Atlas of Metal-ligand Equilibria in Aqueous Solution
Author | : J. Kragten |
Publisher | : Ellis Horwood |
Total Pages | : 886 |
Release | : 1978 |
Genre | : Science |
ISBN | : |
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Author | : J. Kragten |
Publisher | : Ellis Horwood |
Total Pages | : 886 |
Release | : 1978 |
Genre | : Science |
ISBN | : |
Author | : J. Kragten |
Publisher | : Ellis Horwood |
Total Pages | : 792 |
Release | : 1978 |
Genre | : Science |
ISBN | : |
Author | : Arthur E. Martell |
Publisher | : Springer Science & Business Media |
Total Pages | : 259 |
Release | : 2013-06-29 |
Genre | : Science |
ISBN | : 1489914862 |
Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.
Author | : Fritz Scholz |
Publisher | : Springer |
Total Pages | : 251 |
Release | : 2019-08-01 |
Genre | : Science |
ISBN | : 3030171809 |
This book provides a modern and easy-to-understand introduction to the chemical equilibria in solutions. It focuses on aqueous solutions, but also addresses non-aqueous solutions, covering acid–base, complex, precipitation and redox equilibria. The theory behind these and the resulting knowledge for experimental work build the foundations of analytical chemistry. They are also of essential importance for all solution reactions in environmental chemistry, biochemistry and geochemistry as well as pharmaceutics and medicine. Each chapter and section highlights the main aspects, providing examples in separate boxes. Questions and answers are included to facilitate understanding, while the numerous literature references allow students to easily expand their studies.
Author | : G A Webb |
Publisher | : Royal Society of Chemistry |
Total Pages | : 298 |
Release | : 2007-10-31 |
Genre | : Science |
ISBN | : 1847551254 |
Magnetic resonance has long demonstrated its tremendous versatility in many areas of science. Nowhere has this been more apparent than in food science, where problems encountered in a variety of situations can be resolved using one of the many techniques available to the magnetic resonance practitioner. From structural studies and investigations of molecules in frozen sugar solutions, to identifying the origins of salmon and detecting free radicals in irradiated food, magnetic resonance techniques can provide useful information. Divided into four sections entitled A View Towards the Next Century; Food Safety and Health; Structure and Dynamics; and Analysis, Monitoring and Authentication, the book consists of top quality contributions from renowned international scientists, and looks at what magnetic resonance techniques can offer both now and in the future. Offering state-of-the-art material, Magnetic Resonance in Food Science: A View to the Future is essential reading for both academics and industrialists in food science.
Author | : United States. Bureau of Mines |
Publisher | : |
Total Pages | : 84 |
Release | : 1988 |
Genre | : Steel |
ISBN | : |
Author | : S. F. A. Kettle |
Publisher | : Springer |
Total Pages | : 503 |
Release | : 2013-11-11 |
Genre | : Science |
ISBN | : 3662251914 |
GEORGE CHRISTOU Indiana University, Bloomington I am no doubt representative of a large number of current inorganic chemists in having obtained my undergraduate and postgraduate degrees in the 1970s. It was during this period that I began my continuing love affair with this subject, and the fact that it happened while I was a student in an organic laboratory is beside the point. I was always enchanted by the more physical aspects of inorganic chemistry; while being captivated from an early stage by the synthetic side, and the measure of creation with a small c that it entails, I nevertheless found the application of various theoretical, spectroscopic and physicochemical techniques to inorganic compounds to be fascinating, stimulating, educational and downright exciting. The various bonding theories, for example, and their use to explain or interpret spectroscopic observations were more or less universally accepted as belonging within the realm of inorganic chemistry, and textbooks of the day had whole sections on bonding theories, magnetism, kinetics, electron-transfer mechanisms and so on. However, things changed, and subsequent inorganic chemistry teaching texts tended to emphasize the more synthetic and descriptive side of the field. There are a number of reasons for this, and they no doubt include the rise of diamagnetic organometallic chemistry as the dominant subdiscipline within inorganic chemistry and its relative narrowness vis-d-vis physical methods required for its prosecution.
Author | : Jerzy Rużyłło |
Publisher | : The Electrochemical Society |
Total Pages | : 668 |
Release | : 1998 |
Genre | : Technology & Engineering |
ISBN | : 9781566771887 |
Author | : Joseph F. Zemaitis, Jr. |
Publisher | : John Wiley & Sons |
Total Pages | : 876 |
Release | : 2010-09-16 |
Genre | : Technology & Engineering |
ISBN | : 0470938404 |
Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.