisher | : Springer Nature |
| Total Pages | : 1072 |
| Release | : 2022-08-03 |
| Genre | : Science |
| ISBN | : 9811690014 |
This edited book focuses on the application and implementation of bioremediation and other strategies to create a sustainable and healthy environment. It provides a collection of approaches to environmental biotechnology for wastewater treatment, removal of soil heavy metals, degradation of pesticides, removal of dyes, waste management, and microbial conversion of environmental pollutants. This book brings to the fore contributions of certain globally important environmental biotechnologist. Bioremediation is a popular branch of biotechnology that involves the use of living organisms such as microorganisms (microbial remediation), bacteria, fungus (mycoremediation), and plants (phytoremediation) to bind, extract, and clean up contaminants, pollutants, and toxins from soil, groundwater, and other environments. This book is of interest to researchers, scientists, and academic faculty in environmental sciences. Also, it serves as additional reading and reference material for undergraduate and graduate students as well as postdocs in environmental, agriculture, ecology, and soil sciences. National and International policy makers will also find valuable information from this book.
