Oxidation of Alcohols to Aldehydes and Ketones

Oxidation of Alcohols to Aldehydes and Ketones
Author: Gabriel Tojo
Publisher: Springer Science & Business Media
Total Pages: 388
Release: 2006-06-15
Genre: Science
ISBN: 038725725X

The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.

Oxidation of Primary Alcohols to Carboxylic Acids

Oxidation of Primary Alcohols to Carboxylic Acids
Author: Gabriel Tojo
Publisher: Springer Science & Business Media
Total Pages: 124
Release: 2007-05-31
Genre: Science
ISBN: 0387354328

As the second volume in a comprehensive encyclopedia of organic reactions, this work provides an elaborated description of the experimental methods used for the oxidation of alcohols to acids. It supplies important data on possible interferences from protecting groups and functional groups, as well as on potential side-reactions. This book is a must for anyone involved in the preparation of organic compounds.

Alcohol Oxidation

Alcohol Oxidation
Author: Steffan Paterson
Publisher: Nova Science Publishers
Total Pages: 0
Release: 2018
Genre: Alcohols
ISBN: 9781536146042

Over the last few years, there has been a growing interest in the development of sustainable processes for large-scale production of commodities. As such, Alcohol Oxidation: Reaction, Effects and Applications addresses recent developments in metal-catalyzed selective oxidation reactions of alcohols to carbonyl-containing compounds under unconventional conditions. Following this, the authors examine how simple alcohols have been used as feedstocks for the preparation of a variety of enantioenriched substances. Cascade reactions allow for the elaboration of complex molecules from simple starting materials in a very efficient way. Several bonds can be made in one-pot procedures without the need for intermediates to be isolated. Metal-organic frameworks and covalent organic frameworks are two classes of highly porous materials that have been heavily investigated in recent years. As such, in this compilation the authors focus on the use of metal-organic frameworks as heterogeneous oxidation catalysts. Enantiopure alcohols are important starting materials and intermediates for the synthesis of many biologically active compounds and fine chemicals. The use of enzymes for the kinetic resolution of racemates has produced affordable enantiopure compounds in good yields, however non-enzymatic chiral catalytic systems have been gaining ground. Accordingly, the effective non-enzymatic oxidative kinetic resolutions of racemic alcohols and related compounds such as diols or benzoins are summarized and discussed. Lastly, the potential employment of the electrochemical process to oxidize alcohols in a more efficient way than the usual chemical method is presented. The use of the electrode potential as a controllable variable and driving force of the process allows for the oxidation of some alcohol molecules without of the very aggressive nature of reactants.

Transition Metal Catalysis in Aerobic Alcohol Oxidation

Transition Metal Catalysis in Aerobic Alcohol Oxidation
Author: Francesca Cardona
Publisher: Royal Society of Chemistry
Total Pages: 304
Release: 2015
Genre: Science
ISBN: 1849738238

This book deals with the search for environmentally benign procedures for the oxidation of alcohols and gives an overview of their transition-metal-catalyzed aerobic oxidation.

Liquid Phase Aerobic Oxidation Catalysis

Liquid Phase Aerobic Oxidation Catalysis
Author: Shannon S. Stahl
Publisher: John Wiley & Sons
Total Pages: 454
Release: 2016-10-10
Genre: Technology & Engineering
ISBN: 3527337814

The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.

Iron Catalysis

Iron Catalysis
Author: Bernd Plietker
Publisher: Springer Science & Business Media
Total Pages: 227
Release: 2011-01-05
Genre: Science
ISBN: 3642146694

Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.

Alcohol and Its Biomarkers

Alcohol and Its Biomarkers
Author: Amitava Dasgupta
Publisher: Elsevier
Total Pages: 313
Release: 2015-02-18
Genre: Science
ISBN: 0128004096

Alcohol and Its Biomarkers: Clinical Aspects and Laboratory Determination is a concise guide to all currently known alcohol biomarkers, their clinical application, and the laboratory methods used to detect them. Pathologists can use this resource to understand the limitations and cost factors associated with each method for determining certain alcohol biomarkers. In addition, interferences in these determinations are discussed, so that clinicians can understand the causes of falsely elevated biomarkers and pathologists and laboratory scientists can potentially eliminate them. The book focuses on the analytical methods used to detect alcohol in blood and urine, the limitations of alcohol determination using enzymatic methods, and the differences between clinical and forensic alcohol measurement. Chapters also cover cutting-edge alcohol biomarkers for potential use. - Focuses on the analytical methods used for detecting alcohol in blood and urine along with the pitfalls and limitations of alcohol determination using enzymatic methods - Explains the difference between clinical and forensic alcohol measurement - Includes a brief overview of the benefits of consuming alcohol in moderation and the hazards of heavy drinking

Modern Oxidation Methods

Modern Oxidation Methods
Author: Jan-Erling Bäckvall
Publisher: John Wiley & Sons
Total Pages: 350
Release: 2006-03-06
Genre: Science
ISBN: 3527604642

At the very latest, with the award of the 2001 Nobel Prize for work on asymmetric oxidation, there has been a need for a comprehensive book on such methods. Edited by J.-E. Backvall, one of the world's leaders in the field, this book fills that gap by covering the topic, from classical to green chemistry methods. He has put together a plethora of well-established authors from all over the world who cover every important aspect in high-quality contributions -- whether aerobic oxidation or transition metal-catalyzed epoxidation of alkenes. By providing an overview of this huge topic, this book represents an unparalleled aid for any chemist working in the field. Chapters include: Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins Transition Metal-Catalyzed Epoxidation of Alkenes Organocatalytic Oxidation - Ketone-Catalyzed Asymmetric Epoxidation of Olefins Modern Oxidation of Alcohols using environmentally Benign Oxidants Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, b-Lactams, Phenols, and Hydrocarbons Selective Oxidations of Sulfides and Amines Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates Oxidation of Carbonyl Compounds Mn-catalysed Oxidation with Hydrogen Peroxide

Comprehensive Organic Chemistry Experiments for the Laboratory Classroom

Comprehensive Organic Chemistry Experiments for the Laboratory Classroom
Author: Carlos A. M. Afonso
Publisher: Royal Society of Chemistry
Total Pages: 976
Release: 2016-12-16
Genre: Science
ISBN: 1849739633

This expansive and practical textbook contains organic chemistry experiments for teaching in the laboratory at the undergraduate level covering a range of functional group transformations and key organic reactions.The editorial team have collected contributions from around the world and standardized them for publication. Each experiment will explore a modern chemistry scenario, such as: sustainable chemistry; application in the pharmaceutical industry; catalysis and material sciences, to name a few. All the experiments will be complemented with a set of questions to challenge the students and a section for the instructors, concerning the results obtained and advice on getting the best outcome from the experiment. A section covering practical aspects with tips and advice for the instructors, together with the results obtained in the laboratory by students, has been compiled for each experiment. Targeted at professors and lecturers in chemistry, this useful text will provide up to date experiments putting the science into context for the students.

Oxidation

Oxidation
Author: Barry M. Trost
Publisher: Elsevier
Total Pages: 1048
Release: 1991
Genre: Science
ISBN: 9780080405988

Volume 7.