Carbon Dioxide Equilibria and Their Applications

Carbon Dioxide Equilibria and Their Applications
Author: James N. Butler
Publisher: Routledge
Total Pages: 276
Release: 2019-01-22
Genre: Science
ISBN: 135146258X

Carbon dioxide, bicarbonate ion, and carbonate ion comprise the most important acid-base system in natural waters, and the equilibria between them regulate the pH of seawater, as well as most rainwater, stream water, river water, and groundwater. Carbon Dioxide Equilibria and Their Applications provides a clear, compact presentation of this topic,

Carbon Dioxide Equilibria and Their Applications

Carbon Dioxide Equilibria and Their Applications
Author: James N. Butler
Publisher: Routledge
Total Pages: 273
Release: 2019-01-22
Genre: Science
ISBN: 1351462598

Carbon dioxide, bicarbonate ion, and carbonate ion comprise the most important acid-base system in natural waters, and the equilibria between them regulate the pH of seawater, as well as most rainwater, stream water, river water, and groundwater. Carbon Dioxide Equilibria and Their Applications provides a clear, compact presentation of this topic,

Marine Carbon Biogeochemistry

Marine Carbon Biogeochemistry
Author: Jack J. Middelburg
Publisher: Springer
Total Pages: 126
Release: 2019-01-25
Genre: Science
ISBN: 3030108228

This open access book discusses biogeochemical processes relevant to carbon and aims to provide readers, graduate students and researchers, with insight into the functioning of marine ecosystems. A carbon centric approach has been adopted, but other elements are included where relevant or needed. The book focuses on concepts and quantitative understanding of primary production, organic matter mineralization and sediment biogeochemistry. The impact of biogeochemical processes on inorganic carbon dynamics and organic matter transformation are also discussed.

CO2 in Seawater: Equilibrium, Kinetics, Isotopes

CO2 in Seawater: Equilibrium, Kinetics, Isotopes
Author: R.E. Zeebe
Publisher: Elsevier
Total Pages: 361
Release: 2001-10-15
Genre: Science
ISBN: 0080529224

Carbon dioxide is the most important greenhouse gas after water vapor in the atmosphere of the earth. More than 98% of the carbon of the atmosphere-ocean system is stored in the oceans as dissolved inorganic carbon. The key for understanding critical processes of the marine carbon cycle is a sound knowledge of the seawater carbonate chemistry, including equilibrium and nonequilibrium properties as well as stable isotope fractionation.Presenting the first coherent text describing equilibrium and nonequilibrium properties and stable isotope fractionation among the elements of the carbonate system. This volume presents an overview and a synthesis of these subjects which should be useful for graduate students and researchers in various fields such as biogeochemistry, chemical oceanography, paleoceanography, marine biology, marine chemistry, marine geology, and others.The volume includes an introduction to the equilibrium properties of the carbonate system in which basic concepts such as equilibrium constants, alkalinity, pH scales, and buffering are discussed. It also deals with the nonequilibrium properties of the seawater carbonate chemistry. Whereas principle of chemical kinetics are recapitulated, reaction rates and relaxation times of the carbonate system are considered in details. The book also provides a general introduction to stable isotope fractionation and describes the partitioning of carbon, oxygen, and boron isotopes between the species of the carbonate system. The appendix contains formulas for the equilibrium constants of the carbonate system, mathematical expressions to calculate carbonate system parameters, answers to exercises and more.

Ionic Equilibrium

Ionic Equilibrium
Author: James N. Butler
Publisher: John Wiley & Sons
Total Pages: 582
Release: 1998-04-13
Genre: Science
ISBN: 9780471585268

A celebrated classic in the field updated and expanded to includethe latest computerized calculation techniques In 1964, James N. Butler published a book in which he presentedsome simple graphical methods of performing acid-base, solubility,and complex formation equilibrium calculations. Today, both thebook and these methods have become standard for generations ofstudents and professionals in fields ranging from environmentalscience to analytical chemistry. Named a "Citation Classic" by theScience Citation Index in 1990, the book, Ionic Equilibrium,continues to be one of the most widely used texts on the subject.So why tamper with near-perfection by attempting a revision of thatclassic? The reason is simple-- the recent rapid development andwide availability of personal computers. In the revised Ionic Equilibrium, Dr. Butler updates his 1964 workby abandoning the slide rule and graph paper for the PCspreadsheet. He also expands the original coverage with extensivematerial on basic principles and recent research. The first part of Ionic Equilibrium is devoted to the fundamentalsof acid-base, solubility, and complex formation equilibria. In thesecond part, the author discusses oxidation-reduction equilibria,develops the principles of carbon dioxide equilibria, presents casestudies demonstrating the ways in which carbon dioxide equilibriaare used in physiology and oceanography, and explores thepossibility of a pH scale for brines. The concluding chapter,written by David R. Cogley, gives examples of general computerprograms that are capable of performing equilibrium calculations onsystems of many components. Replete with real-world examples, details of importantcalculations, and practical problems, Ionic Equilibrium is an idealcourse text for students of environmental chemistry, engineering,or health; analytical chemistry; oceanography; geochemistry;biochemistry; physical chemistry; and clinical chemistry. It isalso a valuable working resource for professionals in those fieldsas well as industrial chemists involved with solution chemistry.

The Application of Green Solvents in Separation Processes

The Application of Green Solvents in Separation Processes
Author: Francisco Pena-Pereira
Publisher: Elsevier
Total Pages: 561
Release: 2017-02-28
Genre: Science
ISBN: 0128054433

The Application of Green Solvents in Separation Processes features a logical progression of a wide range of topics and methods, beginning with an overview of green solvents, covering everything from water and organic solvents, to ionic liquids, switchable solvents, eutectic mixtures, supercritical fluids, gas-expanded solvents, and more. In addition, the book outlines green extraction techniques, such as green membrane extraction, ultrasound-assisted extraction, and surfactant-mediated extraction techniques. Green sampling and sample preparation techniques are then explored, followed by green analytical separations, including green gas and liquid capillary chromatography, counter current chromatography, supercritical fluid chromatography, capillary electrophoresis, and other electrical separations. Applications of green chemistry techniques that are relevant for a broad range of scientific and technological areas are covered, including the benefits and challenges associated with their application. - Provides insights into recent advances in greener extraction and separation processes - Gives an understanding of alternatives to harmful solvents commonly used in extraction and separation processes, as well as advanced techniques for such processes - Written by a multidisciplinary group of internationally recognized scientists

Trends in Oil and Gas Corrosion Research and Technologies

Trends in Oil and Gas Corrosion Research and Technologies
Author: A. M. El-Sherik
Publisher: Woodhead Publishing
Total Pages: 928
Release: 2017-06-09
Genre: Science
ISBN: 0081012195

Trends in Oil and Gas Corrosion Research and Technologies: Production and Transmission delivers the most up-to-date and highly multidisciplinary reference available to identify emerging developments, fundamental mechanisms and the technologies necessary in one unified source. Starting with a brief explanation on corrosion management that also addresses today's most challenging issues for oil and gas production and transmission operations, the book dives into the latest advances in microbiology-influenced corrosion and other corrosion threats, such as stress corrosion cracking and hydrogen damage just to name a few. In addition, it covers testing and monitoring techniques, such as molecular microbiology and online monitoring for surface and subsurface facilities, mitigation tools, including coatings, nano-packaged biocides, modeling and prediction, cathodic protection and new steels and non-metallics. Rounding out with an extensive glossary and list of abbreviations, the book equips upstream and midstream corrosion professionals in the oil and gas industry with the most advanced collection of topics and solutions to responsibly help solve today's oil and gas corrosion challenges. - Covers the latest in corrosion mitigation techniques, such as corrosion inhibitors, biocides, non-metallics, coatings, and modeling and prediction - Solves knowledge gaps with the most current technology and discoveries on specific corrosion mechanisms, highlighting where future research and industry efforts should be concentrated - Achieves practical and balanced understanding with a full spectrum of subjects presented from multiple academic and world-renowned contributors in the industry

Hydrothermal and Supercritical Water Processes

Hydrothermal and Supercritical Water Processes
Author: Gerd Brunner
Publisher: Elsevier
Total Pages: 683
Release: 2014-04-04
Genre: Science
ISBN: 0444594183

Hydrothermal and Supercritical Water Processes presents an overview on the properties and applications of water at elevated temperatures and pressures. It combines fundamentals with production process aspects. Water is an extraordinary substance. At elevated temperatures (and pressures) its properties change dramatically due to the modifications of the molecular structure of bulk water that varies from a stable three-dimensional network, formed by hydrogen bonds at low and moderate temperatures, to an assembly of separated polar water molecules at high and supercritical temperatures. With varying pressure and temperature, water is turned from a solvent for ionic species to a solvent for polar and non-polar substances. This variability and an enhanced reactivity of water have led to many practical applications and to even more research activities, related to such areas as energy transfer, extraction of functional molecules, unique chemical reactions, biomass conversion and fuel materials processing, destruction of dangerous compounds and recycling of useful ones, growth of monolithic crystals, and preparation of metallic nanoparticles. This book provides an introduction into the wide range of activities that are possible in aqueous mixtures. It is organized to facilitate understanding of the main features, outlines the main applications, and gives access to further information - Summarizes fundamental properties of water for engineering applications - Compares process and reactor designs - Evaluates processes from thermodynamic, economic, and social impact viewpoints

Dense Phase Carbon Dioxide

Dense Phase Carbon Dioxide
Author: Murat O. Balaban
Publisher: John Wiley & Sons
Total Pages: 337
Release: 2012-04-05
Genre: Technology & Engineering
ISBN: 1118243323

Dense phase carbon dioxide (DPCD) is a non-thermal method for food and pharmaceutical processing that can ensure safe products with minimal nutrient loss and better preserved quality attributes. Its application is quite different than, for example, supercritical extraction with CO 2 where the typical solubility of materials in CO 2 is in the order of 1% and therefore requires large volumes of CO 2. In contrast, processing with DPCD requires much less CO 2 (between 5 to 8% CO 2 by weight) and the pressures used are at least one order of magnitude less than those typically used in ultra high pressure (UHP) processing. There is no noticeable temperature increase due to pressurization, and typical process temperatures are around 40°C. DPCD temporarily reduces the pH of liquid foods and because oxygen is removed from the environment, and because the temperature is not high during the short process time (typically about five minutes in continuous systems), nutrients, antioxidant activity, and vitamins are much better preserved than with thermal treatments. In pharmaceutical applications, DPCD facilitates the production of micronized powders of controlled particle size and distribution. Although the capital and operating costs are higher than that of thermal treatments, they are much lower than other non-thermal technology operations. This book is the first to bring together the significant amount of research into DPCD and highlight its effectiveness against microorganisms and enzymes as well as its potential in particle engineering. It is directed at food and pharmaceutical industry scientists and technologists working with DPCD and other traditional or non-thermal technologies that can potentially be used in conjunction with DPCD. It will also be of interest to packaging specialists and regulatory agencies.

Carbon in Earth's Interior

Carbon in Earth's Interior
Author: Craig E. Manning
Publisher: John Wiley & Sons
Total Pages: 373
Release: 2020-04-03
Genre: Science
ISBN: 1119508231

Carbon in Earth's fluid envelopes - the atmosphere, biosphere, and hydrosphere, plays a fundamental role in our planet's climate system and a central role in biology, the environment, and the economy of earth system. The source and original quantity of carbon in our planet is uncertain, as are the identities and relative importance of early chemical processes associated with planetary differentiation. Numerous lines of evidence point to the early and continuing exchange of substantial carbon between Earth's surface and its interior, including diamonds, carbon-rich mantle-derived magmas, carbonate rocks in subduction zones and springs carrying deeply sourced carbon-bearing gases. Thus, there is little doubt that a substantial amount of carbon resides in our planet's interior. Yet, while we know it must be present, carbon's forms, transformations and movements at conditions relevant to the interiors of Earth and other planets remain uncertain and untapped. Volume highlights include: - Reviews key, general topics, such as carbonate minerals, the deep carbon cycle, and carbon in magmas or fluids - Describes new results at the frontiers of the field with presenting results on carbon in minerals, melts, and fluids at extreme conditions of planetary interiors - Brings together emerging insights into carbon's forms, transformations and movements through study of the dynamics, structure, stability and reactivity of carbon-based natural materials - Reviews emerging new insights into the properties of allied substances that carry carbon, into the rates of chemical and physical transformations, and into the complex interactions between moving fluids, magmas, and rocks to the interiors of Earth and other planets - Spans the various chemical redox states of carbon, from reduced hydrocarbons to zero-valent diamond and graphite to oxidized CO2 and carbonates - Captures and synthesizes the exciting results of recent, focused efforts in an emerging scientific discipline - Reports advances over the last decade that have led to a major leap forward in our understanding of carbon science - Compiles the range of methods that can be tapped tap from the deep carbon community, which includes experimentalists, first principles theorists, thermodynamic modelers and geodynamicists - Represents a reference point for future deep carbon science research Carbon in Planetary Interiors will be a valuable resource for researchers and students who study the Earth's interior. The topics of this volume are interdisciplinary, and therefore will be useful to professionals from a wide variety of fields in the Earth Sciences, such as mineral physics, petrology, geochemistry, experimentalists, first principles theorists, thermodynamics, material science, chemistry, geophysics and geodynamics.