The Ordovician was one of the longest of the geological periods, characterized by major magmatic and tectonic activity, an immense biodiversification, swings in climate and sea levels and the first Phanerozoic mass extinction. ‘A Global Synthesis of the Ordovician System’ is presented in two volumes in The Geological Society, Special Publications. This first volume (SP532) charts the history of the Ordovician System and explores significant advances in our understanding of its biostratigraphy, including more precise calibration of its timescale with tephra chronology and regional alignments using astrochronology and cyclostratigraphy. Changes in the world’s oceans, their shifting currents and sea levels, the biogeography of their biotas and the ambient climate are described and discussed against a background of changing palaeogeography. This first volume also includes syntheses of the Ordovician geology for most European countries, including historical key areas, such as Great Britain, Baltoscandia and Bohemia. The second volume (SP533) provides synthetic aspects of the Ordovician geology of most other parts of the world.