Processing of Heavy Crude Oils

Processing of Heavy Crude Oils
Author: Ramasamy Marappa Gounder
Publisher: Intechopen
Total Pages: 274
Release: 2019
Genre: Science
ISBN: 1839684097

Unconventional heavy crude oils are replacing the conventional light crude oils slowly but steadily as a major energy source. Heavy crude oils are cheaper and present an opportunity to the refiners to process them with higher profit margins. However, the unfavourable characteristics of heavy crude oils such as high viscosity, low API gravity, low H/C ratio, chemical complexity with high asphaltenes content, high acidity, high sulfur and increased level of metal and heteroatom impurities impede extraction, pumping, transportation and processing. Very poor mobility of the heavy oils, due to very high viscosities, significantly affects production and transportation. Techniques for viscosity reduction, drag reduction and in-situ upgrading of the crude oil to improve the flow characteristics in pipelines are presented in this book. The heavier and complex molecules of asphaltenes with low H/C ratios present many technological challenges during the refining of the crude oil, such as heavy coking on catalysts. Hydrogen addition and carbon removal are the two approaches used to improve the recovery of value-added products such as gasoline and diesel. In addition, the heavy crude oil needs pre-treatment to remove the high levels of impurities before the crude oil can be refined. This book introduces the major challenges and some of the methods to overcome them.

Nanotechnology in Oil and Gas Industries

Nanotechnology in Oil and Gas Industries
Author: Tawfik Abdo Saleh
Publisher: Springer
Total Pages: 343
Release: 2017-10-06
Genre: Technology & Engineering
ISBN: 3319606301

This book provides a powerful source to develop new, rapid and highly efficient materials for the application in various fields of oil and gas. It focuses on the synthesis, characterization and applications of various Nanomaterials, presenting the state-of-the-art in developments and innovations in nanocomposites. This book provides the complete practical and theoretical information about the synthesis of nanoparticles with potential use in the field of oil and gas.

Fundamentals of Petroleum Refining

Fundamentals of Petroleum Refining
Author: Mohamed A. Fahim
Publisher: Elsevier
Total Pages: 513
Release: 2009-11-19
Genre: Technology & Engineering
ISBN: 0080931561

Fundamentals of Petroleum Refining presents the fundamentals of thermodynamics and kinetics, and it explains the scientific background essential for understanding refinery operations. The text also provides a detailed introduction to refinery engineering topics, ranging from the basic principles and unit operations to overall refinery economics. The book covers important topics, such as clean fuels, gasification, biofuels, and environmental impact of refining, which are not commonly discussed in most refinery textbooks. Throughout the source, problem sets and examples are given to help the reader practice and apply the fundamental principles of refining. Chapters 1-10 can be used as core materials for teaching undergraduate courses. The first two chapters present an introduction to the petroleum refining industry and then focus on feedstocks and products. Thermophysical properties of crude oils and petroleum fractions, including processes of atmospheric and vacuum distillations, are discussed in Chapters 3 and 4. Conversion processes, product blending, and alkylation are covered in chapters 5-10. The remaining chapters discuss hydrogen production, clean fuel production, refining economics and safety, acid gas treatment and removal, and methods for environmental and effluent treatments. This source can serve both professionals and students (on undergraduate and graduate levels) of Chemical and Petroleum Engineering, Chemistry, and Chemical Technology. Beginners in the engineering field, specifically in the oil and gas industry, may also find this book invaluable. - Provides balanced coverage of fundamental and operational topics - Includes spreadsheets and process simulators for showing trends and simulation case studies - Relates processing to planning and management to give an integrated picture of refining

Practical Advances in Petroleum Processing

Practical Advances in Petroleum Processing
Author: Chang Samuel Hsu
Publisher: Springer Science & Business Media
Total Pages: 894
Release: 2007-01-10
Genre: Science
ISBN: 0387257896

Includes topics not found together in books on petroleum processing: economics, automation, process modeling, online optimization, safety, environmental protection Combines overviews of petroleum composition, refinery processes, process automation, and environmental protection with comprehensive chapters on recent advances in hydroprocessing, FCC, lubricants, hydrogen management Gives diverse perspectives, both geographic and topical, because contributors include experts from eight different countries in North America, Europe and Asia, representing oil companies, universities, catalyst vendors, process licensors, consultants and engineering contractors

Carbons and Carbon Supported Catalysts in Hydroprocessing

Carbons and Carbon Supported Catalysts in Hydroprocessing
Author: Edward Furimsky
Publisher: Royal Society of Chemistry
Total Pages: 174
Release: 2008-06-27
Genre: Science
ISBN: 1847558410

Carbon materials have, in recent years, been attracting attention as potential supports in heterogeneous catalysis. In 2006, the number of articles dealing with various types of catalysts supported on carbon approached 1000, however only a fraction of those were devoted to hydroprocessing catalysts, despite the fact that interest in carbons as supports for hydroprocessing catalysts began more than two decades ago. This unique book is a comprehensive summary of recent research in the field and covers all areas of carbons and carbon materials. The potential application of carbon supports, particularly those of carbon black (CB) and activated carbon (AC) in hydroprocessing catalysis are covered extensively in the book. Novel carbon materials such as carbon fibers and carbon nano tubes (CNT) are also covered, including the more recent developments in the use of fullerenes in hydroprocessing applications - an area with little published research. Although the primary focus of this book is on carbons and carbon supported catalysts, it also identifies the difference in the effect of carbon supports compared with the oxidic supports, particularly that of Y-AL2 O3. Although many books claim to have the same objective, this publication is unique as the difference in catalyst activity and stability was estimated using both model compounds and real feeds under variable conditions. The conditions applied during the preparation of carbon supported catalysts are also comprehensively covered and include various methods of pretreatment of carbon supports to enhance catalyst performance. The model compounds results consistently show higher hydrodesulfurization and hydrodeoxygenation activities of carbon supported catalysts than that of the ?-Al2O3 supported catalysts. Also, the deactivation of the former catalysts by coke deposition was much less evident. Importantly, in this book, most of the model compounds studies on hydrodesulfurization and hydrodeoxygenation were conducted in the absence of nitrogen compounds, as the poisoning effects of such compounds on hydroprocessing reactions are well known. Non-conventional metals (e.g., Pt, Pd, Ru, Rh, Re and Ir) supported on carbon supports are also studied in this book as catalysts for hydroprocessing of model feeds and real feeds. The book shows that these catalysts are much more active than conventional metals containing catalysts however the high cost of these metals prevents commercial utilization of these catalysts. Kinetics of hydroprocessing reactions, as well as kinetics of deactivation over carbon supported catalysts are also investigated under a wide range of experimental conditions and the ?-Al2O3 supported catalysts have been included for comparison. This book, unique in its field, indicates the future potential of carbon supported catalysts during hydroprocessing, particularly in deep hydrodesulfurization and hydrodemetallization.

Hydrocarbon Biorefinery

Hydrocarbon Biorefinery
Author: Sunil Kumar Maity
Publisher: Elsevier
Total Pages: 464
Release: 2021-09-02
Genre: Science
ISBN: 0128234202

Sustainable production of hydrocarbon biofuels from biomass, fuels that are fully compatible with existing internal combustion engines, will allow the global transport economy to transition to a sustainable energy source without the need for capital-intensive new infrastructures. Hydrocarbon Biorefinery: Sustainable Processing of Biomass for Hydrocarbon Biofuels presents a comprehensive and easy to understand consolidation of existing knowledge for the production of hydrocarbon biofuels from biomass. Three major areas for the conversion of biomass to hydrocarbon biofuels are addressed: i) Chemical and thermochemical conversion processes, ii) Biological and biochemical conversion processes, and iii) Conversion processes of biomass-derived compounds. Additionally, the book includes process design, life cycle analysis of various processes, reaction engineering, catalysts, process conditions and process concepts, and is supported with detailed case studies. The economic viability of each process is specifically addressed to provide a clear guide for the economic development of future hydrocarbon biofuels. Hydrocarbon Biorefinery: Sustainable Processing of Biomass for Hydrocarbon Biofuels offers an all-in-one resource for researchers, graduate students, and industry professionals working in the area of bioenergy and will be of interest to energy engineers, chemical engineers, bioengineers, chemists, agricultural researchers, and mechanical engineers. Furthermore, this book provides structured foundational content on biorefineries for undergraduate and graduate students. - Presents fundamental concepts and processes of hydrocarbon biofuel production, covering chemical, biological, and biomass-derived conversion processes - Synthesizes the state-of-the-art research and commercial initiatives of this emerging concept into stand-alone chapters, serving as a structured resource for researchers and practitioners - Emphasizes the process design and economic feasibility of each process using life cycle assessments to support commercial development

Thermal and Catalytic Processes in Petroleum Refining

Thermal and Catalytic Processes in Petroleum Refining
Author: Serge Raseev
Publisher: CRC Press
Total Pages: 1185
Release: 2003-02-26
Genre: Science
ISBN: 1135545596

This text examines the thermal and catalytic processes involved in the refining of petroleum including visbreaking, coking, pyrolysis, catalytic cracking, oligomerization, alkylation, hydrofining, hydroisomerization, hydrocracking, and catalytic reforming. It analyzes the thermodynamics, reaction mechanisms, and kinetics of each process, as well as

Catalysis

Catalysis
Author: John R. Anderson
Publisher: Springer Science & Business Media
Total Pages: 270
Release: 2012-12-06
Genre: Science
ISBN: 3642932789

Catalytic oxidation processes are bf central importance to a substantial part of large-scale chemical industry. Indeed, this area of industrial catalysis has an extremely long history which stretches back well into the last century. The development and growth of catalytic oxi dation processes for the manufacture of commodities such as sulfuric acid and nitric acid can be viewed as indicators for the growth of the early and middle years of the entire inorganic chemical industry, and in an analogous fashion the manufacture of products such as phthalic anhydride, maleic anhydride and ethylene oxide has been central to the development of an organic chemical industry. We should all be able" to learn from history, and present-day scientists and technologists will find considerable benefit in following the account of the historical development of catalytic oxidation processes presented in Chapter I by Drs. G. Chinchen, P. Davies and R. J. Sampson. Alkenes are important intermediates in many processes in organic chemical industry. Being mostly petroleum derived, the alkene availability pattern does not necessar ily match consumption requirements and an alkene inter conversion process such as metathesis is clearly of in dustrial importance. In fact alkene metathesis, in addi tion to its industrial significance, poses an interesting mechanistic problem. upon which considerable effort has been expended in recent years and which is now fairly well understood.