Collision-induced Absorption in Gases

Collision-induced Absorption in Gases
Author: Lothar Frommhold
Publisher:
Total Pages: 410
Release: 1993
Genre: Science
ISBN: 9780521393454

This book reviews the theory and experiment of collision-induced absorption of infrared radiation in dense gases.

Collision- and Interaction-Induced Spectroscopy

Collision- and Interaction-Induced Spectroscopy
Author: G.C. Tabisz
Publisher: Springer Science & Business Media
Total Pages: 581
Release: 2012-12-06
Genre: Science
ISBN: 9401101833

Collision-or interaction-induced spectroscopy refers to radiative transitions, which are forbidden in free atoms or molecules, but which occur in clusters of interacting atoms or molecules. The most common phenomena are induced absorption, in the infrared region, and induced light scattering, which involves inelastic scattering of visible laser light. The particle interactions giving rise to the necessary induced dipole moments and polarizabilities are modelled at long range by multipole expansions; at short range, electron overlap and exchange mechanisms come into play. Information on atomic and molecular interactions and dynamics in dense media on a picosecond timescale may be drawn from the spectra. Collision-induced absorption in the infrared was discovered at the University of Toronto in 1949 by Crawford, Welsh and Locke who studied liquid O and N. Through the 1950s and 1960s, 2 2 experimental elucidation of the phenomenon, particularly in gases, continued and theoretical underpinnings were established. In the late 1960s, the related phenomenon of collision-induced light scattering was first observed in compressed inert gases. In 1978, an 'Enrico Fermi' Summer School was held at Varenna, Italy, under the directorship of J. Van Kranendonk. The lectures, there, reviewed activity from the previous two decades, during which the approach to the subject had not changed greatly. In 1983, a highly successful NATO Advanced Research Workshop was held at Bonas, France, under the directorship of G. Birnbaum. An important outcome of that meeting was the demonstration of the maturity and sophistication of current experimental and theoretical techniques.

Collisional Energy Transfer and Topics Related to the Gas Laser Mechanism

Collisional Energy Transfer and Topics Related to the Gas Laser Mechanism
Author: R. Sharma
Publisher:
Total Pages: 6
Release: 1975
Genre:
ISBN:

Through the two year period of the grant the work done represented important steps in the theory of energy transfer during molecular collisions and the theory of collision-induced absorption. Experimental work included measurement of the rates and temperature dependencies for near-resonant transfer processes in several systems. These results were explained by the appropriate theoretical methods using long-range multipolar interactions and the distorted-wave first-order Born approximation. Collision-induced absorption coefficients in rare gas mixtures were also calculated. Eight journal publications resulted from this research.

Collision-induced Absorption in Diatomic Molecule/rare-gas Mixtures

Collision-induced Absorption in Diatomic Molecule/rare-gas Mixtures
Author: H. T. Yura
Publisher:
Total Pages: 42
Release: 1967
Genre: Collisions (Nuclear physics)
ISBN:

A quantum mechanical calculation is given for collision-induced absorption in the infrared and far-infrared spectral regions for mixtures consisting of symmetrical diatomic molecules and rare-gas atoms. The induced moment consists of a short-range overlap term and a long-range quadrupole term. Near molecular transition lines, the quadrupole term gives the main contribution to the absorption, while in the far wings, the overlap term is dominant. The H2-He, H2-Ar, N2-Ar systems are considered, and an estimate is given of the absorption coefficient near 10 millimicrons for N2-N2 systems. (Author).

Phenomena Induced by Intermolecular Interactions

Phenomena Induced by Intermolecular Interactions
Author: G. Birnbaum
Publisher: Springer Science & Business Media
Total Pages: 784
Release: 2013-03-09
Genre: Computers
ISBN: 1461325110

This book is concerned with recent experimental and theoretical work dealing with phenomena created by the transient dipoles and polarizabilities produced by intermolecular interactions. The for mer produce absorption from the microwave to the optical regions of the spectrum and the latter produce Rayleigh and Raman scattering; such absorption and scattering would be absent without collisions. Static properties, such as dielectric constant, refractive index, and Kerr effect, also exhibit the effects of induced dipoles and polarizabilities. The first observation of an infrared absorption spectrum pro duced by the collisions of molecules which ordinarily do not have an allowed dipole transition was reported in 1949 (Crawford, Welsh, and Locke). The first observation of depolarized Rayleigh spectra due to collisions in atomic gases appeared in 1968 (McTague and Birnbaum). However, it was not until 1977 that the first conference dealing with collision-induced phenomena was organized by J. D. Poll at the University of Guelph. This conference was mainly concerned with studies of collision-induced absorption in gases. Light scat tering received more attention at the second meeting of the colli sion-induced community in 1978, at the E. Fermi Summer School on "Intermolecular Spectroscopy and Dynamical Properties of Dense Sys tems," organized by J. Van Kranendonk. However, the emphasis was still on collision-induced absorption in compressed gases, although some work on liquids, solid H , and related subjects such as ro 2 tational relaxation was included. The third induced phenomena con ference, organized by F.